Bioinorganic Relevance of Some Cobalt(II) Complexes with Thiophene-2-glyoxal Derived Schiff Bases
Complexes of Co(II) with two new Schiff bases TEAB [2-hydroxy-4-{[2-oxo-2-(thiophen-2-yl)ethylidene]amino}benzoic acid] and TEPC [N-[2-oxo-2-(thiophen-2-yl)ethylidene]pyridine-3-carboxamide] have been synthesized and characterized with the help of elemental analysis, magnetic, mass, 1H-NMR, 13C-NMR,...
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| Format: | Article |
| Language: | English |
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Wiley
2009-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2009/801345 |
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| author | Prashant Singh Shanu Das Rajesh Dhakarey |
| author_facet | Prashant Singh Shanu Das Rajesh Dhakarey |
| author_sort | Prashant Singh |
| collection | DOAJ |
| description | Complexes of Co(II) with two new Schiff bases TEAB [2-hydroxy-4-{[2-oxo-2-(thiophen-2-yl)ethylidene]amino}benzoic acid] and TEPC [N-[2-oxo-2-(thiophen-2-yl)ethylidene]pyridine-3-carboxamide] have been synthesized and characterized with the help of elemental analysis, magnetic, mass, 1H-NMR, 13C-NMR, IR and electronic spectral data. IR spectra manifest the coordination of the ligand to the metal ion through the carbonyl oxygen, azomethine nitrogen and thienyl sulphur atoms. With the help of electronic spectral data various ligand field parameters were also calculated. All these studies reveal the distorted octahedral Co(II) complexes. Synthesized compounds have also been screened against some micro organisms viz, Escherichia coli, Proteus vulgaris, Aspergillus niger and Aspergillus flavus with the help of ‘filter paper disc’ technique. It has been observed that the antimicrobial activities of metal complexes are higher than that of the free ligand. |
| format | Article |
| id | doaj-art-0fd5a451a43c47fd95ef7e7e10bf53b0 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2009-01-01 |
| publisher | Wiley |
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| series | E-Journal of Chemistry |
| spelling | doaj-art-0fd5a451a43c47fd95ef7e7e10bf53b02025-02-03T05:44:28ZengWileyE-Journal of Chemistry0973-49452090-98102009-01-01619910510.1155/2009/801345Bioinorganic Relevance of Some Cobalt(II) Complexes with Thiophene-2-glyoxal Derived Schiff BasesPrashant Singh0Shanu Das1Rajesh Dhakarey2Department of Chemistry, Institute of Basic Science, Dr. B.R.A. University, Agra-282005, Uttar Pradesh, IndiaDepartment of Chemistry, Institute of Basic Science, Dr. B.R.A. University, Agra-282005, Uttar Pradesh, IndiaDepartment of Chemistry, Institute of Basic Science, Dr. B.R.A. University, Agra-282005, Uttar Pradesh, IndiaComplexes of Co(II) with two new Schiff bases TEAB [2-hydroxy-4-{[2-oxo-2-(thiophen-2-yl)ethylidene]amino}benzoic acid] and TEPC [N-[2-oxo-2-(thiophen-2-yl)ethylidene]pyridine-3-carboxamide] have been synthesized and characterized with the help of elemental analysis, magnetic, mass, 1H-NMR, 13C-NMR, IR and electronic spectral data. IR spectra manifest the coordination of the ligand to the metal ion through the carbonyl oxygen, azomethine nitrogen and thienyl sulphur atoms. With the help of electronic spectral data various ligand field parameters were also calculated. All these studies reveal the distorted octahedral Co(II) complexes. Synthesized compounds have also been screened against some micro organisms viz, Escherichia coli, Proteus vulgaris, Aspergillus niger and Aspergillus flavus with the help of ‘filter paper disc’ technique. It has been observed that the antimicrobial activities of metal complexes are higher than that of the free ligand.http://dx.doi.org/10.1155/2009/801345 |
| spellingShingle | Prashant Singh Shanu Das Rajesh Dhakarey Bioinorganic Relevance of Some Cobalt(II) Complexes with Thiophene-2-glyoxal Derived Schiff Bases E-Journal of Chemistry |
| title | Bioinorganic Relevance of Some Cobalt(II) Complexes with Thiophene-2-glyoxal Derived Schiff Bases |
| title_full | Bioinorganic Relevance of Some Cobalt(II) Complexes with Thiophene-2-glyoxal Derived Schiff Bases |
| title_fullStr | Bioinorganic Relevance of Some Cobalt(II) Complexes with Thiophene-2-glyoxal Derived Schiff Bases |
| title_full_unstemmed | Bioinorganic Relevance of Some Cobalt(II) Complexes with Thiophene-2-glyoxal Derived Schiff Bases |
| title_short | Bioinorganic Relevance of Some Cobalt(II) Complexes with Thiophene-2-glyoxal Derived Schiff Bases |
| title_sort | bioinorganic relevance of some cobalt ii complexes with thiophene 2 glyoxal derived schiff bases |
| url | http://dx.doi.org/10.1155/2009/801345 |
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