The Possibility of Using Barley Grains Extract as an Acidic Corrosion Inhibitor for Carbon Steel

      The effect of barley seed extracts on the corrosion of carbon steel in 1M hydrochloric acid at different temperatures was investigated from the perspective of their potential use as green inhibitors in the cleaning and descaling processes in heat exchangers. A 50% ethanol/water (vol) so...

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Main Authors: Bashar Alhaidar, Fidaa Reeshah, Yousef Jammoal
Format: Article
Language:English
Published: University of Baghdad, College of Science for Women 2024-04-01
Series:مجلة بغداد للعلوم
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Online Access:https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/8501
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author Bashar Alhaidar
Fidaa Reeshah
Yousef Jammoal
author_facet Bashar Alhaidar
Fidaa Reeshah
Yousef Jammoal
author_sort Bashar Alhaidar
collection DOAJ
description       The effect of barley seed extracts on the corrosion of carbon steel in 1M hydrochloric acid at different temperatures was investigated from the perspective of their potential use as green inhibitors in the cleaning and descaling processes in heat exchangers. A 50% ethanol/water (vol) solution was used for extraction. Two extraction methods were used: soaking and ultrasound. The inhibition mechanism of the inhibitor that gave the best efficiency was investigated by studying the adsorption and corrosion processes by electrochemical methods (potentiodynamic polarisation (Tafel curves) and electrochemical resistance spectroscopy) and thermodynamic calculations. The results of the study showed no effect of the extraction method on the inhibition behavior, the inhibition as a function of concentration showed a significant increase in the inhibition efficiency up to concentration 400 ppm, then it appeared independent of it in both methods. However, the inhibition efficiency of the soaking method was higher at 800 ppm (87.01% compared to 80% for the ultrasound method). The study of the inhibition mechanism of this extract indicated the possibility of chemical adsorption. Inhibition activity increased with temperature.
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spelling doaj-art-105e54bd2b1941ef86d0a42666f2a3e02025-08-20T02:54:58ZengUniversity of Baghdad, College of Science for Womenمجلة بغداد للعلوم2078-86652411-79862024-04-0121410.21123/bsj.2023.8501The Possibility of Using Barley Grains Extract as an Acidic Corrosion Inhibitor for Carbon SteelBashar Alhaidar0https://orcid.org/0000-0002-5233-4614Fidaa Reeshah1Yousef Jammoal2https://orcid.org/0000-0003-0333-9408Department of Chemical Engineering, Faculty of Petroleum and Chemical Engineering, Al-Baath University, Syria.Department of Chemical Engineering, Faculty of Petroleum and Chemical Engineering, Al-Baath University, Syria.Hydrometallurgy Office, Atomic Eenergy Commission, Damascus, Syria.       The effect of barley seed extracts on the corrosion of carbon steel in 1M hydrochloric acid at different temperatures was investigated from the perspective of their potential use as green inhibitors in the cleaning and descaling processes in heat exchangers. A 50% ethanol/water (vol) solution was used for extraction. Two extraction methods were used: soaking and ultrasound. The inhibition mechanism of the inhibitor that gave the best efficiency was investigated by studying the adsorption and corrosion processes by electrochemical methods (potentiodynamic polarisation (Tafel curves) and electrochemical resistance spectroscopy) and thermodynamic calculations. The results of the study showed no effect of the extraction method on the inhibition behavior, the inhibition as a function of concentration showed a significant increase in the inhibition efficiency up to concentration 400 ppm, then it appeared independent of it in both methods. However, the inhibition efficiency of the soaking method was higher at 800 ppm (87.01% compared to 80% for the ultrasound method). The study of the inhibition mechanism of this extract indicated the possibility of chemical adsorption. Inhibition activity increased with temperature. https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/8501Acidic corrosion, Barley grains, Carbon steel, Corrosion inhibitors, Electrochemical tests, Extraction.
spellingShingle Bashar Alhaidar
Fidaa Reeshah
Yousef Jammoal
The Possibility of Using Barley Grains Extract as an Acidic Corrosion Inhibitor for Carbon Steel
مجلة بغداد للعلوم
Acidic corrosion, Barley grains, Carbon steel, Corrosion inhibitors, Electrochemical tests, Extraction.
title The Possibility of Using Barley Grains Extract as an Acidic Corrosion Inhibitor for Carbon Steel
title_full The Possibility of Using Barley Grains Extract as an Acidic Corrosion Inhibitor for Carbon Steel
title_fullStr The Possibility of Using Barley Grains Extract as an Acidic Corrosion Inhibitor for Carbon Steel
title_full_unstemmed The Possibility of Using Barley Grains Extract as an Acidic Corrosion Inhibitor for Carbon Steel
title_short The Possibility of Using Barley Grains Extract as an Acidic Corrosion Inhibitor for Carbon Steel
title_sort possibility of using barley grains extract as an acidic corrosion inhibitor for carbon steel
topic Acidic corrosion, Barley grains, Carbon steel, Corrosion inhibitors, Electrochemical tests, Extraction.
url https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/8501
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