Visible Light-Driven Direct Z-Scheme Ho<sub>2</sub>SmSbO<sub>7</sub>/YbDyBiNbO<sub>7</sub> Heterojunction Photocatalyst for Efficient Degradation of Fenitrothion
A highly versatile Z-scheme heterostructure, Ho<sub>2</sub>SmSbO<sub>7</sub>/YbDyBiNbO<sub>7</sub> (HYO), was synthesized using an ultrasonic-assisted solvent thermal method. The HYO heterojunction, composed of dual A<sub>2</sub>B<sub>2</sub&g...
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2024-12-01
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| author | Liang Hao Jingfei Luan |
| author_facet | Liang Hao Jingfei Luan |
| author_sort | Liang Hao |
| collection | DOAJ |
| description | A highly versatile Z-scheme heterostructure, Ho<sub>2</sub>SmSbO<sub>7</sub>/YbDyBiNbO<sub>7</sub> (HYO), was synthesized using an ultrasonic-assisted solvent thermal method. The HYO heterojunction, composed of dual A<sub>2</sub>B<sub>2</sub>O<sub>7</sub> compounds, exhibits superior separation of photogenerated carriers due to its efficient Z-scheme mechanism. The synergistic properties of Ho<sub>2</sub>SmSbO<sub>7</sub> and YbDyBiNbO<sub>7</sub>, particularly the excellent visible light absorption, enable HYO to achieve exceptional photocatalytic performance in the degradation of fenitrothion (FNT). Specifically, HYO demonstrated an outstanding removal efficiency of 99.83% for FNT and a mineralization rate of 98.77% for total organic carbon (TOC) during the degradation process. Comparative analyses revealed that HYO significantly outperformed other photocatalysts, including Ho<sub>2</sub>SmSbO<sub>7</sub>, YbDyBiNbO<sub>7</sub>, and N-doped TiO<sub>2</sub>, achieving removal rates that were 1.10, 1.20, and 2.97 times higher for FNT, respectively. For TOC mineralization, HYO exhibited even greater enhancements, with rates 1.13, 1.26, and 3.37 times higher than those of the aforementioned catalysts. Additionally, the stability and durability of HYO were systematically evaluated, confirming its potential applicability in practical scenarios. Trapping experiments and electron paramagnetic resonance analyses were conducted to identify the active species generated by HYO, specifically hydroxyl radicals (•OH), superoxide anions (•O<sub>2</sub><sup>−</sup>), and holes (h<sup>+</sup>). This facilitated a comprehensive understanding of the degradation mechanisms and pathways associated with FNT. In conclusion, this study represents a substantial contribution to the advancement of efficient Z-scheme heterostructure and offers critical insights for the development of sustainable remediation approaches aimed at mitigating FNT contamination. |
| format | Article |
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| institution | DOAJ |
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| publishDate | 2024-12-01 |
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| spelling | doaj-art-0c810e36da534e5a93d46a06dea6adc22025-08-20T02:51:07ZengMDPI AGMolecules1420-30492024-12-012924593010.3390/molecules29245930Visible Light-Driven Direct Z-Scheme Ho<sub>2</sub>SmSbO<sub>7</sub>/YbDyBiNbO<sub>7</sub> Heterojunction Photocatalyst for Efficient Degradation of FenitrothionLiang Hao0Jingfei Luan1School of Physics, Changchun Normal University, Changchun 130032, ChinaSchool of Physics, Changchun Normal University, Changchun 130032, ChinaA highly versatile Z-scheme heterostructure, Ho<sub>2</sub>SmSbO<sub>7</sub>/YbDyBiNbO<sub>7</sub> (HYO), was synthesized using an ultrasonic-assisted solvent thermal method. The HYO heterojunction, composed of dual A<sub>2</sub>B<sub>2</sub>O<sub>7</sub> compounds, exhibits superior separation of photogenerated carriers due to its efficient Z-scheme mechanism. The synergistic properties of Ho<sub>2</sub>SmSbO<sub>7</sub> and YbDyBiNbO<sub>7</sub>, particularly the excellent visible light absorption, enable HYO to achieve exceptional photocatalytic performance in the degradation of fenitrothion (FNT). Specifically, HYO demonstrated an outstanding removal efficiency of 99.83% for FNT and a mineralization rate of 98.77% for total organic carbon (TOC) during the degradation process. Comparative analyses revealed that HYO significantly outperformed other photocatalysts, including Ho<sub>2</sub>SmSbO<sub>7</sub>, YbDyBiNbO<sub>7</sub>, and N-doped TiO<sub>2</sub>, achieving removal rates that were 1.10, 1.20, and 2.97 times higher for FNT, respectively. For TOC mineralization, HYO exhibited even greater enhancements, with rates 1.13, 1.26, and 3.37 times higher than those of the aforementioned catalysts. Additionally, the stability and durability of HYO were systematically evaluated, confirming its potential applicability in practical scenarios. Trapping experiments and electron paramagnetic resonance analyses were conducted to identify the active species generated by HYO, specifically hydroxyl radicals (•OH), superoxide anions (•O<sub>2</sub><sup>−</sup>), and holes (h<sup>+</sup>). This facilitated a comprehensive understanding of the degradation mechanisms and pathways associated with FNT. In conclusion, this study represents a substantial contribution to the advancement of efficient Z-scheme heterostructure and offers critical insights for the development of sustainable remediation approaches aimed at mitigating FNT contamination.https://www.mdpi.com/1420-3049/29/24/5930Ho<sub>2</sub>SmSbO<sub>7</sub>/YbDyBiNbO<sub>7</sub> heterojunctiondirect Z-schemefenitrothionvisible light absorptionphotocatalytic efficiencydegradation pathway |
| spellingShingle | Liang Hao Jingfei Luan Visible Light-Driven Direct Z-Scheme Ho<sub>2</sub>SmSbO<sub>7</sub>/YbDyBiNbO<sub>7</sub> Heterojunction Photocatalyst for Efficient Degradation of Fenitrothion Molecules Ho<sub>2</sub>SmSbO<sub>7</sub>/YbDyBiNbO<sub>7</sub> heterojunction direct Z-scheme fenitrothion visible light absorption photocatalytic efficiency degradation pathway |
| title | Visible Light-Driven Direct Z-Scheme Ho<sub>2</sub>SmSbO<sub>7</sub>/YbDyBiNbO<sub>7</sub> Heterojunction Photocatalyst for Efficient Degradation of Fenitrothion |
| title_full | Visible Light-Driven Direct Z-Scheme Ho<sub>2</sub>SmSbO<sub>7</sub>/YbDyBiNbO<sub>7</sub> Heterojunction Photocatalyst for Efficient Degradation of Fenitrothion |
| title_fullStr | Visible Light-Driven Direct Z-Scheme Ho<sub>2</sub>SmSbO<sub>7</sub>/YbDyBiNbO<sub>7</sub> Heterojunction Photocatalyst for Efficient Degradation of Fenitrothion |
| title_full_unstemmed | Visible Light-Driven Direct Z-Scheme Ho<sub>2</sub>SmSbO<sub>7</sub>/YbDyBiNbO<sub>7</sub> Heterojunction Photocatalyst for Efficient Degradation of Fenitrothion |
| title_short | Visible Light-Driven Direct Z-Scheme Ho<sub>2</sub>SmSbO<sub>7</sub>/YbDyBiNbO<sub>7</sub> Heterojunction Photocatalyst for Efficient Degradation of Fenitrothion |
| title_sort | visible light driven direct z scheme ho sub 2 sub smsbo sub 7 sub ybdybinbo sub 7 sub heterojunction photocatalyst for efficient degradation of fenitrothion |
| topic | Ho<sub>2</sub>SmSbO<sub>7</sub>/YbDyBiNbO<sub>7</sub> heterojunction direct Z-scheme fenitrothion visible light absorption photocatalytic efficiency degradation pathway |
| url | https://www.mdpi.com/1420-3049/29/24/5930 |
| work_keys_str_mv | AT lianghao visiblelightdrivendirectzschemehosub2subsmsbosub7subybdybinbosub7subheterojunctionphotocatalystforefficientdegradationoffenitrothion AT jingfeiluan visiblelightdrivendirectzschemehosub2subsmsbosub7subybdybinbosub7subheterojunctionphotocatalystforefficientdegradationoffenitrothion |