Theoretical Study of Carbon Clusters in Silicon Carbide Nanowires

Using first-principles methods we performed a theoretical study of carbon clusters in silicon carbide (SiC) nanowires. We examined small clusters with carbon interstitials and antisites in hydrogen-passivated SiC nanowires growth along the [100] and [111] directions. The formation energies of these...

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Main Authors: J. M. Morbec, R. H. Miwa
Format: Article
Language:English
Published: Wiley 2011-01-01
Series:Journal of Nanotechnology
Online Access:http://dx.doi.org/10.1155/2011/203423
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author J. M. Morbec
R. H. Miwa
author_facet J. M. Morbec
R. H. Miwa
author_sort J. M. Morbec
collection DOAJ
description Using first-principles methods we performed a theoretical study of carbon clusters in silicon carbide (SiC) nanowires. We examined small clusters with carbon interstitials and antisites in hydrogen-passivated SiC nanowires growth along the [100] and [111] directions. The formation energies of these clusters were calculated as a function of the carbon concentration. We verified that the energetic stability of the carbon defects in SiC nanowires depends strongly on the composition of the nanowire surface: the energetically most favorable configuration in carbon-coated [100] SiC nanowire is not expected to occur in silicon-coated [100] SiC nanowire. The binding energies of some aggregates were also obtained, and they indicate that the formation of carbon clusters in SiC nanowires is energetically favored.
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spelling doaj-art-12cba9dead014ff7aa7c424ea65b088e2025-08-20T02:02:10ZengWileyJournal of Nanotechnology1687-95031687-95112011-01-01201110.1155/2011/203423203423Theoretical Study of Carbon Clusters in Silicon Carbide NanowiresJ. M. Morbec0R. H. Miwa1Instituto de Ciências Exatas, Universidade Federal de Alfenas, 37130-000 Alfenas, MG, BrazilInstituto de Física, Universidade Federal de Uberlândia, P.O. Box 593, 38400-902 Uberlândia, MG, BrazilUsing first-principles methods we performed a theoretical study of carbon clusters in silicon carbide (SiC) nanowires. We examined small clusters with carbon interstitials and antisites in hydrogen-passivated SiC nanowires growth along the [100] and [111] directions. The formation energies of these clusters were calculated as a function of the carbon concentration. We verified that the energetic stability of the carbon defects in SiC nanowires depends strongly on the composition of the nanowire surface: the energetically most favorable configuration in carbon-coated [100] SiC nanowire is not expected to occur in silicon-coated [100] SiC nanowire. The binding energies of some aggregates were also obtained, and they indicate that the formation of carbon clusters in SiC nanowires is energetically favored.http://dx.doi.org/10.1155/2011/203423
spellingShingle J. M. Morbec
R. H. Miwa
Theoretical Study of Carbon Clusters in Silicon Carbide Nanowires
Journal of Nanotechnology
title Theoretical Study of Carbon Clusters in Silicon Carbide Nanowires
title_full Theoretical Study of Carbon Clusters in Silicon Carbide Nanowires
title_fullStr Theoretical Study of Carbon Clusters in Silicon Carbide Nanowires
title_full_unstemmed Theoretical Study of Carbon Clusters in Silicon Carbide Nanowires
title_short Theoretical Study of Carbon Clusters in Silicon Carbide Nanowires
title_sort theoretical study of carbon clusters in silicon carbide nanowires
url http://dx.doi.org/10.1155/2011/203423
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