Synergetic Effect between Phenolic Extracts of Ammi visnaga and Zea mays Formulation on the Corrosion of Mild Steel in 1 M HCl Solution

The synergetic effects between hydroethanolic extracts of A. visnaga HE (AV) and Z. mays hairs HE (ZM) on corrosion of mild steel in 1 M HCl solution was investigated at 298 K by two techniques: potentiodynamic polarization (PP) methods (Tafel and Stern & Geary) and electrochemical impedance spe...

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Main Authors: Sarra Aourabi, Majid Driouch, Mariya Kadiri, Noura Achnine, Mouhcine Sfaira, Fatima Mahjoubi
Format: Article
Language:English
Published: Wiley 2021-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2021/5589175
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author Sarra Aourabi
Majid Driouch
Mariya Kadiri
Noura Achnine
Mouhcine Sfaira
Fatima Mahjoubi
author_facet Sarra Aourabi
Majid Driouch
Mariya Kadiri
Noura Achnine
Mouhcine Sfaira
Fatima Mahjoubi
author_sort Sarra Aourabi
collection DOAJ
description The synergetic effects between hydroethanolic extracts of A. visnaga HE (AV) and Z. mays hairs HE (ZM) on corrosion of mild steel in 1 M HCl solution was investigated at 298 K by two techniques: potentiodynamic polarization (PP) methods (Tafel and Stern & Geary) and electrochemical impedance spectroscopy (EIS). The mixture of HE (AV)/HE (ZM) acted as an efficient corrosion inhibitor and its inhibition efficiency increased with concentration up to 96.55% at 0.01 gL−1 HE (AV)/0.2 gL−1 HE (ZM). The polarization curves revealed that the mixture acted as a mixed-type inhibitor, with anodic predominant action. The EIS studies were fitted by the (Rs + CPEdl)/(Rct + CPEf/Rf) equivalent circuit model. The kinetic parameters were in favor of a physisorption character of adsorption of HE (AV)/HE (ZM) components onto the mild steel surface. The influence of exposure time on the efficiency of mixture extract was investigated. Scanning electron microscopy (SEM/EDX) analyses confirmed the formation of a protective adsorbed film upon the mild steel surface.
format Article
id doaj-art-0c483e00e305466e85b55adab3189d6a
institution OA Journals
issn 2090-9063
2090-9071
language English
publishDate 2021-01-01
publisher Wiley
record_format Article
series Journal of Chemistry
spelling doaj-art-0c483e00e305466e85b55adab3189d6a2025-08-20T02:02:54ZengWileyJournal of Chemistry2090-90632090-90712021-01-01202110.1155/2021/55891755589175Synergetic Effect between Phenolic Extracts of Ammi visnaga and Zea mays Formulation on the Corrosion of Mild Steel in 1 M HCl SolutionSarra Aourabi0Majid Driouch1Mariya Kadiri2Noura Achnine3Mouhcine Sfaira4Fatima Mahjoubi5Laboratory of Engineering, Modeling and Systems Analysis (LIMAS), University Sidi Mohamed Ben Abdellah (USMBA), Faculty of Sciences, P.O. Box 1796-30000, Fez-Atlas, MoroccoLaboratory of Engineering, Modeling and Systems Analysis (LIMAS), University Sidi Mohamed Ben Abdellah (USMBA), Faculty of Sciences, P.O. Box 1796-30000, Fez-Atlas, MoroccoLaboratory of Engineering, Modeling and Systems Analysis (LIMAS), University Sidi Mohamed Ben Abdellah (USMBA), Faculty of Sciences, P.O. Box 1796-30000, Fez-Atlas, MoroccoLaboratory of Engineering, Modeling and Systems Analysis (LIMAS), University Sidi Mohamed Ben Abdellah (USMBA), Faculty of Sciences, P.O. Box 1796-30000, Fez-Atlas, MoroccoLaboratory of Engineering, Modeling and Systems Analysis (LIMAS), University Sidi Mohamed Ben Abdellah (USMBA), Faculty of Sciences, P.O. Box 1796-30000, Fez-Atlas, MoroccoLaboratory of Engineering, Modeling and Systems Analysis (LIMAS), University Sidi Mohamed Ben Abdellah (USMBA), Faculty of Sciences, P.O. Box 1796-30000, Fez-Atlas, MoroccoThe synergetic effects between hydroethanolic extracts of A. visnaga HE (AV) and Z. mays hairs HE (ZM) on corrosion of mild steel in 1 M HCl solution was investigated at 298 K by two techniques: potentiodynamic polarization (PP) methods (Tafel and Stern & Geary) and electrochemical impedance spectroscopy (EIS). The mixture of HE (AV)/HE (ZM) acted as an efficient corrosion inhibitor and its inhibition efficiency increased with concentration up to 96.55% at 0.01 gL−1 HE (AV)/0.2 gL−1 HE (ZM). The polarization curves revealed that the mixture acted as a mixed-type inhibitor, with anodic predominant action. The EIS studies were fitted by the (Rs + CPEdl)/(Rct + CPEf/Rf) equivalent circuit model. The kinetic parameters were in favor of a physisorption character of adsorption of HE (AV)/HE (ZM) components onto the mild steel surface. The influence of exposure time on the efficiency of mixture extract was investigated. Scanning electron microscopy (SEM/EDX) analyses confirmed the formation of a protective adsorbed film upon the mild steel surface.http://dx.doi.org/10.1155/2021/5589175
spellingShingle Sarra Aourabi
Majid Driouch
Mariya Kadiri
Noura Achnine
Mouhcine Sfaira
Fatima Mahjoubi
Synergetic Effect between Phenolic Extracts of Ammi visnaga and Zea mays Formulation on the Corrosion of Mild Steel in 1 M HCl Solution
Journal of Chemistry
title Synergetic Effect between Phenolic Extracts of Ammi visnaga and Zea mays Formulation on the Corrosion of Mild Steel in 1 M HCl Solution
title_full Synergetic Effect between Phenolic Extracts of Ammi visnaga and Zea mays Formulation on the Corrosion of Mild Steel in 1 M HCl Solution
title_fullStr Synergetic Effect between Phenolic Extracts of Ammi visnaga and Zea mays Formulation on the Corrosion of Mild Steel in 1 M HCl Solution
title_full_unstemmed Synergetic Effect between Phenolic Extracts of Ammi visnaga and Zea mays Formulation on the Corrosion of Mild Steel in 1 M HCl Solution
title_short Synergetic Effect between Phenolic Extracts of Ammi visnaga and Zea mays Formulation on the Corrosion of Mild Steel in 1 M HCl Solution
title_sort synergetic effect between phenolic extracts of ammi visnaga and zea mays formulation on the corrosion of mild steel in 1 m hcl solution
url http://dx.doi.org/10.1155/2021/5589175
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