Comparative microscopic study of entropies and their production

We study the time evolution of eleven microscopic entropy definitions (of Boltzmann-surface, Gibbs-volume, canonical, coarse-grained-observational, entanglement and diagonal type) and three microscopic temperature definitions (based on Boltzmann, Gibbs or canonical entropy). This is done for the arc...

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Main Author: Philipp Strasberg, Joseph Schindler
Format: Article
Language:English
Published: SciPost 2024-11-01
Series:SciPost Physics
Online Access:https://scipost.org/SciPostPhys.17.5.143
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author Philipp Strasberg, Joseph Schindler
author_facet Philipp Strasberg, Joseph Schindler
author_sort Philipp Strasberg, Joseph Schindler
collection DOAJ
description We study the time evolution of eleven microscopic entropy definitions (of Boltzmann-surface, Gibbs-volume, canonical, coarse-grained-observational, entanglement and diagonal type) and three microscopic temperature definitions (based on Boltzmann, Gibbs or canonical entropy). This is done for the archetypal nonequilibrium setup of two systems exchanging energy, modeled here with random matrix theory, based on numerical integration of the Schrödinger equation. We consider three types of pure initial states (local energy eigenstates, decorrelated and entangled microcanonical states) and three classes of systems: (A) two normal systems, (B) a normal and a negative temperature system and (C) a normal and a negative heat capacity system. We find: (1) All types of initial states give rise to the same macroscopic dynamics. (2) Entanglement and diagonal entropy sensitively depend on the microstate, in contrast to all other entropies. (3) For class B and C, Gibbs-volume entropies can violate the second law and the associated temperature becomes meaningless. (4) For class C, Boltzmann-surface entropies can violate the second law and the associated temperature becomes meaningless. (5) Canonical entropy has a tendency to remain almost constant. (6) For a Haar random initial state, entanglement or diagonal entropy behave similar or identical to coarse-grained-observational entropy.
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spelling doaj-art-0c09a0155a774a9a93cd62e441b8ba282025-08-20T02:23:45ZengSciPostSciPost Physics2542-46532024-11-0117514310.21468/SciPostPhys.17.5.143Comparative microscopic study of entropies and their productionPhilipp Strasberg, Joseph SchindlerWe study the time evolution of eleven microscopic entropy definitions (of Boltzmann-surface, Gibbs-volume, canonical, coarse-grained-observational, entanglement and diagonal type) and three microscopic temperature definitions (based on Boltzmann, Gibbs or canonical entropy). This is done for the archetypal nonequilibrium setup of two systems exchanging energy, modeled here with random matrix theory, based on numerical integration of the Schrödinger equation. We consider three types of pure initial states (local energy eigenstates, decorrelated and entangled microcanonical states) and three classes of systems: (A) two normal systems, (B) a normal and a negative temperature system and (C) a normal and a negative heat capacity system. We find: (1) All types of initial states give rise to the same macroscopic dynamics. (2) Entanglement and diagonal entropy sensitively depend on the microstate, in contrast to all other entropies. (3) For class B and C, Gibbs-volume entropies can violate the second law and the associated temperature becomes meaningless. (4) For class C, Boltzmann-surface entropies can violate the second law and the associated temperature becomes meaningless. (5) Canonical entropy has a tendency to remain almost constant. (6) For a Haar random initial state, entanglement or diagonal entropy behave similar or identical to coarse-grained-observational entropy.https://scipost.org/SciPostPhys.17.5.143
spellingShingle Philipp Strasberg, Joseph Schindler
Comparative microscopic study of entropies and their production
SciPost Physics
title Comparative microscopic study of entropies and their production
title_full Comparative microscopic study of entropies and their production
title_fullStr Comparative microscopic study of entropies and their production
title_full_unstemmed Comparative microscopic study of entropies and their production
title_short Comparative microscopic study of entropies and their production
title_sort comparative microscopic study of entropies and their production
url https://scipost.org/SciPostPhys.17.5.143
work_keys_str_mv AT philippstrasbergjosephschindler comparativemicroscopicstudyofentropiesandtheirproduction