Substutited molybdates of bismuth on a basis of Bi13Mo5O34±δ: production and properties
The present work is devoted to the investigation of the methods of a synthesis and properties of the one of the most interesting one-dimensional oxygen –ion conductors, the Bi13Mo5O34±δ –based complex oxides. The general compositions of these bismuth molybdates are Bi13Mo5-хMeхO34-δ, and Bi13-yMeyMo...
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| Language: | English |
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Ural Federal University
2014-06-01
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| Series: | Chimica Techno Acta |
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| Online Access: | https://chimicatechnoacta.ru/article/view/679 |
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| author | Z. A. Mikhailovskaya E. S. Buyanova S. A. Petrova R. G. Zakharov |
| author_facet | Z. A. Mikhailovskaya E. S. Buyanova S. A. Petrova R. G. Zakharov |
| author_sort | Z. A. Mikhailovskaya |
| collection | DOAJ |
| description | The present work is devoted to the investigation of the methods of a synthesis and properties of the one of the most interesting one-dimensional oxygen –ion conductors, the Bi13Mo5O34±δ –based complex oxides. The general compositions of these bismuth molybdates are Bi13Mo5-хMeхO34-δ, and Bi13-yMeyMo5O34-δ, with Me = Mg, Ca, Sr, Ba (IIA group) and Co, Fe, Ni (Fe triade). The samples have been synthesized using conventional ceramic technology. The powders and pellets of the bismuth molybdates were studied by X-Ray diffraction, scanning electron microscopy, laser dispersion, dilatometry, atom absorption and inductively-coupled plasma atomic emission spectrometry. Electrical conductivity has been studied using impedance spectroscopy method. |
| format | Article |
| id | doaj-art-0b613286bf494fdea923ad2b1fe3cc4b |
| institution | OA Journals |
| issn | 2411-1414 |
| language | English |
| publishDate | 2014-06-01 |
| publisher | Ural Federal University |
| record_format | Article |
| series | Chimica Techno Acta |
| spelling | doaj-art-0b613286bf494fdea923ad2b1fe3cc4b2025-08-20T02:03:28ZengUral Federal UniversityChimica Techno Acta2411-14142014-06-0111142010.15826/chimtech.2014.1.1.6791006Substutited molybdates of bismuth on a basis of Bi13Mo5O34±δ: production and propertiesZ. A. Mikhailovskaya0E. S. Buyanova1S. A. Petrova2R. G. Zakharov3Уральский федеральный университет, ЕкатеринбургУральский федеральный университет, ЕкатеринбургИнститут металлургии УрО РАН, ЕкатеринбургИнститут металлургии УрО РАН, ЕкатеринбургThe present work is devoted to the investigation of the methods of a synthesis and properties of the one of the most interesting one-dimensional oxygen –ion conductors, the Bi13Mo5O34±δ –based complex oxides. The general compositions of these bismuth molybdates are Bi13Mo5-хMeхO34-δ, and Bi13-yMeyMo5O34-δ, with Me = Mg, Ca, Sr, Ba (IIA group) and Co, Fe, Ni (Fe triade). The samples have been synthesized using conventional ceramic technology. The powders and pellets of the bismuth molybdates were studied by X-Ray diffraction, scanning electron microscopy, laser dispersion, dilatometry, atom absorption and inductively-coupled plasma atomic emission spectrometry. Electrical conductivity has been studied using impedance spectroscopy method.https://chimicatechnoacta.ru/article/view/679молибдаты висмутакислород-ионная проводимостьионный транспортрентгенофазовый анализэлектронная микроскопия |
| spellingShingle | Z. A. Mikhailovskaya E. S. Buyanova S. A. Petrova R. G. Zakharov Substutited molybdates of bismuth on a basis of Bi13Mo5O34±δ: production and properties Chimica Techno Acta молибдаты висмута кислород-ионная проводимость ионный транспорт рентгенофазовый анализ электронная микроскопия |
| title | Substutited molybdates of bismuth on a basis of Bi13Mo5O34±δ: production and properties |
| title_full | Substutited molybdates of bismuth on a basis of Bi13Mo5O34±δ: production and properties |
| title_fullStr | Substutited molybdates of bismuth on a basis of Bi13Mo5O34±δ: production and properties |
| title_full_unstemmed | Substutited molybdates of bismuth on a basis of Bi13Mo5O34±δ: production and properties |
| title_short | Substutited molybdates of bismuth on a basis of Bi13Mo5O34±δ: production and properties |
| title_sort | substutited molybdates of bismuth on a basis of bi13mo5o34 δ production and properties |
| topic | молибдаты висмута кислород-ионная проводимость ионный транспорт рентгенофазовый анализ электронная микроскопия |
| url | https://chimicatechnoacta.ru/article/view/679 |
| work_keys_str_mv | AT zamikhailovskaya substutitedmolybdatesofbismuthonabasisofbi13mo5o34dproductionandproperties AT esbuyanova substutitedmolybdatesofbismuthonabasisofbi13mo5o34dproductionandproperties AT sapetrova substutitedmolybdatesofbismuthonabasisofbi13mo5o34dproductionandproperties AT rgzakharov substutitedmolybdatesofbismuthonabasisofbi13mo5o34dproductionandproperties |