Concentrations and Water Mass Transport of Legacy POPs in the Arctic Ocean

Abstract The Arctic Ocean is known to be contaminated by various persistent organic pollutants (POPs). The Fram Strait, the only deepwater passage to the Arctic Ocean (from the Atlantic Ocean), represents an unquantified gateway for POPs fluxes into and out of the Arctic. Polyethylene passive sample...

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Main Authors: Yuxin Ma, Dave A. Adelman, Eduard Bauerfeind, Ana Cabrerizo, Carrie A. McDonough, Derek Muir, Thomas Soltwedel, Caoxin Sun, Charlotte C. Wagner, Elsie M. Sunderland, Rainer Lohmann
Format: Article
Language:English
Published: Wiley 2018-12-01
Series:Geophysical Research Letters
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Online Access:https://doi.org/10.1029/2018GL078759
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author Yuxin Ma
Dave A. Adelman
Eduard Bauerfeind
Ana Cabrerizo
Carrie A. McDonough
Derek Muir
Thomas Soltwedel
Caoxin Sun
Charlotte C. Wagner
Elsie M. Sunderland
Rainer Lohmann
author_facet Yuxin Ma
Dave A. Adelman
Eduard Bauerfeind
Ana Cabrerizo
Carrie A. McDonough
Derek Muir
Thomas Soltwedel
Caoxin Sun
Charlotte C. Wagner
Elsie M. Sunderland
Rainer Lohmann
author_sort Yuxin Ma
collection DOAJ
description Abstract The Arctic Ocean is known to be contaminated by various persistent organic pollutants (POPs). The Fram Strait, the only deepwater passage to the Arctic Ocean (from the Atlantic Ocean), represents an unquantified gateway for POPs fluxes into and out of the Arctic. Polyethylene passive samplers were deployed in vertical profiles in the Fram Strait and in air and surface water in the Canadian Archipelago to determine the concentrations, profiles, and mass fluxes of dissolved polychlorinated biphenyls (PCBs) and organochlorine pesticides. In the Fram Strait, higher concentrations of ΣPCBs (1.3–3.6 pg/L) and dichlorodiphenyltrichloroethanes (ΣDDTs, 5.2–9.1 pg/L) were observed in the deepwater masses (below 1,000 m), similar to nutrient‐like vertical profiles. There was net southward transport of hexachlorobenzene and hexachlorocyclohexanes (ΣHCHs) of 0.70 and 14 Mg/year but a net northward transport of ΣPCBs at 0.16 Mg/year through the Fram Strait.
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spelling doaj-art-105b2b6803744f628145e20e9f9047dd2025-08-20T03:09:42ZengWileyGeophysical Research Letters0094-82761944-80072018-12-01452312,97212,98110.1029/2018GL078759Concentrations and Water Mass Transport of Legacy POPs in the Arctic OceanYuxin Ma0Dave A. Adelman1Eduard Bauerfeind2Ana Cabrerizo3Carrie A. McDonough4Derek Muir5Thomas Soltwedel6Caoxin Sun7Charlotte C. Wagner8Elsie M. Sunderland9Rainer Lohmann10Graduate School of Oceanography University of Rhode Island Narragansett RI USAGraduate School of Oceanography University of Rhode Island Narragansett RI USAAlfred Wegener Institute, Helmholtz Center for Polar and Marine Research Bremerhaven GermanyAquatic Contaminants Research Division Environment and Climate Change Canada Burlington Ontario CanadaGraduate School of Oceanography University of Rhode Island Narragansett RI USAAquatic Contaminants Research Division Environment and Climate Change Canada Burlington Ontario CanadaAlfred Wegener Institute, Helmholtz Center for Polar and Marine Research Bremerhaven GermanyGraduate School of Oceanography University of Rhode Island Narragansett RI USAHarvard John A. Paulson School of Engineering and Applied Sciences Harvard University Cambridge MA USAHarvard John A. Paulson School of Engineering and Applied Sciences Harvard University Cambridge MA USAGraduate School of Oceanography University of Rhode Island Narragansett RI USAAbstract The Arctic Ocean is known to be contaminated by various persistent organic pollutants (POPs). The Fram Strait, the only deepwater passage to the Arctic Ocean (from the Atlantic Ocean), represents an unquantified gateway for POPs fluxes into and out of the Arctic. Polyethylene passive samplers were deployed in vertical profiles in the Fram Strait and in air and surface water in the Canadian Archipelago to determine the concentrations, profiles, and mass fluxes of dissolved polychlorinated biphenyls (PCBs) and organochlorine pesticides. In the Fram Strait, higher concentrations of ΣPCBs (1.3–3.6 pg/L) and dichlorodiphenyltrichloroethanes (ΣDDTs, 5.2–9.1 pg/L) were observed in the deepwater masses (below 1,000 m), similar to nutrient‐like vertical profiles. There was net southward transport of hexachlorobenzene and hexachlorocyclohexanes (ΣHCHs) of 0.70 and 14 Mg/year but a net northward transport of ΣPCBs at 0.16 Mg/year through the Fram Strait.https://doi.org/10.1029/2018GL078759legacy POPsArcticFram Straitpassive samplervertical profilesmass transport
spellingShingle Yuxin Ma
Dave A. Adelman
Eduard Bauerfeind
Ana Cabrerizo
Carrie A. McDonough
Derek Muir
Thomas Soltwedel
Caoxin Sun
Charlotte C. Wagner
Elsie M. Sunderland
Rainer Lohmann
Concentrations and Water Mass Transport of Legacy POPs in the Arctic Ocean
Geophysical Research Letters
legacy POPs
Arctic
Fram Strait
passive sampler
vertical profiles
mass transport
title Concentrations and Water Mass Transport of Legacy POPs in the Arctic Ocean
title_full Concentrations and Water Mass Transport of Legacy POPs in the Arctic Ocean
title_fullStr Concentrations and Water Mass Transport of Legacy POPs in the Arctic Ocean
title_full_unstemmed Concentrations and Water Mass Transport of Legacy POPs in the Arctic Ocean
title_short Concentrations and Water Mass Transport of Legacy POPs in the Arctic Ocean
title_sort concentrations and water mass transport of legacy pops in the arctic ocean
topic legacy POPs
Arctic
Fram Strait
passive sampler
vertical profiles
mass transport
url https://doi.org/10.1029/2018GL078759
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