Immobilization of Peroxidase onto Magnetite Modified Polyaniline

The present study describes the immobilization of horseradish peroxidase (HRP) on magnetite-modified polyaniline (PANImG) activated with glutaraldehyde. After the optimization of the methodology, the immobilization of HRP on PANImG produced the same yield (25%) obtained for PANIG with an efficiency...

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Main Authors: Eduardo Fernandes Barbosa, Fernando Javier Molina, Flavio Marques Lopes, Pedro Antonio García-Ruíz, Samantha Salomão Caramori, Kátia Flávia Fernandes
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:The Scientific World Journal
Online Access:http://dx.doi.org/10.1100/2012/716374
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author Eduardo Fernandes Barbosa
Fernando Javier Molina
Flavio Marques Lopes
Pedro Antonio García-Ruíz
Samantha Salomão Caramori
Kátia Flávia Fernandes
author_facet Eduardo Fernandes Barbosa
Fernando Javier Molina
Flavio Marques Lopes
Pedro Antonio García-Ruíz
Samantha Salomão Caramori
Kátia Flávia Fernandes
author_sort Eduardo Fernandes Barbosa
collection DOAJ
description The present study describes the immobilization of horseradish peroxidase (HRP) on magnetite-modified polyaniline (PANImG) activated with glutaraldehyde. After the optimization of the methodology, the immobilization of HRP on PANImG produced the same yield (25%) obtained for PANIG with an efficiency of 100% (active protein). The optimum pH for immobilization was displaced by the effect of the partition of protons produced in the microenvironment by the magnetite. The tests of repeated use have shown that PANImG-HRP can be used for 13 cycles with maintenance of 50% of the initial activity.
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institution Kabale University
issn 1537-744X
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publishDate 2012-01-01
publisher Wiley
record_format Article
series The Scientific World Journal
spelling doaj-art-12b4f121705b40bc8be4010d29f8f4512025-08-20T03:54:20ZengWileyThe Scientific World Journal1537-744X2012-01-01201210.1100/2012/716374716374Immobilization of Peroxidase onto Magnetite Modified PolyanilineEduardo Fernandes Barbosa0Fernando Javier Molina1Flavio Marques Lopes2Pedro Antonio García-Ruíz3Samantha Salomão Caramori4Kátia Flávia Fernandes5Laboratório de Química de Proteínas, Instituto de Ciências Biológicas, Universidade Federal de Goiás, Codigo Postal 131, 74001-970 Goiânia, GO, BrazilGrupo de Química de Carboydratos y Biotecnología de Alimentos, Departamento de Química Orgánica, Universidad de Murcia, Campus Espinardo, 34100 Murcia, SpainLaboratório de Química de Proteínas, Instituto de Ciências Biológicas, Universidade Federal de Goiás, Codigo Postal 131, 74001-970 Goiânia, GO, BrazilGrupo de Química de Carboydratos y Biotecnología de Alimentos, Departamento de Química Orgánica, Universidad de Murcia, Campus Espinardo, 34100 Murcia, SpainUnidade Universitária de Ciências Exatas e Tecnológicas, Campus Dr. Henrique Santillo, Universidade Estadual de Goiás, Rodovia BR 153 Km 98, Codigo Postal 459, 75132-903 Anápolis, GO, BrazilLaboratório de Química de Proteínas, Instituto de Ciências Biológicas, Universidade Federal de Goiás, Codigo Postal 131, 74001-970 Goiânia, GO, BrazilThe present study describes the immobilization of horseradish peroxidase (HRP) on magnetite-modified polyaniline (PANImG) activated with glutaraldehyde. After the optimization of the methodology, the immobilization of HRP on PANImG produced the same yield (25%) obtained for PANIG with an efficiency of 100% (active protein). The optimum pH for immobilization was displaced by the effect of the partition of protons produced in the microenvironment by the magnetite. The tests of repeated use have shown that PANImG-HRP can be used for 13 cycles with maintenance of 50% of the initial activity.http://dx.doi.org/10.1100/2012/716374
spellingShingle Eduardo Fernandes Barbosa
Fernando Javier Molina
Flavio Marques Lopes
Pedro Antonio García-Ruíz
Samantha Salomão Caramori
Kátia Flávia Fernandes
Immobilization of Peroxidase onto Magnetite Modified Polyaniline
The Scientific World Journal
title Immobilization of Peroxidase onto Magnetite Modified Polyaniline
title_full Immobilization of Peroxidase onto Magnetite Modified Polyaniline
title_fullStr Immobilization of Peroxidase onto Magnetite Modified Polyaniline
title_full_unstemmed Immobilization of Peroxidase onto Magnetite Modified Polyaniline
title_short Immobilization of Peroxidase onto Magnetite Modified Polyaniline
title_sort immobilization of peroxidase onto magnetite modified polyaniline
url http://dx.doi.org/10.1100/2012/716374
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