Anions of α-Amino Acids as (O,N)-Donor Ligands in Si-, Ge- and Sn-Coordination Chemistry
This review gives an overview of Si-, Ge- and Sn-compounds with (O,N)-bi- and -oligodentate ligands, which have the α-amino carboxylic acid motif N–C(<i>R</i>,<i>R</i>′)–C(=O)O in common (<i>R</i>,<i>R</i>′ = H or hydrocarbyl). While the amino acids th...
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2025-02-01
|
| Series: | Molecules |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1420-3049/30/4/834 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1850082171410186240 |
|---|---|
| author | Anne Seidel Jörg Wagler |
| author_facet | Anne Seidel Jörg Wagler |
| author_sort | Anne Seidel |
| collection | DOAJ |
| description | This review gives an overview of Si-, Ge- and Sn-compounds with (O,N)-bi- and -oligodentate ligands, which have the α-amino carboxylic acid motif N–C(<i>R</i>,<i>R</i>′)–C(=O)O in common (<i>R</i>,<i>R</i>′ = H or hydrocarbyl). While the amino acids themselves are encountered as mono- and di-anionic ligands, modifications at the N-terminus (e.g., extension of the ligand backbone by, e.g., additional alkane carboxylic acid groups) give rise to a wealth of ligands, which bear the α-amino carboxylic acid motif. With particular interest in the coordination features of these ligands, crystallographically characterized complexes are the focus of this review. |
| format | Article |
| id | doaj-art-0b19178e3b9c4d2fb19e92e52f640b72 |
| institution | DOAJ |
| issn | 1420-3049 |
| language | English |
| publishDate | 2025-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj-art-0b19178e3b9c4d2fb19e92e52f640b722025-08-20T02:44:35ZengMDPI AGMolecules1420-30492025-02-0130483410.3390/molecules30040834Anions of α-Amino Acids as (O,N)-Donor Ligands in Si-, Ge- and Sn-Coordination ChemistryAnne Seidel0Jörg Wagler1Institut für Anorganische Chemie, TU Bergakademie Freiberg, D-09596 Freiberg, GermanyInstitut für Anorganische Chemie, TU Bergakademie Freiberg, D-09596 Freiberg, GermanyThis review gives an overview of Si-, Ge- and Sn-compounds with (O,N)-bi- and -oligodentate ligands, which have the α-amino carboxylic acid motif N–C(<i>R</i>,<i>R</i>′)–C(=O)O in common (<i>R</i>,<i>R</i>′ = H or hydrocarbyl). While the amino acids themselves are encountered as mono- and di-anionic ligands, modifications at the N-terminus (e.g., extension of the ligand backbone by, e.g., additional alkane carboxylic acid groups) give rise to a wealth of ligands, which bear the α-amino carboxylic acid motif. With particular interest in the coordination features of these ligands, crystallographically characterized complexes are the focus of this review.https://www.mdpi.com/1420-3049/30/4/834amine acetic acidchelatechiral poolcomplexationhypercoordinationpeptide |
| spellingShingle | Anne Seidel Jörg Wagler Anions of α-Amino Acids as (O,N)-Donor Ligands in Si-, Ge- and Sn-Coordination Chemistry Molecules amine acetic acid chelate chiral pool complexation hypercoordination peptide |
| title | Anions of α-Amino Acids as (O,N)-Donor Ligands in Si-, Ge- and Sn-Coordination Chemistry |
| title_full | Anions of α-Amino Acids as (O,N)-Donor Ligands in Si-, Ge- and Sn-Coordination Chemistry |
| title_fullStr | Anions of α-Amino Acids as (O,N)-Donor Ligands in Si-, Ge- and Sn-Coordination Chemistry |
| title_full_unstemmed | Anions of α-Amino Acids as (O,N)-Donor Ligands in Si-, Ge- and Sn-Coordination Chemistry |
| title_short | Anions of α-Amino Acids as (O,N)-Donor Ligands in Si-, Ge- and Sn-Coordination Chemistry |
| title_sort | anions of α amino acids as o n donor ligands in si ge and sn coordination chemistry |
| topic | amine acetic acid chelate chiral pool complexation hypercoordination peptide |
| url | https://www.mdpi.com/1420-3049/30/4/834 |
| work_keys_str_mv | AT anneseidel anionsofaaminoacidsasondonorligandsinsigeandsncoordinationchemistry AT jorgwagler anionsofaaminoacidsasondonorligandsinsigeandsncoordinationchemistry |