Synthesis, crystal structure, and Hirshfeld surface analysis of undecacarbonyl{tris[4-(methylsulfanyl)phenyl]arsine}-triangulo-triosmium(0)
The title compound, [Os3(C21H21AsS3)(CO)11] or [Os3{As(C6H4SCH3)3}(CO)11], comprises a triangle of Os atoms, two of which are bonded to four carbonyl ligands. The third Os atom is bound to three carbonyl ligands, and the arsine ligand [As(C6H4SCH3)3] occupies the equatorial position. In the crystal,...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2025-08-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | https://journals.iucr.org/paper?S2056989025006541 |
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| author | Siti Syaida Sirat Mohd Mustaqim Rosli Sang Loon Tan Ibrahim Abdul Razak Omar bin Shawkataly |
| author_facet | Siti Syaida Sirat Mohd Mustaqim Rosli Sang Loon Tan Ibrahim Abdul Razak Omar bin Shawkataly |
| author_sort | Siti Syaida Sirat |
| collection | DOAJ |
| description | The title compound, [Os3(C21H21AsS3)(CO)11] or [Os3{As(C6H4SCH3)3}(CO)11], comprises a triangle of Os atoms, two of which are bonded to four carbonyl ligands. The third Os atom is bound to three carbonyl ligands, and the arsine ligand [As(C6H4SCH3)3] occupies the equatorial position. In the crystal, the molecules are linked by C—H...O hydrogen bonds. To further analyse the intermolecular interactions, a Hirshfeld surface analysis was performed. Two out of the three methylsulfanyl groups are disordered over two sites with final refinement occupancy ratios of 0.612 (12):0.388 (12) and 0.620 (9):0.380 (9). |
| format | Article |
| id | doaj-art-0a204c6744db4c95a9db0c31de684fc4 |
| institution | Kabale University |
| issn | 2056-9890 |
| language | English |
| publishDate | 2025-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj-art-0a204c6744db4c95a9db0c31de684fc42025-08-20T03:44:29ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902025-08-0181876576910.1107/S2056989025006541tx2100Synthesis, crystal structure, and Hirshfeld surface analysis of undecacarbonyl{tris[4-(methylsulfanyl)phenyl]arsine}-triangulo-triosmium(0)Siti Syaida Sirat0Mohd Mustaqim Rosli1Sang Loon Tan2Ibrahim Abdul Razak3Omar bin Shawkataly4Faculty of Applied Sciences, Universiti Teknologi MARA, Cawangan Negeri Sembilan, Kampus Kuala Pilah, 72000 Kuala Pilah, Negeri Sembilan, MalaysiaX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, MalaysiaSunway Biofunctional Molecules Discovery Centre, Faculty of Medical and Life Sciences, Sunway University, 47500 Sunway City, MalaysiaX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, MalaysiaDepartment of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310 Skudai, Johor Bahru, MalaysiaThe title compound, [Os3(C21H21AsS3)(CO)11] or [Os3{As(C6H4SCH3)3}(CO)11], comprises a triangle of Os atoms, two of which are bonded to four carbonyl ligands. The third Os atom is bound to three carbonyl ligands, and the arsine ligand [As(C6H4SCH3)3] occupies the equatorial position. In the crystal, the molecules are linked by C—H...O hydrogen bonds. To further analyse the intermolecular interactions, a Hirshfeld surface analysis was performed. Two out of the three methylsulfanyl groups are disordered over two sites with final refinement occupancy ratios of 0.612 (12):0.388 (12) and 0.620 (9):0.380 (9).https://journals.iucr.org/paper?S2056989025006541osmiumcrystal-structureclusterhirshfeld surface analysis |
| spellingShingle | Siti Syaida Sirat Mohd Mustaqim Rosli Sang Loon Tan Ibrahim Abdul Razak Omar bin Shawkataly Synthesis, crystal structure, and Hirshfeld surface analysis of undecacarbonyl{tris[4-(methylsulfanyl)phenyl]arsine}-triangulo-triosmium(0) Acta Crystallographica Section E: Crystallographic Communications osmium crystal-structure cluster hirshfeld surface analysis |
| title | Synthesis, crystal structure, and Hirshfeld surface analysis of undecacarbonyl{tris[4-(methylsulfanyl)phenyl]arsine}-triangulo-triosmium(0) |
| title_full | Synthesis, crystal structure, and Hirshfeld surface analysis of undecacarbonyl{tris[4-(methylsulfanyl)phenyl]arsine}-triangulo-triosmium(0) |
| title_fullStr | Synthesis, crystal structure, and Hirshfeld surface analysis of undecacarbonyl{tris[4-(methylsulfanyl)phenyl]arsine}-triangulo-triosmium(0) |
| title_full_unstemmed | Synthesis, crystal structure, and Hirshfeld surface analysis of undecacarbonyl{tris[4-(methylsulfanyl)phenyl]arsine}-triangulo-triosmium(0) |
| title_short | Synthesis, crystal structure, and Hirshfeld surface analysis of undecacarbonyl{tris[4-(methylsulfanyl)phenyl]arsine}-triangulo-triosmium(0) |
| title_sort | synthesis crystal structure and hirshfeld surface analysis of undecacarbonyl tris 4 methylsulfanyl phenyl arsine triangulo triosmium 0 |
| topic | osmium crystal-structure cluster hirshfeld surface analysis |
| url | https://journals.iucr.org/paper?S2056989025006541 |
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