A Study on Physical Performance for Poly(L-lactic acid) in Addition to Layered Strontium Phenylphosphonate

The organic-inorganic hybrid layered strontium phenylphosphonate (SrP) was synthesized by using strontium chloride and phenylphosphinic acid. And the influence of layered SrP on the crystallization behavior and thermal stability of poly(L-lactic acid) (PLLA) was investigated through DSC, XRD, and TG...

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Main Authors: Yan-Hua Zhang, Yan-Hua Cai
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2016/3926876
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author Yan-Hua Zhang
Yan-Hua Cai
author_facet Yan-Hua Zhang
Yan-Hua Cai
author_sort Yan-Hua Zhang
collection DOAJ
description The organic-inorganic hybrid layered strontium phenylphosphonate (SrP) was synthesized by using strontium chloride and phenylphosphinic acid. And the influence of layered SrP on the crystallization behavior and thermal stability of poly(L-lactic acid) (PLLA) was investigated through DSC, XRD, and TGA. Both DSC and XRD results demonstrated that layered SrP had the powerful accelerated ability for PLLA crystallization, and in the range of studied concentration, 0.7 wt%–1 wt% is the optimum concentration range to achieve rapid crystallization of PLLA. Meantime, as a result, the increase of cooling rate in nonisothermal crystallization procedure seriously affected the crystallization accelerated efficiency of SrP. Thermal stability measurement showed that layered SrP could cause the onset decomposition temperature of PLLA to decrease, but the thermal decomposition behavior of PLLA hardly depended on the SrP concentration.
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institution Kabale University
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language English
publishDate 2016-01-01
publisher Wiley
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series International Journal of Polymer Science
spelling doaj-art-0fa77bad2c7e4dfeb192a316058710dd2025-02-03T01:26:22ZengWileyInternational Journal of Polymer Science1687-94221687-94302016-01-01201610.1155/2016/39268763926876A Study on Physical Performance for Poly(L-lactic acid) in Addition to Layered Strontium PhenylphosphonateYan-Hua Zhang0Yan-Hua Cai1Chongqing Key Laboratory of Environmental Materials & Remediation Technologies, Chongqing University of Arts and Sciences, Chongqing 402160, ChinaChongqing Key Laboratory of Environmental Materials & Remediation Technologies, Chongqing University of Arts and Sciences, Chongqing 402160, ChinaThe organic-inorganic hybrid layered strontium phenylphosphonate (SrP) was synthesized by using strontium chloride and phenylphosphinic acid. And the influence of layered SrP on the crystallization behavior and thermal stability of poly(L-lactic acid) (PLLA) was investigated through DSC, XRD, and TGA. Both DSC and XRD results demonstrated that layered SrP had the powerful accelerated ability for PLLA crystallization, and in the range of studied concentration, 0.7 wt%–1 wt% is the optimum concentration range to achieve rapid crystallization of PLLA. Meantime, as a result, the increase of cooling rate in nonisothermal crystallization procedure seriously affected the crystallization accelerated efficiency of SrP. Thermal stability measurement showed that layered SrP could cause the onset decomposition temperature of PLLA to decrease, but the thermal decomposition behavior of PLLA hardly depended on the SrP concentration.http://dx.doi.org/10.1155/2016/3926876
spellingShingle Yan-Hua Zhang
Yan-Hua Cai
A Study on Physical Performance for Poly(L-lactic acid) in Addition to Layered Strontium Phenylphosphonate
International Journal of Polymer Science
title A Study on Physical Performance for Poly(L-lactic acid) in Addition to Layered Strontium Phenylphosphonate
title_full A Study on Physical Performance for Poly(L-lactic acid) in Addition to Layered Strontium Phenylphosphonate
title_fullStr A Study on Physical Performance for Poly(L-lactic acid) in Addition to Layered Strontium Phenylphosphonate
title_full_unstemmed A Study on Physical Performance for Poly(L-lactic acid) in Addition to Layered Strontium Phenylphosphonate
title_short A Study on Physical Performance for Poly(L-lactic acid) in Addition to Layered Strontium Phenylphosphonate
title_sort study on physical performance for poly l lactic acid in addition to layered strontium phenylphosphonate
url http://dx.doi.org/10.1155/2016/3926876
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AT yanhuacai astudyonphysicalperformanceforpolyllacticacidinadditiontolayeredstrontiumphenylphosphonate
AT yanhuazhang studyonphysicalperformanceforpolyllacticacidinadditiontolayeredstrontiumphenylphosphonate
AT yanhuacai studyonphysicalperformanceforpolyllacticacidinadditiontolayeredstrontiumphenylphosphonate