Temperature-dependent rigidity and magnetism of polyamide 6 nanocomposites based on nanocrystalline Fe-Ni alloy of various geometries
The focus of this study is to explore the potential use of Polyamide 6 nanocomposite reinforced with nanocrystalline (nc) Fe20Ni80 alloy (Fe20Ni80/PA6 PNC) in electromagnetic applications and provide understanding of how the alloy particle geometry is controlling the nanocomposite’s physical propert...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Budapest University of Technology and Economics
2016-10-01
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| Series: | eXPRESS Polymer Letters |
| Subjects: | |
| Online Access: | http://www.expresspolymlett.com/letolt.php?file=EPL-0007212&mi=cd |
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| Summary: | The focus of this study is to explore the potential use of Polyamide 6 nanocomposite reinforced with nanocrystalline (nc) Fe20Ni80 alloy (Fe20Ni80/PA6 PNC) in electromagnetic applications and provide understanding of how the alloy particle geometry is controlling the nanocomposite’s physical properties. Thermomechanical rigidity, room-temperature soft magnetic performance and thermal soft magnetic stability of Fe20Ni80/PA6 PNCs based on spherical-sea urchin alloy particles (UMB2-SU) and necklace-like alloy chains (UMB2-NC) have been investigated. Both PNCs have considerably superior bulk properties compared to neat PA6 and UMB2-SU exhibits the most remarkable overall performance. Morphological observations disclose two relevant phenomena: i) improved dispersion and distribution of the SU alloy particles than the NC ones within PA6 matrix, leading to stronger filler-matrix interfacial interactions within the UMB2-SU as compared to the UMB2-NC and ii) presence of constraint polymer regions in between alloy segments within the UMB2-SU that provide secondary reinforcing and soft magnetic mechanisms. Such phenomena along with the lower alloy crystallite size and PA6 γ-crystal type content within the UMB2-SU than in the UMB2-NC, are considered the main responsible factors for the distinctive performance of UMB2-SU. Overall, compared to various ferromagnetic nanocrystalline metallic materials, the research proposes the SU nc Fe20Ni80 alloy as a valuable nanofiller in polymers for electromagnetic applications. |
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| ISSN: | 1788-618X |