Straightforward Superbase-Mediated Reductive O-Phosphorylation of Aromatic and Heteroaromatic Ketones with Red Phosphorus in the Superbase Suspension KOH/DMSO(H<sub>2</sub>O)

Straightforward Superbase-Mediated Reductive O-Phosphorylation of Aromatic and Heteroaromatic Ketones with Red Phosphorus in the Superbase Suspension KOH/DMSO(H<sub>2</sub>O)

It was shown for the first time that diaryl(hetaryl)ketones are capable of directly phosphorylating with red phosphorus in the superbase suspension KOH/DMSO(H<sub>2</sub>O) at 85 °C for 1.5 h to afford potassium bis(diaryl(hetaryl)methyl)phosphates that were earlier inaccessible in a yie...

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Bibliographic Details
Main Authors: Vladimir A. Kuimov, Svetlana F. Malysheva, Natalia A. Belogorlova, Ruslan I. Fattakhov, Alexander I. Albanov, Irina Yu. Bagryanskaya, Nikolay I. Tikhonov, Boris A. Trofimov
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Molecules
Subjects:
red phosphorus
strong base
bis(benzhydryl)phosphates
benzophenone
single-electron transfer
Online Access:https://www.mdpi.com/1420-3049/30/6/1367
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