High Resistivity of Single Crystal CsPbBr3 Semiconductor for Radiation Detection via Proposed Temperature‐Concentration Balance Method

High Resistivity of Single Crystal CsPbBr3 Semiconductor for Radiation Detection via Proposed Temperature‐Concentration Balance Method

Abstract Lead halide perovskites have shown high performance in radiation detection techniques owing to their excellent optoelectronic properties and stability. However, the high resistivity of the CsPbBr3 radiation detector is intensively dependent on the growth quality of the single crystal, which...

Full description

Saved in:
Bibliographic Details
Main Authors: Xuebao Zhang, Qingbo Wang, Ying Gao, Junying Zhang, Youpeng Wu, Peijie Ma, Lin Ma, Jianing Cai, Fenglei Niu, Qiang Zhao, Yunchao Tang, Junwei Bian, Chenming Liang, Chunxia Shen, Zeqian Wu, Fang Liu, Zhiling Hou, Jinxing Cheng
Format: Article
Language:English
Published: Wiley-VCH 2025-07-01
Series:Advanced Electronic Materials
Subjects:
CsPbBr3
radiation detector
single crystal growth
temperature‐concentration balance
Online Access:https://doi.org/10.1002/aelm.202400972
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Abstract Lead halide perovskites have shown high performance in radiation detection techniques owing to their excellent optoelectronic properties and stability. However, the high resistivity of the CsPbBr3 radiation detector is intensively dependent on the growth quality of the single crystal, which is closely related to temperature gradients or the introduction of additives. Herein, a CsPbBr3 single crystal with high radiation performance is grown based on the proposed temperature‐concentration balance (TCB) method. The prepared perfect single crystal remains high quality in repeated experiments, which belongs to the Pnma space group, benefiting from the effective growth method. Based on the CsPbBr3 single crystal, the fabricated detector with the asymmetrical Au‐In electrodes demonstrates outstanding linearity under reverse bias. It exhibits a lower dark current (2.66 × 10−2 nA) and high resistivity, which helps acquire a broader radiation measurement range. Moreover, the emission spectrum of the CsPbBr3 single crystals exhibits a sharp emission peak at 527 nm and narrower full width at half maximum, making crystals easily couple into radiation detectors. These findings provide insight into the growth and regulation of CsPbBr3 crystal for more extensive applications in radiation detection in the future.
ISSN:2199-160X

Similar Items