(Pyridin-2-ylmethyl)porphyrins: synthesis, characterization and C–N oxidative fusion attempts

(Pyridin-2-ylmethyl)porphyrins: synthesis, characterization and C–N oxidative fusion attempts

A new route for the synthesis of meso-(pyridin-2-ylmethyl)porphyrins was developed, based on the nucleophilic attack of (pyridin-2-ylmethyl)lithium reagent on a porphyrin bearing one free meso position. The latter is then metalated with Zn(II) and Ni(II). These products were characterized by NMR spe...

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Bibliographic Details
Main Authors: Berthelot, Mathieu, Echaubard, Julie, Bousfiha, Asmae, Devillers, Charles H.
Format: Article
Language:English
Published: Académie des sciences 2024-06-01
Series:Comptes Rendus. Chimie
Subjects:
Pyridinylporphyrin
Pyridine
Oxidative C–N fusion
π-extension
Cyclic voltammetry
NMR spectroscopy
Online Access:https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.307/
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