Multianalysis Characterization of Mineralogical Properties of Copper-Lead-Zinc Mixed Ores and Implications for Comprehensive Recovery

Copper-lead-zinc mixed ore in Tibet, China, is a complex and refractory polymetallic ore resource; thus, ascertaining its mineralogical properties is very important for comprehensive recovery of valuable elements. In this work, the mineralogical properties of this copper-lead-zinc mixed ore have bee...

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Main Authors: Qian Zhang, Shuming Wen, Qicheng Feng, Song Zhang, Wenlin Nie
Format: Article
Language:English
Published: Wiley 2020-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2020/2804924
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author Qian Zhang
Shuming Wen
Qicheng Feng
Song Zhang
Wenlin Nie
author_facet Qian Zhang
Shuming Wen
Qicheng Feng
Song Zhang
Wenlin Nie
author_sort Qian Zhang
collection DOAJ
description Copper-lead-zinc mixed ore in Tibet, China, is a complex and refractory polymetallic ore resource; thus, ascertaining its mineralogical properties is very important for comprehensive recovery of valuable elements. In this work, the mineralogical properties of this copper-lead-zinc mixed ore have been characterized in detail following a multidisciplinary approach, including chemical, phase, x-ray diffraction (XRD), electron microprobe, and mineral liberation analyses. The results show that the raw ore contained 0.53% Cu, 1.29% Pb, and 0.54% Zn; the oxidation rates of copper, lead, and zinc were 40.21%, 79.31%, and 84.83%, respectively. The Au and Ag contents in the raw ore were 0.28 g/t and 23.6 g/t, which can be comprehensively utilized along with the recovery of copper, lead, and zinc. The gangue mainly contained SiO2, CaO, and Al2O3. Copper in the raw ore mainly existed in bornite, duftite, chalcopyrite, and chrysocolla; lead mainly existed in cerussite, duftite, and galena; zinc mainly existed in willemite, hemimorphite, and sphalerite. The complexity in the embedding and wrapping relationships, fine-grained dissemination, high oxidation, and considerable differences in the floatability of various minerals result in difficulties in recovering the target minerals using a single method. Based on the systematic mineralogical properties obtained, an integrated technology of “bulk flotation-oxidation roasting-hydrometallurgy” has been proposed to enrich and separate copper, lead, and zinc in the ore, providing new ideas for the comprehensive and efficient utilization of polymetallic mineral resources in Tibet.
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spelling doaj-art-0caeb61708044e699bd9217381875cab2025-02-03T01:00:18ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422020-01-01202010.1155/2020/28049242804924Multianalysis Characterization of Mineralogical Properties of Copper-Lead-Zinc Mixed Ores and Implications for Comprehensive RecoveryQian Zhang0Shuming Wen1Qicheng Feng2Song Zhang3Wenlin Nie4State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaState Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaState Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaKunming Natural Resources Survey Center, China Geological Survey, Kunming 650100, ChinaState Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaCopper-lead-zinc mixed ore in Tibet, China, is a complex and refractory polymetallic ore resource; thus, ascertaining its mineralogical properties is very important for comprehensive recovery of valuable elements. In this work, the mineralogical properties of this copper-lead-zinc mixed ore have been characterized in detail following a multidisciplinary approach, including chemical, phase, x-ray diffraction (XRD), electron microprobe, and mineral liberation analyses. The results show that the raw ore contained 0.53% Cu, 1.29% Pb, and 0.54% Zn; the oxidation rates of copper, lead, and zinc were 40.21%, 79.31%, and 84.83%, respectively. The Au and Ag contents in the raw ore were 0.28 g/t and 23.6 g/t, which can be comprehensively utilized along with the recovery of copper, lead, and zinc. The gangue mainly contained SiO2, CaO, and Al2O3. Copper in the raw ore mainly existed in bornite, duftite, chalcopyrite, and chrysocolla; lead mainly existed in cerussite, duftite, and galena; zinc mainly existed in willemite, hemimorphite, and sphalerite. The complexity in the embedding and wrapping relationships, fine-grained dissemination, high oxidation, and considerable differences in the floatability of various minerals result in difficulties in recovering the target minerals using a single method. Based on the systematic mineralogical properties obtained, an integrated technology of “bulk flotation-oxidation roasting-hydrometallurgy” has been proposed to enrich and separate copper, lead, and zinc in the ore, providing new ideas for the comprehensive and efficient utilization of polymetallic mineral resources in Tibet.http://dx.doi.org/10.1155/2020/2804924
spellingShingle Qian Zhang
Shuming Wen
Qicheng Feng
Song Zhang
Wenlin Nie
Multianalysis Characterization of Mineralogical Properties of Copper-Lead-Zinc Mixed Ores and Implications for Comprehensive Recovery
Advances in Materials Science and Engineering
title Multianalysis Characterization of Mineralogical Properties of Copper-Lead-Zinc Mixed Ores and Implications for Comprehensive Recovery
title_full Multianalysis Characterization of Mineralogical Properties of Copper-Lead-Zinc Mixed Ores and Implications for Comprehensive Recovery
title_fullStr Multianalysis Characterization of Mineralogical Properties of Copper-Lead-Zinc Mixed Ores and Implications for Comprehensive Recovery
title_full_unstemmed Multianalysis Characterization of Mineralogical Properties of Copper-Lead-Zinc Mixed Ores and Implications for Comprehensive Recovery
title_short Multianalysis Characterization of Mineralogical Properties of Copper-Lead-Zinc Mixed Ores and Implications for Comprehensive Recovery
title_sort multianalysis characterization of mineralogical properties of copper lead zinc mixed ores and implications for comprehensive recovery
url http://dx.doi.org/10.1155/2020/2804924
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