Engineering and Optimization of Stable 2-Dimensional MXene-Based Nanofluid for Direct Absorption Photothermal Energy Conversion

The world is striving to design renewable energy systems to reduce reliance on finite fossil fuels and minimize environmental impacts. Photothermal nanofluids (NFs) in solar energy harvesting center on achieving a delicate balance between effective solar absorption, light-to-heat thermal conversion,...

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Main Authors: Shoaib Anwer, Anas Alazzam, Eiyad Abu–Nada
Format: Article
Language:English
Published: American Association for the Advancement of Science (AAAS) 2025-01-01
Series:Energy Material Advances
Online Access:https://spj.science.org/doi/10.34133/energymatadv.0153
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author Shoaib Anwer
Anas Alazzam
Eiyad Abu–Nada
author_facet Shoaib Anwer
Anas Alazzam
Eiyad Abu–Nada
author_sort Shoaib Anwer
collection DOAJ
description The world is striving to design renewable energy systems to reduce reliance on finite fossil fuels and minimize environmental impacts. Photothermal nanofluids (NFs) in solar energy harvesting center on achieving a delicate balance between effective solar absorption, light-to-heat thermal conversion, dispersion stability, and viscosity. This study focuses on the formulation of high-performance stable NFs by incorporating different mass fractions of sodium ascorbate-treated ultrathin 2-dimensional (2D) Ti3C2Tx MXene nanosheets (SA-TMS) in ethylene glycol (EG) base fluid. Optical and photothermal characterization of the NF, including dispersion, suspension stability, viscosity, and photothermal conversion, were thoroughly examined for the prepared series. Interestingly, compared to pure EG, adding 0.0018 wt % of SA-TMS improved the photothermal performance of EG by 68.73%, credited to the large extinction coefficient of 64.4 l/(g·cm) and localized surface plasmon resonance effect of high conductive ultrathin SA-TMS nanosheets. Furthermore, the optimized SA-TMS/EGo NF was semitransparent with a minimum effective viscosity of 18.88 mPa·s because of its exceptional self-lubricating properties. In addition to having a good cycling life, the recruited SA-TMS/EG NFs showed no signs of sedimentation after 90 d and showed promising shelf stability. Furthermore, the photothermal conversion performance study proved that large-size 2D sheets are more efficient than smaller-size sheets. This comprehensive study opens an exciting regime to design stable and efficient 2D material-based NFs for direct solar energy harvesting, leveraging their enhanced thermal conductivity and optically semitransparent nature.
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spelling doaj-art-0cb2cc7ed9f2432ebf7162a08e626fdc2025-08-20T02:12:41ZengAmerican Association for the Advancement of Science (AAAS)Energy Material Advances2692-76402025-01-01610.34133/energymatadv.0153Engineering and Optimization of Stable 2-Dimensional MXene-Based Nanofluid for Direct Absorption Photothermal Energy ConversionShoaib Anwer0Anas Alazzam1Eiyad Abu–Nada2Department of Mechanical & Nuclear Engineering, Khalifa University of Science and Technology, Abu Dhabi 127788, UAE.Department of Mechanical & Nuclear Engineering, Khalifa University of Science and Technology, Abu Dhabi 127788, UAE.Department of Mechanical & Nuclear Engineering, Khalifa University of Science and Technology, Abu Dhabi 127788, UAE.The world is striving to design renewable energy systems to reduce reliance on finite fossil fuels and minimize environmental impacts. Photothermal nanofluids (NFs) in solar energy harvesting center on achieving a delicate balance between effective solar absorption, light-to-heat thermal conversion, dispersion stability, and viscosity. This study focuses on the formulation of high-performance stable NFs by incorporating different mass fractions of sodium ascorbate-treated ultrathin 2-dimensional (2D) Ti3C2Tx MXene nanosheets (SA-TMS) in ethylene glycol (EG) base fluid. Optical and photothermal characterization of the NF, including dispersion, suspension stability, viscosity, and photothermal conversion, were thoroughly examined for the prepared series. Interestingly, compared to pure EG, adding 0.0018 wt % of SA-TMS improved the photothermal performance of EG by 68.73%, credited to the large extinction coefficient of 64.4 l/(g·cm) and localized surface plasmon resonance effect of high conductive ultrathin SA-TMS nanosheets. Furthermore, the optimized SA-TMS/EGo NF was semitransparent with a minimum effective viscosity of 18.88 mPa·s because of its exceptional self-lubricating properties. In addition to having a good cycling life, the recruited SA-TMS/EG NFs showed no signs of sedimentation after 90 d and showed promising shelf stability. Furthermore, the photothermal conversion performance study proved that large-size 2D sheets are more efficient than smaller-size sheets. This comprehensive study opens an exciting regime to design stable and efficient 2D material-based NFs for direct solar energy harvesting, leveraging their enhanced thermal conductivity and optically semitransparent nature.https://spj.science.org/doi/10.34133/energymatadv.0153
spellingShingle Shoaib Anwer
Anas Alazzam
Eiyad Abu–Nada
Engineering and Optimization of Stable 2-Dimensional MXene-Based Nanofluid for Direct Absorption Photothermal Energy Conversion
Energy Material Advances
title Engineering and Optimization of Stable 2-Dimensional MXene-Based Nanofluid for Direct Absorption Photothermal Energy Conversion
title_full Engineering and Optimization of Stable 2-Dimensional MXene-Based Nanofluid for Direct Absorption Photothermal Energy Conversion
title_fullStr Engineering and Optimization of Stable 2-Dimensional MXene-Based Nanofluid for Direct Absorption Photothermal Energy Conversion
title_full_unstemmed Engineering and Optimization of Stable 2-Dimensional MXene-Based Nanofluid for Direct Absorption Photothermal Energy Conversion
title_short Engineering and Optimization of Stable 2-Dimensional MXene-Based Nanofluid for Direct Absorption Photothermal Energy Conversion
title_sort engineering and optimization of stable 2 dimensional mxene based nanofluid for direct absorption photothermal energy conversion
url https://spj.science.org/doi/10.34133/energymatadv.0153
work_keys_str_mv AT shoaibanwer engineeringandoptimizationofstable2dimensionalmxenebasednanofluidfordirectabsorptionphotothermalenergyconversion
AT anasalazzam engineeringandoptimizationofstable2dimensionalmxenebasednanofluidfordirectabsorptionphotothermalenergyconversion
AT eiyadabunada engineeringandoptimizationofstable2dimensionalmxenebasednanofluidfordirectabsorptionphotothermalenergyconversion