Photoacoustic spectroscopy of layered crystals: An enhancement of the photoacoustic signal and its analysis from the perspective of heat generation

Photoacoustic spectroscopy is a powerful tool for investigating semiconductors and determining some of their basic properties. However, generating a signal that is large enough for the investigated samples is still challenging. To address this, the focus is on enhancing photoacoustic (PA) signal int...

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Main Authors: Kamil Misztal, Jan Kopaczek, Robert Kudrawiec
Format: Article
Language:English
Published: Elsevier 2025-02-01
Series:Photoacoustics
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Online Access:http://www.sciencedirect.com/science/article/pii/S2213597924000855
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author Kamil Misztal
Jan Kopaczek
Robert Kudrawiec
author_facet Kamil Misztal
Jan Kopaczek
Robert Kudrawiec
author_sort Kamil Misztal
collection DOAJ
description Photoacoustic spectroscopy is a powerful tool for investigating semiconductors and determining some of their basic properties. However, generating a signal that is large enough for the investigated samples is still challenging. To address this, the focus is on enhancing photoacoustic (PA) signal intensity in a non-complex way, which does not require changing any part of an experimental setup. The PA signal intensity enhancement is mainly achieved by manipulating the sample volume and its surroundings. MoS2, a layered material that belongs to the van der Waals crystals was selected due to ease of exfoliation to the proper thickness. A reduction in MoS2 thickness from 112 to 7 µm, resulted in enhancement of the PA signal by a factor of ∼50. A simple model has been proposed to describe the results based on thermal processes. Additionally, a method to determine the energy gap in transition metal dichalcogenides from PA measurements is presented.
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institution Kabale University
issn 2213-5979
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publishDate 2025-02-01
publisher Elsevier
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series Photoacoustics
spelling doaj-art-0c454fc4184d4bd682edc06ea1503ec22025-01-17T04:49:29ZengElsevierPhotoacoustics2213-59792025-02-0141100668Photoacoustic spectroscopy of layered crystals: An enhancement of the photoacoustic signal and its analysis from the perspective of heat generationKamil Misztal0Jan Kopaczek1Robert Kudrawiec2Corresponding author.; Department of Semiconductor Materials Engineering, Wrocław University of Science and Technology, Wybrzeże Stanisława Wyspiańskiego 27, Wrocław 50-370, PolandDepartment of Semiconductor Materials Engineering, Wrocław University of Science and Technology, Wybrzeże Stanisława Wyspiańskiego 27, Wrocław 50-370, PolandDepartment of Semiconductor Materials Engineering, Wrocław University of Science and Technology, Wybrzeże Stanisława Wyspiańskiego 27, Wrocław 50-370, PolandPhotoacoustic spectroscopy is a powerful tool for investigating semiconductors and determining some of their basic properties. However, generating a signal that is large enough for the investigated samples is still challenging. To address this, the focus is on enhancing photoacoustic (PA) signal intensity in a non-complex way, which does not require changing any part of an experimental setup. The PA signal intensity enhancement is mainly achieved by manipulating the sample volume and its surroundings. MoS2, a layered material that belongs to the van der Waals crystals was selected due to ease of exfoliation to the proper thickness. A reduction in MoS2 thickness from 112 to 7 µm, resulted in enhancement of the PA signal by a factor of ∼50. A simple model has been proposed to describe the results based on thermal processes. Additionally, a method to determine the energy gap in transition metal dichalcogenides from PA measurements is presented.http://www.sciencedirect.com/science/article/pii/S2213597924000855Photoacoustic spectroscopyVan der Waals crystalsMoS2
spellingShingle Kamil Misztal
Jan Kopaczek
Robert Kudrawiec
Photoacoustic spectroscopy of layered crystals: An enhancement of the photoacoustic signal and its analysis from the perspective of heat generation
Photoacoustics
Photoacoustic spectroscopy
Van der Waals crystals
MoS2
title Photoacoustic spectroscopy of layered crystals: An enhancement of the photoacoustic signal and its analysis from the perspective of heat generation
title_full Photoacoustic spectroscopy of layered crystals: An enhancement of the photoacoustic signal and its analysis from the perspective of heat generation
title_fullStr Photoacoustic spectroscopy of layered crystals: An enhancement of the photoacoustic signal and its analysis from the perspective of heat generation
title_full_unstemmed Photoacoustic spectroscopy of layered crystals: An enhancement of the photoacoustic signal and its analysis from the perspective of heat generation
title_short Photoacoustic spectroscopy of layered crystals: An enhancement of the photoacoustic signal and its analysis from the perspective of heat generation
title_sort photoacoustic spectroscopy of layered crystals an enhancement of the photoacoustic signal and its analysis from the perspective of heat generation
topic Photoacoustic spectroscopy
Van der Waals crystals
MoS2
url http://www.sciencedirect.com/science/article/pii/S2213597924000855
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AT jankopaczek photoacousticspectroscopyoflayeredcrystalsanenhancementofthephotoacousticsignalanditsanalysisfromtheperspectiveofheatgeneration
AT robertkudrawiec photoacousticspectroscopyoflayeredcrystalsanenhancementofthephotoacousticsignalanditsanalysisfromtheperspectiveofheatgeneration