Synthesis, crystal structure, and Hirshfeld surface analysis of undecacarbonyl{tris[4-(methylsulfanyl)phenyl]arsine}-triangulo-triosmium(0)

Synthesis, crystal structure, and Hirshfeld surface analysis of undecacarbonyl{tris[4-(methylsulfanyl)phenyl]arsine}-triangulo-triosmium(0)

The title compound, [Os3(C21H21AsS3)(CO)11] or [Os3{As(C6H4SCH3)3}(CO)11], comprises a triangle of Os atoms, two of which are bonded to four carbonyl ligands. The third Os atom is bound to three carbonyl ligands, and the arsine ligand [As(C6H4SCH3)3] occupies the equatorial position. In the crystal,...

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Bibliographic Details
Main Authors: Siti Syaida Sirat, Mohd Mustaqim Rosli, Sang Loon Tan, Ibrahim Abdul Razak, Omar bin Shawkataly
Format: Article
Language:English
Published: International Union of Crystallography 2025-08-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
osmium
crystal-structure
cluster
hirshfeld surface analysis
Online Access:https://journals.iucr.org/paper?S2056989025006541
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