Highly Efficient Organic UV Photodetectors Based on Polyfluorene and Naphthalenediimide Blends: Effect of Thermal Annealing

A solution-processed organic ultraviolet photodetector (UV-PD) is introduced. The active layer of the UV-PD consists of poly(9,9-dioctyl fluorenyl-2,7–yleneethynylene) (PFE) and N,N′-bis-n-butyl-1,4,5,8- naphthalenediimide (BNDI) with a weight ratio of 3 : 1 in chloroform. The effect of thermal anne...

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Main Authors: Gorkem Memisoglu, Canan Varlikli
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2012/936075
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author Gorkem Memisoglu
Canan Varlikli
author_facet Gorkem Memisoglu
Canan Varlikli
author_sort Gorkem Memisoglu
collection DOAJ
description A solution-processed organic ultraviolet photodetector (UV-PD) is introduced. The active layer of the UV-PD consists of poly(9,9-dioctyl fluorenyl-2,7–yleneethynylene) (PFE) and N,N′-bis-n-butyl-1,4,5,8- naphthalenediimide (BNDI) with a weight ratio of 3 : 1 in chloroform. The effect of thermal annealing on the device properties was investigated from room temperature to 80∘C. The full device structure of ITO/PEDOT:PSS/PFE:BNDI (3 : 1)/Al gave responsivity of 410 mA/W at −4 V under 1 mW/cm2 UV light at 368 nm when 60∘C of annealing temperature was used during its preparation. The devices that were annealed over the crystallization temperature of PFE showed a charge transfer resistance increase and a mobility decrease.
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series International Journal of Photoenergy
spelling doaj-art-0e68cfcc52a543538ba2da8ec089a1492025-08-20T03:17:19ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2012-01-01201210.1155/2012/936075936075Highly Efficient Organic UV Photodetectors Based on Polyfluorene and Naphthalenediimide Blends: Effect of Thermal AnnealingGorkem Memisoglu0Canan Varlikli1Solar Energy Institute, Ege University, Izmir, 35100 Bornova, TurkeySolar Energy Institute, Ege University, Izmir, 35100 Bornova, TurkeyA solution-processed organic ultraviolet photodetector (UV-PD) is introduced. The active layer of the UV-PD consists of poly(9,9-dioctyl fluorenyl-2,7–yleneethynylene) (PFE) and N,N′-bis-n-butyl-1,4,5,8- naphthalenediimide (BNDI) with a weight ratio of 3 : 1 in chloroform. The effect of thermal annealing on the device properties was investigated from room temperature to 80∘C. The full device structure of ITO/PEDOT:PSS/PFE:BNDI (3 : 1)/Al gave responsivity of 410 mA/W at −4 V under 1 mW/cm2 UV light at 368 nm when 60∘C of annealing temperature was used during its preparation. The devices that were annealed over the crystallization temperature of PFE showed a charge transfer resistance increase and a mobility decrease.http://dx.doi.org/10.1155/2012/936075
spellingShingle Gorkem Memisoglu
Canan Varlikli
Highly Efficient Organic UV Photodetectors Based on Polyfluorene and Naphthalenediimide Blends: Effect of Thermal Annealing
International Journal of Photoenergy
title Highly Efficient Organic UV Photodetectors Based on Polyfluorene and Naphthalenediimide Blends: Effect of Thermal Annealing
title_full Highly Efficient Organic UV Photodetectors Based on Polyfluorene and Naphthalenediimide Blends: Effect of Thermal Annealing
title_fullStr Highly Efficient Organic UV Photodetectors Based on Polyfluorene and Naphthalenediimide Blends: Effect of Thermal Annealing
title_full_unstemmed Highly Efficient Organic UV Photodetectors Based on Polyfluorene and Naphthalenediimide Blends: Effect of Thermal Annealing
title_short Highly Efficient Organic UV Photodetectors Based on Polyfluorene and Naphthalenediimide Blends: Effect of Thermal Annealing
title_sort highly efficient organic uv photodetectors based on polyfluorene and naphthalenediimide blends effect of thermal annealing
url http://dx.doi.org/10.1155/2012/936075
work_keys_str_mv AT gorkemmemisoglu highlyefficientorganicuvphotodetectorsbasedonpolyfluoreneandnaphthalenediimideblendseffectofthermalannealing
AT cananvarlikli highlyefficientorganicuvphotodetectorsbasedonpolyfluoreneandnaphthalenediimideblendseffectofthermalannealing