SEPARATION OF DIFFRACTION SPECTRA BY PRINCIPAL COMPONENT METHOD BY THE EXAMPLE OF ARIFON DRUG

The article deals with the results of experimental studies on statistical processing of diffraction spectra of solid drugs for the purpose of their separation and identification. Diffractograms of the original and falsified drugs Arifon were used for the study. They were obtained on a desktop diffra...

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Main Authors: R. V. Chekhova, V. M. Pyshniy, L. A. Pyankova, V. A. Elokhin
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2019-02-01
Series:Российский технологический журнал
Subjects:
Online Access:https://www.rtj-mirea.ru/jour/article/view/143
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author R. V. Chekhova
V. M. Pyshniy
L. A. Pyankova
V. A. Elokhin
author_facet R. V. Chekhova
V. M. Pyshniy
L. A. Pyankova
V. A. Elokhin
author_sort R. V. Chekhova
collection DOAJ
description The article deals with the results of experimental studies on statistical processing of diffraction spectra of solid drugs for the purpose of their separation and identification. Diffractograms of the original and falsified drugs Arifon were used for the study. They were obtained on a desktop diffractometer Difray 401 produced by Scientific Instruments Inc. (Saint Petersburg, Russia). The research was conducted in the Scilab environment distributed under a free license. The captured diffraction spectra were processed using a smoothing procedure that eliminated the influence of a random component in the original data. Analysis of the results of smoothing by the moving average method showed that the smoothing algorithm with the window 41 point is most preferable. The results of statistical processing of diffractograms of the drugs investigated by the principal component analysis (PCA) in graphical and numerical form, which showed good convergence and efficiency of this method in the separation of diffraction spectra, are presented. The conducted studies make it possible to create a technique that allows identifying solid drugs by X-ray diffraction.
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institution DOAJ
issn 2782-3210
2500-316X
language Russian
publishDate 2019-02-01
publisher MIREA - Russian Technological University
record_format Article
series Российский технологический журнал
spelling doaj-art-0f888dce2ec74facb2d400d5514742872025-08-20T02:53:54ZrusMIREA - Russian Technological UniversityРоссийский технологический журнал2782-32102500-316X2019-02-017110211210.32362/2500-316X-2019-7-1-102-112143SEPARATION OF DIFFRACTION SPECTRA BY PRINCIPAL COMPONENT METHOD BY THE EXAMPLE OF ARIFON DRUGR. V. Chekhova0V. M. Pyshniy1L. A. Pyankova2V. A. Elokhin3MIREA - Russian Technological UniversityMIREA - Russian Technological UniversityScientific Instruments Inc.Scientific Instruments Inc.The article deals with the results of experimental studies on statistical processing of diffraction spectra of solid drugs for the purpose of their separation and identification. Diffractograms of the original and falsified drugs Arifon were used for the study. They were obtained on a desktop diffractometer Difray 401 produced by Scientific Instruments Inc. (Saint Petersburg, Russia). The research was conducted in the Scilab environment distributed under a free license. The captured diffraction spectra were processed using a smoothing procedure that eliminated the influence of a random component in the original data. Analysis of the results of smoothing by the moving average method showed that the smoothing algorithm with the window 41 point is most preferable. The results of statistical processing of diffractograms of the drugs investigated by the principal component analysis (PCA) in graphical and numerical form, which showed good convergence and efficiency of this method in the separation of diffraction spectra, are presented. The conducted studies make it possible to create a technique that allows identifying solid drugs by X-ray diffraction.https://www.rtj-mirea.ru/jour/article/view/143diffraction spectrumdrugprincipal component analysiseigenvalueeigenvector
spellingShingle R. V. Chekhova
V. M. Pyshniy
L. A. Pyankova
V. A. Elokhin
SEPARATION OF DIFFRACTION SPECTRA BY PRINCIPAL COMPONENT METHOD BY THE EXAMPLE OF ARIFON DRUG
Российский технологический журнал
diffraction spectrum
drug
principal component analysis
eigenvalue
eigenvector
title SEPARATION OF DIFFRACTION SPECTRA BY PRINCIPAL COMPONENT METHOD BY THE EXAMPLE OF ARIFON DRUG
title_full SEPARATION OF DIFFRACTION SPECTRA BY PRINCIPAL COMPONENT METHOD BY THE EXAMPLE OF ARIFON DRUG
title_fullStr SEPARATION OF DIFFRACTION SPECTRA BY PRINCIPAL COMPONENT METHOD BY THE EXAMPLE OF ARIFON DRUG
title_full_unstemmed SEPARATION OF DIFFRACTION SPECTRA BY PRINCIPAL COMPONENT METHOD BY THE EXAMPLE OF ARIFON DRUG
title_short SEPARATION OF DIFFRACTION SPECTRA BY PRINCIPAL COMPONENT METHOD BY THE EXAMPLE OF ARIFON DRUG
title_sort separation of diffraction spectra by principal component method by the example of arifon drug
topic diffraction spectrum
drug
principal component analysis
eigenvalue
eigenvector
url https://www.rtj-mirea.ru/jour/article/view/143
work_keys_str_mv AT rvchekhova separationofdiffractionspectrabyprincipalcomponentmethodbytheexampleofarifondrug
AT vmpyshniy separationofdiffractionspectrabyprincipalcomponentmethodbytheexampleofarifondrug
AT lapyankova separationofdiffractionspectrabyprincipalcomponentmethodbytheexampleofarifondrug
AT vaelokhin separationofdiffractionspectrabyprincipalcomponentmethodbytheexampleofarifondrug