1,1′-Disubstituted Ferrocene Ligand Scaffolds Featuring Pnictogens Other than Phosphorus as Donor Sites
The chemistry of bidentate ligands with a dppf-like motif, where phosphorus is fully or partially replaced by other pnictogens as donor sites, is summarized and discussed in this comprehensive review, while covering the literature from 1966 to 2024, related to more than 165 original references and d...
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MDPI AG
2024-11-01
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| author | Subhayan Dey Rudolf Pietschnig |
| author_facet | Subhayan Dey Rudolf Pietschnig |
| author_sort | Subhayan Dey |
| collection | DOAJ |
| description | The chemistry of bidentate ligands with a dppf-like motif, where phosphorus is fully or partially replaced by other pnictogens as donor sites, is summarized and discussed in this comprehensive review, while covering the literature from 1966 to 2024, related to more than 165 original references and discussing more than 75 independent chemical entities (<b>1</b>–<b>41</b>). Besides addressing synthetic, structural, and electrochemical aspects of such compounds, their donor properties and metal coordination behavior is discussed, along with catalytic applications. Based on their electronic and steric situations, trends in the performance of such compounds, either as ligands for catalysis or on their own merits for non-catalytic purposes, have been elucidated. Related topics that could not be covered in this article have been acknowledged by referring to the literature for completeness. |
| format | Article |
| id | doaj-art-11a02cb84eba4804884e1f0418074c87 |
| institution | OA Journals |
| issn | 1420-3049 |
| language | English |
| publishDate | 2024-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj-art-11a02cb84eba4804884e1f0418074c872025-08-20T02:04:59ZengMDPI AGMolecules1420-30492024-11-012922528310.3390/molecules292252831,1′-Disubstituted Ferrocene Ligand Scaffolds Featuring Pnictogens Other than Phosphorus as Donor SitesSubhayan Dey0Rudolf Pietschnig1Department of Chemistry, School of Advanced Sciences, Vellore Institute of Technology, Vandalur-Kelambakkam Road, Chennai 600127, Tamil Nadu, IndiaInstitut für Chemie und CINSaT, University of Kassel, Heinrich Plett-Straße 40, 34132 Kassel, GermanyThe chemistry of bidentate ligands with a dppf-like motif, where phosphorus is fully or partially replaced by other pnictogens as donor sites, is summarized and discussed in this comprehensive review, while covering the literature from 1966 to 2024, related to more than 165 original references and discussing more than 75 independent chemical entities (<b>1</b>–<b>41</b>). Besides addressing synthetic, structural, and electrochemical aspects of such compounds, their donor properties and metal coordination behavior is discussed, along with catalytic applications. Based on their electronic and steric situations, trends in the performance of such compounds, either as ligands for catalysis or on their own merits for non-catalytic purposes, have been elucidated. Related topics that could not be covered in this article have been acknowledged by referring to the literature for completeness.https://www.mdpi.com/1420-3049/29/22/5283pnictogensferrocenedppf-analogsaminearsenicantimony |
| spellingShingle | Subhayan Dey Rudolf Pietschnig 1,1′-Disubstituted Ferrocene Ligand Scaffolds Featuring Pnictogens Other than Phosphorus as Donor Sites Molecules pnictogens ferrocene dppf-analogs amine arsenic antimony |
| title | 1,1′-Disubstituted Ferrocene Ligand Scaffolds Featuring Pnictogens Other than Phosphorus as Donor Sites |
| title_full | 1,1′-Disubstituted Ferrocene Ligand Scaffolds Featuring Pnictogens Other than Phosphorus as Donor Sites |
| title_fullStr | 1,1′-Disubstituted Ferrocene Ligand Scaffolds Featuring Pnictogens Other than Phosphorus as Donor Sites |
| title_full_unstemmed | 1,1′-Disubstituted Ferrocene Ligand Scaffolds Featuring Pnictogens Other than Phosphorus as Donor Sites |
| title_short | 1,1′-Disubstituted Ferrocene Ligand Scaffolds Featuring Pnictogens Other than Phosphorus as Donor Sites |
| title_sort | 1 1 disubstituted ferrocene ligand scaffolds featuring pnictogens other than phosphorus as donor sites |
| topic | pnictogens ferrocene dppf-analogs amine arsenic antimony |
| url | https://www.mdpi.com/1420-3049/29/22/5283 |
| work_keys_str_mv | AT subhayandey 11disubstitutedferroceneligandscaffoldsfeaturingpnictogensotherthanphosphorusasdonorsites AT rudolfpietschnig 11disubstitutedferroceneligandscaffoldsfeaturingpnictogensotherthanphosphorusasdonorsites |