Tuning BMI.NTf<sub>2</sub> Ionic Liquid Concentration in Dental Adhesives Towards a Rational Design of Antibacterial Materials

1-Butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (BMI.NTf<sub>2</sub>) is a hydrophobic ionic liquid with potential antibacterial properties for dental materials. This study aimed to (1) incorporate different mass fractions of BMI.NTf<sub>2</sub> into a dental ad...

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Main Authors: Isadora Martini Garcia, Andressa Simionato, Virgínia Serra Souza, Jackson Damiani Scholten, Mary Anne Sampaio Melo, Fabrício Mezzomo Collares
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Applied Sciences
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Online Access:https://www.mdpi.com/2076-3417/15/7/3810
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author Isadora Martini Garcia
Andressa Simionato
Virgínia Serra Souza
Jackson Damiani Scholten
Mary Anne Sampaio Melo
Fabrício Mezzomo Collares
author_facet Isadora Martini Garcia
Andressa Simionato
Virgínia Serra Souza
Jackson Damiani Scholten
Mary Anne Sampaio Melo
Fabrício Mezzomo Collares
author_sort Isadora Martini Garcia
collection DOAJ
description 1-Butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (BMI.NTf<sub>2</sub>) is a hydrophobic ionic liquid with potential antibacterial properties for dental materials. This study aimed to (1) incorporate different mass fractions of BMI.NTf<sub>2</sub> into a dental adhesive and (2) assess its impact on physical and chemical properties. Adhesive resins were prepared with 1 (G<sub>1%</sub>), 2.5 (G<sub>2.5%</sub>), and 5 wt.% (G<sub>5%</sub>) BMI.NTf<sub>2</sub>, with a control group (G<sub>CTRL</sub>) lacking the ionic liquid. Evaluations included polymerization kinetics, degree of conversion (DC), softening in solvent (ΔKHN%), and ultimate tensile strength (UTS). Groups with BMI.NTf<sub>2</sub> showed accelerated polymerization kinetics, with G<sub>5%</sub> achieving a higher DC and ΔKHN% compared to G<sub>CTRL</sub> (<i>p</i> < 0.05). Lower concentrations (1% and 2.5%) did not affect ΔKHN%, and no significant differences were found in UTS across groups (<i>p</i> > 0.05). Notably, 2.5 wt.% of BMI.NTf<sub>2</sub> increased the DC without affecting other properties, indicating optimal polymerization rates and handling characteristics. These results support the development of BMI.NTf<sub>2</sub>-based antibacterial adhesives that may assist in preventing secondary caries in restorative dentistry.
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spelling doaj-art-0c4d9eec67a0424ea022ea0ee607adfb2025-08-20T02:09:18ZengMDPI AGApplied Sciences2076-34172025-03-01157381010.3390/app15073810Tuning BMI.NTf<sub>2</sub> Ionic Liquid Concentration in Dental Adhesives Towards a Rational Design of Antibacterial MaterialsIsadora Martini Garcia0Andressa Simionato1Virgínia Serra Souza2Jackson Damiani Scholten3Mary Anne Sampaio Melo4Fabrício Mezzomo Collares5Division of Cariology and Operative Dentistry, Department of Comprehensive Dentistry, University of Maryland School of Dentistry, 650 W Baltimore Street, Baltimore, MD 21201, USADepartment of Dental Materials, School of Dentistry, Federal University of Rio Grande do Sul, Ramiro Barcelos Street, 2492, Rio Branco, Porto Alegre 90035-004, RS, BrazilLaboratory of Molecular Catalysis, Institute of Chemistry, Federal University of Rio Grande do Sul, Bento Gonçalves Avenue, 9500, Agronomia, Porto Alegre 91501-970, RS, BrazilLaboratory of Molecular Catalysis, Institute of Chemistry, Federal University of Rio Grande do Sul, Bento Gonçalves Avenue, 9500, Agronomia, Porto Alegre 91501-970, RS, BrazilDivision of Cariology and Operative Dentistry, Department of Comprehensive Dentistry, University of Maryland School of Dentistry, 650 W Baltimore Street, Baltimore, MD 21201, USADepartment of Dental Materials, School of Dentistry, Federal University of Rio Grande do Sul, Ramiro Barcelos Street, 2492, Rio Branco, Porto Alegre 90035-004, RS, Brazil1-Butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (BMI.NTf<sub>2</sub>) is a hydrophobic ionic liquid with potential antibacterial properties for dental materials. This study aimed to (1) incorporate different mass fractions of BMI.NTf<sub>2</sub> into a dental adhesive and (2) assess its impact on physical and chemical properties. Adhesive resins were prepared with 1 (G<sub>1%</sub>), 2.5 (G<sub>2.5%</sub>), and 5 wt.% (G<sub>5%</sub>) BMI.NTf<sub>2</sub>, with a control group (G<sub>CTRL</sub>) lacking the ionic liquid. Evaluations included polymerization kinetics, degree of conversion (DC), softening in solvent (ΔKHN%), and ultimate tensile strength (UTS). Groups with BMI.NTf<sub>2</sub> showed accelerated polymerization kinetics, with G<sub>5%</sub> achieving a higher DC and ΔKHN% compared to G<sub>CTRL</sub> (<i>p</i> < 0.05). Lower concentrations (1% and 2.5%) did not affect ΔKHN%, and no significant differences were found in UTS across groups (<i>p</i> > 0.05). Notably, 2.5 wt.% of BMI.NTf<sub>2</sub> increased the DC without affecting other properties, indicating optimal polymerization rates and handling characteristics. These results support the development of BMI.NTf<sub>2</sub>-based antibacterial adhesives that may assist in preventing secondary caries in restorative dentistry.https://www.mdpi.com/2076-3417/15/7/3810dental cariesdental materialsdentin-bonding agentsionic liquidspolymersin vitro techniques
spellingShingle Isadora Martini Garcia
Andressa Simionato
Virgínia Serra Souza
Jackson Damiani Scholten
Mary Anne Sampaio Melo
Fabrício Mezzomo Collares
Tuning BMI.NTf<sub>2</sub> Ionic Liquid Concentration in Dental Adhesives Towards a Rational Design of Antibacterial Materials
Applied Sciences
dental caries
dental materials
dentin-bonding agents
ionic liquids
polymers
in vitro techniques
title Tuning BMI.NTf<sub>2</sub> Ionic Liquid Concentration in Dental Adhesives Towards a Rational Design of Antibacterial Materials
title_full Tuning BMI.NTf<sub>2</sub> Ionic Liquid Concentration in Dental Adhesives Towards a Rational Design of Antibacterial Materials
title_fullStr Tuning BMI.NTf<sub>2</sub> Ionic Liquid Concentration in Dental Adhesives Towards a Rational Design of Antibacterial Materials
title_full_unstemmed Tuning BMI.NTf<sub>2</sub> Ionic Liquid Concentration in Dental Adhesives Towards a Rational Design of Antibacterial Materials
title_short Tuning BMI.NTf<sub>2</sub> Ionic Liquid Concentration in Dental Adhesives Towards a Rational Design of Antibacterial Materials
title_sort tuning bmi ntf sub 2 sub ionic liquid concentration in dental adhesives towards a rational design of antibacterial materials
topic dental caries
dental materials
dentin-bonding agents
ionic liquids
polymers
in vitro techniques
url https://www.mdpi.com/2076-3417/15/7/3810
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