Fate of Microplastics in Deep Gravel Riverbeds: Evidence for Direct Transfer from River Water to Groundwater

Riverbed sediments act as potential retention reservoirs or transport corridors for microplastic particles (MPs) from river water to groundwater. Vertical concentration profiles of MPs, together with river water and groundwater analysis, provide insight into their fate and transport behavior in fres...

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Main Authors: Marco Pittroff, Matthias Munz, Bernhard Valenti, Constantin Loui, Hermann-Josef Lensing
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Microplastics
Subjects:
Online Access:https://www.mdpi.com/2673-8929/4/2/26
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author Marco Pittroff
Matthias Munz
Bernhard Valenti
Constantin Loui
Hermann-Josef Lensing
author_facet Marco Pittroff
Matthias Munz
Bernhard Valenti
Constantin Loui
Hermann-Josef Lensing
author_sort Marco Pittroff
collection DOAJ
description Riverbed sediments act as potential retention reservoirs or transport corridors for microplastic particles (MPs) from river water to groundwater. Vertical concentration profiles of MPs, together with river water and groundwater analysis, provide insight into their fate and transport behavior in freshwater systems. However, such data remain scarce. This study provides a depth-specific analysis of MPs ≥ 100 µm (abundance, type, and size) in gravelly riverbed sediments down to 200 cm, along with river water and groundwater analysis. Three sediment freeze cores were collected from the Alpine Rhine, a channelized mountain stream with high flow velocities and permanent losing stream conditions. The average MP abundance in the riverbed was 3.1 ± 2.3 MP/kg (100–929 µm); in the river, 92 ± 5 MP/m<sup>3</sup> (112–822 µm); and in the groundwater, 111 ± 6 MP/m<sup>3</sup> (112–676 µm). The dominant polymer types in the riverbed were polypropylene (PP), polyvinyl chloride (PVC), and polyethylene terephthalate (PET) (>70%), while polyamide (PA) dominated in the river water (56%) and the groundwater (76%). The comparable MP concentration, particle sizes, and polymer types between river water and groundwater, as well as the vertical MP concentration profiles, indicate that even large MPs up to 676 µm are transported from river water to groundwater without significant retention in the gravel sediment.
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institution Kabale University
issn 2673-8929
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series Microplastics
spelling doaj-art-12a349dc10c34d09b2f37336f097bb4d2025-08-20T03:29:43ZengMDPI AGMicroplastics2673-89292025-05-01422610.3390/microplastics4020026Fate of Microplastics in Deep Gravel Riverbeds: Evidence for Direct Transfer from River Water to GroundwaterMarco Pittroff0Matthias Munz1Bernhard Valenti2Constantin Loui3Hermann-Josef Lensing4Department Geotechnical Engineering, Federal Waterways Engineering and Research Institute (BAW), 76187 Karlsruhe, GermanyInstitute of Environmental Science and Geography, University of Potsdam, 14476 Potsdam, GermanyInternational Rhine Regulation (IRR), St. Margrethen, 9000 St. Gallen, SwitzerlandInstitute of Environmental Science and Geography, University of Potsdam, 14476 Potsdam, GermanyDepartment Geotechnical Engineering, Federal Waterways Engineering and Research Institute (BAW), 76187 Karlsruhe, GermanyRiverbed sediments act as potential retention reservoirs or transport corridors for microplastic particles (MPs) from river water to groundwater. Vertical concentration profiles of MPs, together with river water and groundwater analysis, provide insight into their fate and transport behavior in freshwater systems. However, such data remain scarce. This study provides a depth-specific analysis of MPs ≥ 100 µm (abundance, type, and size) in gravelly riverbed sediments down to 200 cm, along with river water and groundwater analysis. Three sediment freeze cores were collected from the Alpine Rhine, a channelized mountain stream with high flow velocities and permanent losing stream conditions. The average MP abundance in the riverbed was 3.1 ± 2.3 MP/kg (100–929 µm); in the river, 92 ± 5 MP/m<sup>3</sup> (112–822 µm); and in the groundwater, 111 ± 6 MP/m<sup>3</sup> (112–676 µm). The dominant polymer types in the riverbed were polypropylene (PP), polyvinyl chloride (PVC), and polyethylene terephthalate (PET) (>70%), while polyamide (PA) dominated in the river water (56%) and the groundwater (76%). The comparable MP concentration, particle sizes, and polymer types between river water and groundwater, as well as the vertical MP concentration profiles, indicate that even large MPs up to 676 µm are transported from river water to groundwater without significant retention in the gravel sediment.https://www.mdpi.com/2673-8929/4/2/26microplasticssedimentvertical distributionadvective transportriverbedfreeze core
spellingShingle Marco Pittroff
Matthias Munz
Bernhard Valenti
Constantin Loui
Hermann-Josef Lensing
Fate of Microplastics in Deep Gravel Riverbeds: Evidence for Direct Transfer from River Water to Groundwater
Microplastics
microplastics
sediment
vertical distribution
advective transport
riverbed
freeze core
title Fate of Microplastics in Deep Gravel Riverbeds: Evidence for Direct Transfer from River Water to Groundwater
title_full Fate of Microplastics in Deep Gravel Riverbeds: Evidence for Direct Transfer from River Water to Groundwater
title_fullStr Fate of Microplastics in Deep Gravel Riverbeds: Evidence for Direct Transfer from River Water to Groundwater
title_full_unstemmed Fate of Microplastics in Deep Gravel Riverbeds: Evidence for Direct Transfer from River Water to Groundwater
title_short Fate of Microplastics in Deep Gravel Riverbeds: Evidence for Direct Transfer from River Water to Groundwater
title_sort fate of microplastics in deep gravel riverbeds evidence for direct transfer from river water to groundwater
topic microplastics
sediment
vertical distribution
advective transport
riverbed
freeze core
url https://www.mdpi.com/2673-8929/4/2/26
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AT bernhardvalenti fateofmicroplasticsindeepgravelriverbedsevidencefordirecttransferfromriverwatertogroundwater
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