Effects of AlN addition on the reactive sintering behavior and comprehensive properties of h-BN/ZrO2 composites prepared by spark plasma sintering
The h-BN/ZrO2 composites for preparing ceramic side sealing plate were obtained with spark plasma sintering (SPS) at 1700 °C for 10 min in the study. By varying AlN content from 0 to 20 wt%, we systematically explored its influence on sintering behavior, microstructure evolution, mechanical performa...
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2025-06-01
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| Series: | Materials & Design |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S0264127525004617 |
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| Summary: | The h-BN/ZrO2 composites for preparing ceramic side sealing plate were obtained with spark plasma sintering (SPS) at 1700 °C for 10 min in the study. By varying AlN content from 0 to 20 wt%, we systematically explored its influence on sintering behavior, microstructure evolution, mechanical performance, and corrosion mechanism at1600 °C. Results show that the rapid heating and uniaxial pressure during SPS and the in-situ reactions between AlN and ZrO2 promoted the densification of composites. The main reaction products were ZrN, which acted as an effective oxygen scavenger, consuming dissolved oxygen ([O]) and converting into ZrO2. These newly formed ZrO2 particles filled residual porosity within the matrix and nucleated around pre-existing ZrO2 grains, progressively coalescing into continuous Zr-rich barrier layer.Thereby preventing molten steel from further penetrating into the matrix. The corrosion depth of the composite with 5 wt% AlN content in molten steel at 1600 °C after 2 h was only 69 μm. Meanwhile, it showed a thermal conductivity of 25 W m−1 K−1 and a coefficient of thermal expansion of 3.7 × 10-6 K−1, demonstrating excellent thermal shock resistance. The composites are expected to be used to manufacture side sealing plates for the novel continuous casting of thin strip. |
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| ISSN: | 0264-1275 |