Production of Microcrystalline Cellulose Aerogels by Supercritical Gel Drying, for Water Remediation

Dye abundance in industrial wastewater is emerging as a critical issue in chemical engineering, due to their harmful impact on natural ecosystems equilibrium. Adsorption is a cost-effective and flexible unit operation to perform: however, its outcomes rely on the choice of the sorbent. Indeed, the a...

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Main Authors: Alessandra Zanotti, Stefano Cardea
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2025-07-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/15302
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author Alessandra Zanotti
Stefano Cardea
author_facet Alessandra Zanotti
Stefano Cardea
author_sort Alessandra Zanotti
collection DOAJ
description Dye abundance in industrial wastewater is emerging as a critical issue in chemical engineering, due to their harmful impact on natural ecosystems equilibrium. Adsorption is a cost-effective and flexible unit operation to perform: however, its outcomes rely on the choice of the sorbent. Indeed, the adsorbent should expose large surface areas, to optimize the performance-to-size ratio; it should be selective, and affine with the molecule to remove from the sludge. Moreover, it should be low-cost and biodegradable. Cellulose meets these last requirements: in this work, it has been processed by supercritical drying, in order to improve network interconnectivity and enhance active sites availability. The present research focuses on the efficacy of microcrystalline cellulose on removing different dyes, as well as the effect of supercritical drying operating conditions on adsorption performances, as well as. The present study outlined that the lower the carbon dioxide density is, the more likely is for the adsorption to worsen. Moreover, pristine cellulose results to be affine with cationic dyes, rather than anionic; on the other hand, adsorption is less favourable for linear molecules rather than more compact ones.
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institution Kabale University
issn 2283-9216
language English
publishDate 2025-07-01
publisher AIDIC Servizi S.r.l.
record_format Article
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spelling doaj-art-0948013455d94dac9b676aae42e0898f2025-08-20T03:58:36ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162025-07-01117Production of Microcrystalline Cellulose Aerogels by Supercritical Gel Drying, for Water RemediationAlessandra ZanottiStefano CardeaDye abundance in industrial wastewater is emerging as a critical issue in chemical engineering, due to their harmful impact on natural ecosystems equilibrium. Adsorption is a cost-effective and flexible unit operation to perform: however, its outcomes rely on the choice of the sorbent. Indeed, the adsorbent should expose large surface areas, to optimize the performance-to-size ratio; it should be selective, and affine with the molecule to remove from the sludge. Moreover, it should be low-cost and biodegradable. Cellulose meets these last requirements: in this work, it has been processed by supercritical drying, in order to improve network interconnectivity and enhance active sites availability. The present research focuses on the efficacy of microcrystalline cellulose on removing different dyes, as well as the effect of supercritical drying operating conditions on adsorption performances, as well as. The present study outlined that the lower the carbon dioxide density is, the more likely is for the adsorption to worsen. Moreover, pristine cellulose results to be affine with cationic dyes, rather than anionic; on the other hand, adsorption is less favourable for linear molecules rather than more compact ones.https://www.cetjournal.it/index.php/cet/article/view/15302
spellingShingle Alessandra Zanotti
Stefano Cardea
Production of Microcrystalline Cellulose Aerogels by Supercritical Gel Drying, for Water Remediation
Chemical Engineering Transactions
title Production of Microcrystalline Cellulose Aerogels by Supercritical Gel Drying, for Water Remediation
title_full Production of Microcrystalline Cellulose Aerogels by Supercritical Gel Drying, for Water Remediation
title_fullStr Production of Microcrystalline Cellulose Aerogels by Supercritical Gel Drying, for Water Remediation
title_full_unstemmed Production of Microcrystalline Cellulose Aerogels by Supercritical Gel Drying, for Water Remediation
title_short Production of Microcrystalline Cellulose Aerogels by Supercritical Gel Drying, for Water Remediation
title_sort production of microcrystalline cellulose aerogels by supercritical gel drying for water remediation
url https://www.cetjournal.it/index.php/cet/article/view/15302
work_keys_str_mv AT alessandrazanotti productionofmicrocrystallinecelluloseaerogelsbysupercriticalgeldryingforwaterremediation
AT stefanocardea productionofmicrocrystallinecelluloseaerogelsbysupercriticalgeldryingforwaterremediation