Synthesis of xLiMnPO4·yLi3V2(PO4)3/C Nanocomposites for Lithium Ion Batteries Using Tributyl Phosphate as Phosphor Source

The xLiMnPO4·yLi3V2(PO4)3/C (x/y = 1 : 0, 12 : 1, 8 : 1, 6 : 1, 4 : 1, 0 : 1) composite cathode materials are synthesized using tributyl phosphate as a novel organic phosphor source via a solid-state reaction process. All obtained xLiMnPO4·yLi3V2(PO4)3/C composites present similar particles morpholo...

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Main Authors: Yanming Wang, Bo Zhu, Xiaoyu Liu, Fei Wang
Format: Article
Language:English
Published: Wiley 2017-01-01
Series:Journal of Nanotechnology
Online Access:http://dx.doi.org/10.1155/2017/4030249
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author Yanming Wang
Bo Zhu
Xiaoyu Liu
Fei Wang
author_facet Yanming Wang
Bo Zhu
Xiaoyu Liu
Fei Wang
author_sort Yanming Wang
collection DOAJ
description The xLiMnPO4·yLi3V2(PO4)3/C (x/y = 1 : 0, 12 : 1, 8 : 1, 6 : 1, 4 : 1, 0 : 1) composite cathode materials are synthesized using tributyl phosphate as a novel organic phosphor source via a solid-state reaction process. All obtained xLiMnPO4·yLi3V2(PO4)3/C composites present similar particles morphology with an average size of ca. 100 nm and low extent agglomeration. The electrochemical performance of pristine LiMnPO4/C can be effectively improved by adding small amounts of Li3V2(PO4)3 additives. The 4LiMnPO4·Li3V2(PO4)3/C has a high discharge capacity of 143 mAh g−1 at 0.1 C and keeps its 94% at the end of 100 cycles.
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institution Kabale University
issn 1687-9503
1687-9511
language English
publishDate 2017-01-01
publisher Wiley
record_format Article
series Journal of Nanotechnology
spelling doaj-art-0b35d7d1d47444daad326c164b9009092025-02-03T01:30:00ZengWileyJournal of Nanotechnology1687-95031687-95112017-01-01201710.1155/2017/40302494030249Synthesis of xLiMnPO4·yLi3V2(PO4)3/C Nanocomposites for Lithium Ion Batteries Using Tributyl Phosphate as Phosphor SourceYanming Wang0Bo Zhu1Xiaoyu Liu2Fei Wang3Anhui Key Laboratory of Energetic Materials and School of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, ChinaAnhui Key Laboratory of Energetic Materials and School of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, ChinaAnhui Key Laboratory of Energetic Materials and School of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, ChinaAnhui Key Laboratory of Energetic Materials and School of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, ChinaThe xLiMnPO4·yLi3V2(PO4)3/C (x/y = 1 : 0, 12 : 1, 8 : 1, 6 : 1, 4 : 1, 0 : 1) composite cathode materials are synthesized using tributyl phosphate as a novel organic phosphor source via a solid-state reaction process. All obtained xLiMnPO4·yLi3V2(PO4)3/C composites present similar particles morphology with an average size of ca. 100 nm and low extent agglomeration. The electrochemical performance of pristine LiMnPO4/C can be effectively improved by adding small amounts of Li3V2(PO4)3 additives. The 4LiMnPO4·Li3V2(PO4)3/C has a high discharge capacity of 143 mAh g−1 at 0.1 C and keeps its 94% at the end of 100 cycles.http://dx.doi.org/10.1155/2017/4030249
spellingShingle Yanming Wang
Bo Zhu
Xiaoyu Liu
Fei Wang
Synthesis of xLiMnPO4·yLi3V2(PO4)3/C Nanocomposites for Lithium Ion Batteries Using Tributyl Phosphate as Phosphor Source
Journal of Nanotechnology
title Synthesis of xLiMnPO4·yLi3V2(PO4)3/C Nanocomposites for Lithium Ion Batteries Using Tributyl Phosphate as Phosphor Source
title_full Synthesis of xLiMnPO4·yLi3V2(PO4)3/C Nanocomposites for Lithium Ion Batteries Using Tributyl Phosphate as Phosphor Source
title_fullStr Synthesis of xLiMnPO4·yLi3V2(PO4)3/C Nanocomposites for Lithium Ion Batteries Using Tributyl Phosphate as Phosphor Source
title_full_unstemmed Synthesis of xLiMnPO4·yLi3V2(PO4)3/C Nanocomposites for Lithium Ion Batteries Using Tributyl Phosphate as Phosphor Source
title_short Synthesis of xLiMnPO4·yLi3V2(PO4)3/C Nanocomposites for Lithium Ion Batteries Using Tributyl Phosphate as Phosphor Source
title_sort synthesis of xlimnpo4·yli3v2 po4 3 c nanocomposites for lithium ion batteries using tributyl phosphate as phosphor source
url http://dx.doi.org/10.1155/2017/4030249
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AT xiaoyuliu synthesisofxlimnpo4yli3v2po43cnanocompositesforlithiumionbatteriesusingtributylphosphateasphosphorsource
AT feiwang synthesisofxlimnpo4yli3v2po43cnanocompositesforlithiumionbatteriesusingtributylphosphateasphosphorsource