Synthesis of xLiMnPO4·yLi3V2(PO4)3/C Nanocomposites for Lithium Ion Batteries Using Tributyl Phosphate as Phosphor Source
The xLiMnPO4·yLi3V2(PO4)3/C (x/y = 1 : 0, 12 : 1, 8 : 1, 6 : 1, 4 : 1, 0 : 1) composite cathode materials are synthesized using tributyl phosphate as a novel organic phosphor source via a solid-state reaction process. All obtained xLiMnPO4·yLi3V2(PO4)3/C composites present similar particles morpholo...
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Wiley
2017-01-01
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Series: | Journal of Nanotechnology |
Online Access: | http://dx.doi.org/10.1155/2017/4030249 |
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author | Yanming Wang Bo Zhu Xiaoyu Liu Fei Wang |
author_facet | Yanming Wang Bo Zhu Xiaoyu Liu Fei Wang |
author_sort | Yanming Wang |
collection | DOAJ |
description | The xLiMnPO4·yLi3V2(PO4)3/C (x/y = 1 : 0, 12 : 1, 8 : 1, 6 : 1, 4 : 1, 0 : 1) composite cathode materials are synthesized using tributyl phosphate as a novel organic phosphor source via a solid-state reaction process. All obtained xLiMnPO4·yLi3V2(PO4)3/C composites present similar particles morphology with an average size of ca. 100 nm and low extent agglomeration. The electrochemical performance of pristine LiMnPO4/C can be effectively improved by adding small amounts of Li3V2(PO4)3 additives. The 4LiMnPO4·Li3V2(PO4)3/C has a high discharge capacity of 143 mAh g−1 at 0.1 C and keeps its 94% at the end of 100 cycles. |
format | Article |
id | doaj-art-0b35d7d1d47444daad326c164b900909 |
institution | Kabale University |
issn | 1687-9503 1687-9511 |
language | English |
publishDate | 2017-01-01 |
publisher | Wiley |
record_format | Article |
series | Journal of Nanotechnology |
spelling | doaj-art-0b35d7d1d47444daad326c164b9009092025-02-03T01:30:00ZengWileyJournal of Nanotechnology1687-95031687-95112017-01-01201710.1155/2017/40302494030249Synthesis of xLiMnPO4·yLi3V2(PO4)3/C Nanocomposites for Lithium Ion Batteries Using Tributyl Phosphate as Phosphor SourceYanming Wang0Bo Zhu1Xiaoyu Liu2Fei Wang3Anhui Key Laboratory of Energetic Materials and School of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, ChinaAnhui Key Laboratory of Energetic Materials and School of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, ChinaAnhui Key Laboratory of Energetic Materials and School of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, ChinaAnhui Key Laboratory of Energetic Materials and School of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, ChinaThe xLiMnPO4·yLi3V2(PO4)3/C (x/y = 1 : 0, 12 : 1, 8 : 1, 6 : 1, 4 : 1, 0 : 1) composite cathode materials are synthesized using tributyl phosphate as a novel organic phosphor source via a solid-state reaction process. All obtained xLiMnPO4·yLi3V2(PO4)3/C composites present similar particles morphology with an average size of ca. 100 nm and low extent agglomeration. The electrochemical performance of pristine LiMnPO4/C can be effectively improved by adding small amounts of Li3V2(PO4)3 additives. The 4LiMnPO4·Li3V2(PO4)3/C has a high discharge capacity of 143 mAh g−1 at 0.1 C and keeps its 94% at the end of 100 cycles.http://dx.doi.org/10.1155/2017/4030249 |
spellingShingle | Yanming Wang Bo Zhu Xiaoyu Liu Fei Wang Synthesis of xLiMnPO4·yLi3V2(PO4)3/C Nanocomposites for Lithium Ion Batteries Using Tributyl Phosphate as Phosphor Source Journal of Nanotechnology |
title | Synthesis of xLiMnPO4·yLi3V2(PO4)3/C Nanocomposites for Lithium Ion Batteries Using Tributyl Phosphate as Phosphor Source |
title_full | Synthesis of xLiMnPO4·yLi3V2(PO4)3/C Nanocomposites for Lithium Ion Batteries Using Tributyl Phosphate as Phosphor Source |
title_fullStr | Synthesis of xLiMnPO4·yLi3V2(PO4)3/C Nanocomposites for Lithium Ion Batteries Using Tributyl Phosphate as Phosphor Source |
title_full_unstemmed | Synthesis of xLiMnPO4·yLi3V2(PO4)3/C Nanocomposites for Lithium Ion Batteries Using Tributyl Phosphate as Phosphor Source |
title_short | Synthesis of xLiMnPO4·yLi3V2(PO4)3/C Nanocomposites for Lithium Ion Batteries Using Tributyl Phosphate as Phosphor Source |
title_sort | synthesis of xlimnpo4·yli3v2 po4 3 c nanocomposites for lithium ion batteries using tributyl phosphate as phosphor source |
url | http://dx.doi.org/10.1155/2017/4030249 |
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