Progress in ZnO Acceptor Doping: What Is the Best Strategy?

This paper reviews the recent progress in acceptor doping of ZnO that has been achieved with a focus toward the optimum strategy. There are three main approaches for generating p-type ZnO: substitutional group IA elements on a zinc site, codoping of donors and acceptors, and substitution of group VA...

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Main Authors: Judith G. Reynolds, C. Lewis Reynolds
Format: Article
Language:English
Published: Wiley 2014-01-01
Series:Advances in Condensed Matter Physics
Online Access:http://dx.doi.org/10.1155/2014/457058
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author Judith G. Reynolds
C. Lewis Reynolds
author_facet Judith G. Reynolds
C. Lewis Reynolds
author_sort Judith G. Reynolds
collection DOAJ
description This paper reviews the recent progress in acceptor doping of ZnO that has been achieved with a focus toward the optimum strategy. There are three main approaches for generating p-type ZnO: substitutional group IA elements on a zinc site, codoping of donors and acceptors, and substitution of group VA elements on an oxygen site. The relevant issues are whether there is sufficient incorporation of the appropriate dopant impurity species, does it reside on the appropriate lattice site, and lastly whether the acceptor ionization energy is sufficiently small to enable significant p-type conduction at room temperature. The potential of nitrogen doping and formation of the appropriate acceptor complexes is highlighted although theoretical calculations predict that nitrogen on an oxygen site is a deep acceptor. We show that an understanding of the growth and annealing steps to achieve the relevant acceptor defect complexes is crucial to meet requirements.
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spelling doaj-art-0cce96916af14b1e8447ff74fc0f16822025-08-20T02:03:01ZengWileyAdvances in Condensed Matter Physics1687-81081687-81242014-01-01201410.1155/2014/457058457058Progress in ZnO Acceptor Doping: What Is the Best Strategy?Judith G. Reynolds0C. Lewis Reynolds1Department of Physics, North Carolina State University, Raleigh, NC 27695, USADepartment of Materials Science and Engineering, North Carolina State University, Raleigh, NC 27695, USAThis paper reviews the recent progress in acceptor doping of ZnO that has been achieved with a focus toward the optimum strategy. There are three main approaches for generating p-type ZnO: substitutional group IA elements on a zinc site, codoping of donors and acceptors, and substitution of group VA elements on an oxygen site. The relevant issues are whether there is sufficient incorporation of the appropriate dopant impurity species, does it reside on the appropriate lattice site, and lastly whether the acceptor ionization energy is sufficiently small to enable significant p-type conduction at room temperature. The potential of nitrogen doping and formation of the appropriate acceptor complexes is highlighted although theoretical calculations predict that nitrogen on an oxygen site is a deep acceptor. We show that an understanding of the growth and annealing steps to achieve the relevant acceptor defect complexes is crucial to meet requirements.http://dx.doi.org/10.1155/2014/457058
spellingShingle Judith G. Reynolds
C. Lewis Reynolds
Progress in ZnO Acceptor Doping: What Is the Best Strategy?
Advances in Condensed Matter Physics
title Progress in ZnO Acceptor Doping: What Is the Best Strategy?
title_full Progress in ZnO Acceptor Doping: What Is the Best Strategy?
title_fullStr Progress in ZnO Acceptor Doping: What Is the Best Strategy?
title_full_unstemmed Progress in ZnO Acceptor Doping: What Is the Best Strategy?
title_short Progress in ZnO Acceptor Doping: What Is the Best Strategy?
title_sort progress in zno acceptor doping what is the best strategy
url http://dx.doi.org/10.1155/2014/457058
work_keys_str_mv AT judithgreynolds progressinznoacceptordopingwhatisthebeststrategy
AT clewisreynolds progressinznoacceptordopingwhatisthebeststrategy