Production of High Viscosity Chitosan from Biologically Purified Chitin Isolated by Microbial Fermentation and Deproteinization

The objective of this study was to produce high viscosity chitosan from shrimp chitin prepared by using a two-step biological treatment process: decalcification and deproteinization. Glucose was fermented with Lactobacillus pentosus L7 to lactic acid. At a pH of 3.9±0.1, the calcium carbonate of th...

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Main Authors: Ekkalak Ploydee, Saipin Chaiyanan
Format: Article
Language:English
Published: Wiley 2014-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2014/162173
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author Ekkalak Ploydee
Saipin Chaiyanan
author_facet Ekkalak Ploydee
Saipin Chaiyanan
author_sort Ekkalak Ploydee
collection DOAJ
description The objective of this study was to produce high viscosity chitosan from shrimp chitin prepared by using a two-step biological treatment process: decalcification and deproteinization. Glucose was fermented with Lactobacillus pentosus L7 to lactic acid. At a pH of 3.9±0.1, the calcium carbonate of the shells was solubilized in 48 hours. The amounts of residual calcium in the form of ash (1.4±0.5%) and crude protein (23.2±2.5%) were further eliminated by the activity of proteolytic Bacillus thuringiensis SA. After decalcification and deproteinization of the shrimp shells, residual calcium and crude protein of shrimp chitin flakes were 1.7±0.4% and 3.8±1.3%, respectively. Chitin was deacetylated with 50% NaOH at 121°C for 5 hours. After deacetylation, the chitosan had residual calcium, crude protein content, and degree of acetylation of 1.6±0.6%, 0.4±0.3%, and 83.2±1.5%, respectively. The viscosity of chitosan prepared from chitin extracted by this two-step biological process was 1,007±14.7 mPa·s, whereas chitosan prepared from chemically processed chitin had a viscosity of 323±15.6   mPa·s, indicating that biologically purified chitin gave chitosan with a high quality.
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spelling doaj-art-111f55d94e924724965fde42f090ebca2025-08-20T02:02:19ZengWileyInternational Journal of Polymer Science1687-94221687-94302014-01-01201410.1155/2014/162173162173Production of High Viscosity Chitosan from Biologically Purified Chitin Isolated by Microbial Fermentation and DeproteinizationEkkalak Ploydee0Saipin Chaiyanan1Department of Microbiology, Faculty of Science, King Mongkut’s University of Technology Thonburi, Pracha Uthit Road, Bangkok 10140, ThailandDepartment of Microbiology, Faculty of Science, King Mongkut’s University of Technology Thonburi, Pracha Uthit Road, Bangkok 10140, ThailandThe objective of this study was to produce high viscosity chitosan from shrimp chitin prepared by using a two-step biological treatment process: decalcification and deproteinization. Glucose was fermented with Lactobacillus pentosus L7 to lactic acid. At a pH of 3.9±0.1, the calcium carbonate of the shells was solubilized in 48 hours. The amounts of residual calcium in the form of ash (1.4±0.5%) and crude protein (23.2±2.5%) were further eliminated by the activity of proteolytic Bacillus thuringiensis SA. After decalcification and deproteinization of the shrimp shells, residual calcium and crude protein of shrimp chitin flakes were 1.7±0.4% and 3.8±1.3%, respectively. Chitin was deacetylated with 50% NaOH at 121°C for 5 hours. After deacetylation, the chitosan had residual calcium, crude protein content, and degree of acetylation of 1.6±0.6%, 0.4±0.3%, and 83.2±1.5%, respectively. The viscosity of chitosan prepared from chitin extracted by this two-step biological process was 1,007±14.7 mPa·s, whereas chitosan prepared from chemically processed chitin had a viscosity of 323±15.6   mPa·s, indicating that biologically purified chitin gave chitosan with a high quality.http://dx.doi.org/10.1155/2014/162173
spellingShingle Ekkalak Ploydee
Saipin Chaiyanan
Production of High Viscosity Chitosan from Biologically Purified Chitin Isolated by Microbial Fermentation and Deproteinization
International Journal of Polymer Science
title Production of High Viscosity Chitosan from Biologically Purified Chitin Isolated by Microbial Fermentation and Deproteinization
title_full Production of High Viscosity Chitosan from Biologically Purified Chitin Isolated by Microbial Fermentation and Deproteinization
title_fullStr Production of High Viscosity Chitosan from Biologically Purified Chitin Isolated by Microbial Fermentation and Deproteinization
title_full_unstemmed Production of High Viscosity Chitosan from Biologically Purified Chitin Isolated by Microbial Fermentation and Deproteinization
title_short Production of High Viscosity Chitosan from Biologically Purified Chitin Isolated by Microbial Fermentation and Deproteinization
title_sort production of high viscosity chitosan from biologically purified chitin isolated by microbial fermentation and deproteinization
url http://dx.doi.org/10.1155/2014/162173
work_keys_str_mv AT ekkalakploydee productionofhighviscositychitosanfrombiologicallypurifiedchitinisolatedbymicrobialfermentationanddeproteinization
AT saipinchaiyanan productionofhighviscositychitosanfrombiologicallypurifiedchitinisolatedbymicrobialfermentationanddeproteinization