Enhanced phosphorus regeneration linked to Ediacaran ocean oxygenation

Abstract Several pulses of ocean oxygenation events were recognized in the Ediacaran period. However, the intrinsic triggers behind them remain ambiguous. Here we report phosphorus speciation data from the Ediacaran Doushantuo Formation, South China, to elucidate the role of recycled phosphorus in d...

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Main Authors: Dongtao Xu, Xinqiang Wang, Eva E. Stüeken, Weiming Xu, Zheng Qin, Jihua Hao, Xiaoying Shi, Dongjie Tang
Format: Article
Language:English
Published: Nature Portfolio 2025-06-01
Series:Communications Earth & Environment
Online Access:https://doi.org/10.1038/s43247-025-02463-2
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author Dongtao Xu
Xinqiang Wang
Eva E. Stüeken
Weiming Xu
Zheng Qin
Jihua Hao
Xiaoying Shi
Dongjie Tang
author_facet Dongtao Xu
Xinqiang Wang
Eva E. Stüeken
Weiming Xu
Zheng Qin
Jihua Hao
Xiaoying Shi
Dongjie Tang
author_sort Dongtao Xu
collection DOAJ
description Abstract Several pulses of ocean oxygenation events were recognized in the Ediacaran period. However, the intrinsic triggers behind them remain ambiguous. Here we report phosphorus speciation data from the Ediacaran Doushantuo Formation, South China, to elucidate the role of recycled phosphorus in driving ocean oxygenation. High ratios of organic carbon to organic phosphorus in all samples relative to the Redfield ratio generally imply preferential release of phosphorus during the remineralization of organic matter. Notably, ratios of organic carbon to reactive phosphorus exceed the Redfield ratio during purported oxygenation intervals, but fall mostly below or close to the Redfield ratio in the rest of the section. Quantitative calculations suggest that enhanced benthic and water-column recycling created a phosphorus influx into the ocean that was comparable to or outpaced that of weathering input. Our study provides empirical evidence for untangling the mechanisms of the Ediacaran oxygenation.
format Article
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institution OA Journals
issn 2662-4435
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publishDate 2025-06-01
publisher Nature Portfolio
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series Communications Earth & Environment
spelling doaj-art-106cd892f83c492caf75d0eb82b0902f2025-08-20T02:37:36ZengNature PortfolioCommunications Earth & Environment2662-44352025-06-01611710.1038/s43247-025-02463-2Enhanced phosphorus regeneration linked to Ediacaran ocean oxygenationDongtao Xu0Xinqiang Wang1Eva E. Stüeken2Weiming Xu3Zheng Qin4Jihua Hao5Xiaoying Shi6Dongjie Tang7State Key Laboratory of Geomicrobiology and Environmental Changes, China University of Geosciences (Beijing)State Key Laboratory of Geomicrobiology and Environmental Changes, China University of Geosciences (Beijing)School of Earth & Environmental Sciences, University of St AndrewsCAS Key Laboratory of Crust-Mantle Materials and Environments, School of Earth and Space Sciences, University of Science and Technology of ChinaState Key Laboratory of Geological Processes and Mineral Resources, China University of GeosciencesCAS Key Laboratory of Crust-Mantle Materials and Environments, School of Earth and Space Sciences, University of Science and Technology of ChinaState Key Laboratory of Geomicrobiology and Environmental Changes, China University of Geosciences (Beijing)State Key Laboratory of Geomicrobiology and Environmental Changes, China University of Geosciences (Beijing)Abstract Several pulses of ocean oxygenation events were recognized in the Ediacaran period. However, the intrinsic triggers behind them remain ambiguous. Here we report phosphorus speciation data from the Ediacaran Doushantuo Formation, South China, to elucidate the role of recycled phosphorus in driving ocean oxygenation. High ratios of organic carbon to organic phosphorus in all samples relative to the Redfield ratio generally imply preferential release of phosphorus during the remineralization of organic matter. Notably, ratios of organic carbon to reactive phosphorus exceed the Redfield ratio during purported oxygenation intervals, but fall mostly below or close to the Redfield ratio in the rest of the section. Quantitative calculations suggest that enhanced benthic and water-column recycling created a phosphorus influx into the ocean that was comparable to or outpaced that of weathering input. Our study provides empirical evidence for untangling the mechanisms of the Ediacaran oxygenation.https://doi.org/10.1038/s43247-025-02463-2
spellingShingle Dongtao Xu
Xinqiang Wang
Eva E. Stüeken
Weiming Xu
Zheng Qin
Jihua Hao
Xiaoying Shi
Dongjie Tang
Enhanced phosphorus regeneration linked to Ediacaran ocean oxygenation
Communications Earth & Environment
title Enhanced phosphorus regeneration linked to Ediacaran ocean oxygenation
title_full Enhanced phosphorus regeneration linked to Ediacaran ocean oxygenation
title_fullStr Enhanced phosphorus regeneration linked to Ediacaran ocean oxygenation
title_full_unstemmed Enhanced phosphorus regeneration linked to Ediacaran ocean oxygenation
title_short Enhanced phosphorus regeneration linked to Ediacaran ocean oxygenation
title_sort enhanced phosphorus regeneration linked to ediacaran ocean oxygenation
url https://doi.org/10.1038/s43247-025-02463-2
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AT xinqiangwang enhancedphosphorusregenerationlinkedtoediacaranoceanoxygenation
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AT weimingxu enhancedphosphorusregenerationlinkedtoediacaranoceanoxygenation
AT zhengqin enhancedphosphorusregenerationlinkedtoediacaranoceanoxygenation
AT jihuahao enhancedphosphorusregenerationlinkedtoediacaranoceanoxygenation
AT xiaoyingshi enhancedphosphorusregenerationlinkedtoediacaranoceanoxygenation
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