Surfactant‐Assisted Construction of Covalent Organic Frameworks
Abstract Covalent organic frameworks (COFs), characterized by their unique ordered pore structures, chemical diversity, and high degree of designability, have demonstrated immense application potential across multiple fields. However, traditional synthesis methods often encounter challenges such as...
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| Format: | Article |
| Language: | English |
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Wiley
2025-05-01
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| Series: | Advanced Science |
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| Online Access: | https://doi.org/10.1002/advs.202501580 |
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| author | Youqi Li Qingqing Zhang Zhendong Dai Renzhong Wang Zhaohua Li Yu Huang Runchen Lai Facai Wei Feng Shao |
| author_facet | Youqi Li Qingqing Zhang Zhendong Dai Renzhong Wang Zhaohua Li Yu Huang Runchen Lai Facai Wei Feng Shao |
| author_sort | Youqi Li |
| collection | DOAJ |
| description | Abstract Covalent organic frameworks (COFs), characterized by their unique ordered pore structures, chemical diversity, and high degree of designability, have demonstrated immense application potential across multiple fields. However, traditional synthesis methods often encounter challenges such as low crystallinity and uneven morphology. The introduction of surfactants has opened up new pathways for the synthesis of COFs. Leveraging their intermolecular interactions and self‐assembly properties, surfactants can effectively regulate the nucleation, growth processes, and ultimate structure and properties of COFs. This paper systematically reviews the latest research achievements and future trends in surfactant‐assisted COF synthesis, emphasizing the crucial role of surfactants as key additives in the preparation of COFs. Surfactants not only facilitate uniform nucleation and growth of COFs, enhancing the crystallinity and structural order of the products but also enable precise and diverse regulation of the dimensionality, morphology, and structure of COFs. Furthermore, by influencing the dispersion and processability of COFs, surfactants enhance their practicality and workability. Finally, the paper presents some prospects for the challenges and future opportunities in this emerging research area. |
| format | Article |
| id | doaj-art-127662fefbea4652b9d5032351cbb02a |
| institution | OA Journals |
| issn | 2198-3844 |
| language | English |
| publishDate | 2025-05-01 |
| publisher | Wiley |
| record_format | Article |
| series | Advanced Science |
| spelling | doaj-art-127662fefbea4652b9d5032351cbb02a2025-08-20T02:34:43ZengWileyAdvanced Science2198-38442025-05-011220n/an/a10.1002/advs.202501580Surfactant‐Assisted Construction of Covalent Organic FrameworksYouqi Li0Qingqing Zhang1Zhendong Dai2Renzhong Wang3Zhaohua Li4Yu Huang5Runchen Lai6Facai Wei7Feng Shao8State Key Laboratory of Materials‐Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Nanjing 211816 ChinaState Key Laboratory of Materials‐Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Nanjing 211816 ChinaState Key Laboratory of Materials‐Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Nanjing 211816 ChinaState Key Laboratory of Materials‐Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Nanjing 211816 ChinaSuzhou Laboratory Suzhou 215100 ChinaSuzhou Laboratory Suzhou 215100 ChinaSuzhou Laboratory Suzhou 215100 ChinaSuzhou Laboratory Suzhou 215100 ChinaState Key Laboratory of Materials‐Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Nanjing 211816 ChinaAbstract Covalent organic frameworks (COFs), characterized by their unique ordered pore structures, chemical diversity, and high degree of designability, have demonstrated immense application potential across multiple fields. However, traditional synthesis methods often encounter challenges such as low crystallinity and uneven morphology. The introduction of surfactants has opened up new pathways for the synthesis of COFs. Leveraging their intermolecular interactions and self‐assembly properties, surfactants can effectively regulate the nucleation, growth processes, and ultimate structure and properties of COFs. This paper systematically reviews the latest research achievements and future trends in surfactant‐assisted COF synthesis, emphasizing the crucial role of surfactants as key additives in the preparation of COFs. Surfactants not only facilitate uniform nucleation and growth of COFs, enhancing the crystallinity and structural order of the products but also enable precise and diverse regulation of the dimensionality, morphology, and structure of COFs. Furthermore, by influencing the dispersion and processability of COFs, surfactants enhance their practicality and workability. Finally, the paper presents some prospects for the challenges and future opportunities in this emerging research area.https://doi.org/10.1002/advs.202501580covalent organic frameworkscrystallinitydispersion and processabilitymorphologysurfactant‐assisted synthesis |
| spellingShingle | Youqi Li Qingqing Zhang Zhendong Dai Renzhong Wang Zhaohua Li Yu Huang Runchen Lai Facai Wei Feng Shao Surfactant‐Assisted Construction of Covalent Organic Frameworks Advanced Science covalent organic frameworks crystallinity dispersion and processability morphology surfactant‐assisted synthesis |
| title | Surfactant‐Assisted Construction of Covalent Organic Frameworks |
| title_full | Surfactant‐Assisted Construction of Covalent Organic Frameworks |
| title_fullStr | Surfactant‐Assisted Construction of Covalent Organic Frameworks |
| title_full_unstemmed | Surfactant‐Assisted Construction of Covalent Organic Frameworks |
| title_short | Surfactant‐Assisted Construction of Covalent Organic Frameworks |
| title_sort | surfactant assisted construction of covalent organic frameworks |
| topic | covalent organic frameworks crystallinity dispersion and processability morphology surfactant‐assisted synthesis |
| url | https://doi.org/10.1002/advs.202501580 |
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