Sustainable Production of Graphene from Solar‐Driven Expanded Graphite

Scalable synthesis of graphene sheets is challenging due to the complex production processes. Few‐layered graphene sheets with high lateral sizes (4–5 μm) through a state‐of‐the‐art solar irradiation‐driven liquid‐phase exfoliation technique are achieved. The sunlight is directly used on the interca...

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Main Authors: Shanavas Shajahan, Rami Elkaffas, Dhinesh Babu Velusamy, Dalaver H. Anjum, Yarjan Abdul Samad
Format: Article
Language:English
Published: Wiley-VCH 2025-03-01
Series:Advanced Energy & Sustainability Research
Subjects:
Online Access:https://doi.org/10.1002/aesr.202400274
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author Shanavas Shajahan
Rami Elkaffas
Dhinesh Babu Velusamy
Dalaver H. Anjum
Yarjan Abdul Samad
author_facet Shanavas Shajahan
Rami Elkaffas
Dhinesh Babu Velusamy
Dalaver H. Anjum
Yarjan Abdul Samad
author_sort Shanavas Shajahan
collection DOAJ
description Scalable synthesis of graphene sheets is challenging due to the complex production processes. Few‐layered graphene sheets with high lateral sizes (4–5 μm) through a state‐of‐the‐art solar irradiation‐driven liquid‐phase exfoliation technique are achieved. The sunlight is directly used on the intercalated graphite flakes for just 0.5 s to achieve the graphite expansion. Using focused sunlight makes our solar expansion technique sustainable with zero energy demand (0 J). The total energy spent to produce 1 kg of graphene through this technique is only around 2.135 MJ. The produced graphene sheets show significant electrical conductivity (1586 S cm−1) and high in‐plane thermal conductivity (196.3 W mK−1). The electromagnetic interference (EMI) shielding properties of solar graphene are evaluated in the X‐band region, and it shows a very high shielding effectiveness of about 71.5 dB at a thickness of ≈80 μm with an absolute EMI shielding effectiveness of about 11983.7 dB cm2 g−1. Overall, this work provides a viable approach for the efficient, scalable production of graphene with reduced energy consumption and cost, contributing to the sustainable production of graphene.
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issn 2699-9412
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series Advanced Energy & Sustainability Research
spelling doaj-art-11a4baecb9bc4c12977e7a40b14f04242025-08-20T03:16:35ZengWiley-VCHAdvanced Energy & Sustainability Research2699-94122025-03-0163n/an/a10.1002/aesr.202400274Sustainable Production of Graphene from Solar‐Driven Expanded GraphiteShanavas Shajahan0Rami Elkaffas1Dhinesh Babu Velusamy2Dalaver H. Anjum3Yarjan Abdul Samad4Department of Aerospace Engineering Khalifa University of Science and Technology 127788 Abu Dhabi United Arab EmiratesDepartment of Aerospace Engineering Khalifa University of Science and Technology 127788 Abu Dhabi United Arab EmiratesDepartment of Aerospace Engineering Khalifa University of Science and Technology 127788 Abu Dhabi United Arab EmiratesDepartment of Physics Khalifa University of Science and Technology 127788 Abu Dhabi United Arab EmiratesDepartment of Aerospace Engineering Khalifa University of Science and Technology 127788 Abu Dhabi United Arab EmiratesScalable synthesis of graphene sheets is challenging due to the complex production processes. Few‐layered graphene sheets with high lateral sizes (4–5 μm) through a state‐of‐the‐art solar irradiation‐driven liquid‐phase exfoliation technique are achieved. The sunlight is directly used on the intercalated graphite flakes for just 0.5 s to achieve the graphite expansion. Using focused sunlight makes our solar expansion technique sustainable with zero energy demand (0 J). The total energy spent to produce 1 kg of graphene through this technique is only around 2.135 MJ. The produced graphene sheets show significant electrical conductivity (1586 S cm−1) and high in‐plane thermal conductivity (196.3 W mK−1). The electromagnetic interference (EMI) shielding properties of solar graphene are evaluated in the X‐band region, and it shows a very high shielding effectiveness of about 71.5 dB at a thickness of ≈80 μm with an absolute EMI shielding effectiveness of about 11983.7 dB cm2 g−1. Overall, this work provides a viable approach for the efficient, scalable production of graphene with reduced energy consumption and cost, contributing to the sustainable production of graphene.https://doi.org/10.1002/aesr.202400274energy demandsgraphenesolar irradiationssustainabilities
spellingShingle Shanavas Shajahan
Rami Elkaffas
Dhinesh Babu Velusamy
Dalaver H. Anjum
Yarjan Abdul Samad
Sustainable Production of Graphene from Solar‐Driven Expanded Graphite
Advanced Energy & Sustainability Research
energy demands
graphene
solar irradiations
sustainabilities
title Sustainable Production of Graphene from Solar‐Driven Expanded Graphite
title_full Sustainable Production of Graphene from Solar‐Driven Expanded Graphite
title_fullStr Sustainable Production of Graphene from Solar‐Driven Expanded Graphite
title_full_unstemmed Sustainable Production of Graphene from Solar‐Driven Expanded Graphite
title_short Sustainable Production of Graphene from Solar‐Driven Expanded Graphite
title_sort sustainable production of graphene from solar driven expanded graphite
topic energy demands
graphene
solar irradiations
sustainabilities
url https://doi.org/10.1002/aesr.202400274
work_keys_str_mv AT shanavasshajahan sustainableproductionofgraphenefromsolardrivenexpandedgraphite
AT ramielkaffas sustainableproductionofgraphenefromsolardrivenexpandedgraphite
AT dhineshbabuvelusamy sustainableproductionofgraphenefromsolardrivenexpandedgraphite
AT dalaverhanjum sustainableproductionofgraphenefromsolardrivenexpandedgraphite
AT yarjanabdulsamad sustainableproductionofgraphenefromsolardrivenexpandedgraphite