4-(10-Phenyl-9-Anthracenyl)-1,2-Benzenediol
The title compound, 4-(10-phenyl-9-anthracenyl)-1,2-benzenediol, was synthesized using a two-step protocol. In the first step, 9-phenyl,10-bromoanthracene was coupled to 3,4-dimethoyphenylboronic acid by employing Pd(PPh<sub>3</sub>)<sub>4</sub> as the catalyst and potassium...
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MDPI AG
2024-09-01
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| Online Access: | https://www.mdpi.com/1422-8599/2024/3/M1884 |
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| author | Nicola Edwards Kelsey Harris |
| author_facet | Nicola Edwards Kelsey Harris |
| author_sort | Nicola Edwards |
| collection | DOAJ |
| description | The title compound, 4-(10-phenyl-9-anthracenyl)-1,2-benzenediol, was synthesized using a two-step protocol. In the first step, 9-phenyl,10-bromoanthracene was coupled to 3,4-dimethoyphenylboronic acid by employing Pd(PPh<sub>3</sub>)<sub>4</sub> as the catalyst and potassium carbonate as the base. Methoxy group removal was effected using HBr in the presence of acetic acid in the second step. Overall, two novel 9,10-diphenylanthracence-based compounds were synthesized in this work; standard spectroscopic techniques and high-resolution mass spectrometry were employed in their characterization. The photophysical properties of these compounds are also reported. These compounds are potentially useful as sensors, catalysts and building blocks for larger architectures. |
| format | Article |
| id | doaj-art-0a52865d53884d07abef5272b5f0e047 |
| institution | OA Journals |
| issn | 1422-8599 |
| language | English |
| publishDate | 2024-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj-art-0a52865d53884d07abef5272b5f0e0472025-08-20T01:55:42ZengMDPI AGMolbank1422-85992024-09-0120243M188410.3390/M18844-(10-Phenyl-9-Anthracenyl)-1,2-BenzenediolNicola Edwards0Kelsey Harris1Department of Chemistry, University of Saint Joseph, West Hartford, CT 06117, USADepartment of Chemistry, University of Saint Joseph, West Hartford, CT 06117, USAThe title compound, 4-(10-phenyl-9-anthracenyl)-1,2-benzenediol, was synthesized using a two-step protocol. In the first step, 9-phenyl,10-bromoanthracene was coupled to 3,4-dimethoyphenylboronic acid by employing Pd(PPh<sub>3</sub>)<sub>4</sub> as the catalyst and potassium carbonate as the base. Methoxy group removal was effected using HBr in the presence of acetic acid in the second step. Overall, two novel 9,10-diphenylanthracence-based compounds were synthesized in this work; standard spectroscopic techniques and high-resolution mass spectrometry were employed in their characterization. The photophysical properties of these compounds are also reported. These compounds are potentially useful as sensors, catalysts and building blocks for larger architectures.https://www.mdpi.com/1422-8599/2024/3/M1884diphenylanthraceneSuzuki–Miyaura couplingluminescencefluorescence |
| spellingShingle | Nicola Edwards Kelsey Harris 4-(10-Phenyl-9-Anthracenyl)-1,2-Benzenediol Molbank diphenylanthracene Suzuki–Miyaura coupling luminescence fluorescence |
| title | 4-(10-Phenyl-9-Anthracenyl)-1,2-Benzenediol |
| title_full | 4-(10-Phenyl-9-Anthracenyl)-1,2-Benzenediol |
| title_fullStr | 4-(10-Phenyl-9-Anthracenyl)-1,2-Benzenediol |
| title_full_unstemmed | 4-(10-Phenyl-9-Anthracenyl)-1,2-Benzenediol |
| title_short | 4-(10-Phenyl-9-Anthracenyl)-1,2-Benzenediol |
| title_sort | 4 10 phenyl 9 anthracenyl 1 2 benzenediol |
| topic | diphenylanthracene Suzuki–Miyaura coupling luminescence fluorescence |
| url | https://www.mdpi.com/1422-8599/2024/3/M1884 |
| work_keys_str_mv | AT nicolaedwards 410phenyl9anthracenyl12benzenediol AT kelseyharris 410phenyl9anthracenyl12benzenediol |