Recent research on chemically modifying the surface of zero-valent iron: A mini review
Zero-valent iron (ZVI) is a widely employed material for environmental remediation due to its capability to effectively degrade or reduce various pollutants. The enhancement of its reactivity and applicability can be achieved through chemical surface modification. Chemical surface modification invol...
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Elsevier
2025-03-01
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2666821125000067 |
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author | Zhendong Li Wei Ye Huiting Li Jianzhe Qiao Yunyi Du Zhujun Dong Lichun Fu Yuwei Pan |
author_facet | Zhendong Li Wei Ye Huiting Li Jianzhe Qiao Yunyi Du Zhujun Dong Lichun Fu Yuwei Pan |
author_sort | Zhendong Li |
collection | DOAJ |
description | Zero-valent iron (ZVI) is a widely employed material for environmental remediation due to its capability to effectively degrade or reduce various pollutants. The enhancement of its reactivity and applicability can be achieved through chemical surface modification. Chemical surface modification involves introducing specific chemical functional groups onto the surface of ZVI, altering its surface chemical properties and structural morphology. This article provides an overview of the advancements made in four commonly used chemical modifications of ZVI, namely ZVI sulfide, ZVI silicide, ZVI oxalate, and ZVI phosphate. The review examines the impacts of these four different modified compounds on the surface structure and reactivity of ZVI, as well as elucidates the mechanisms by which modified ZVI interacts with and removes pollutants. Furthermore, the article discusses the prospects and challenges associated with modified ZVI, offering valuable insights for future research and the application of environmental remediation technologies. |
format | Article |
id | doaj-art-0923ed316aa44587888dd9f1fbf9329d |
institution | Kabale University |
issn | 2666-8211 |
language | English |
publishDate | 2025-03-01 |
publisher | Elsevier |
record_format | Article |
series | Chemical Engineering Journal Advances |
spelling | doaj-art-0923ed316aa44587888dd9f1fbf9329d2025-02-03T04:17:05ZengElsevierChemical Engineering Journal Advances2666-82112025-03-0121100709Recent research on chemically modifying the surface of zero-valent iron: A mini reviewZhendong Li0Wei Ye1Huiting Li2Jianzhe Qiao3Yunyi Du4Zhujun Dong5Lichun Fu6Yuwei Pan7Laboratory of Environmental Protection in Water Transport Engineering, Tianjin Research Institute of Water Transport Engineering, Tanggu, Tianjin 300456, ChinaLaboratory of Environmental Protection in Water Transport Engineering, Tianjin Research Institute of Water Transport Engineering, Tanggu, Tianjin 300456, ChinaLaboratory of Environmental Protection in Water Transport Engineering, Tianjin Research Institute of Water Transport Engineering, Tanggu, Tianjin 300456, ChinaLaboratory of Environmental Protection in Water Transport Engineering, Tianjin Research Institute of Water Transport Engineering, Tanggu, Tianjin 300456, ChinaLaboratory of Environmental Protection in Water Transport Engineering, Tianjin Research Institute of Water Transport Engineering, Tanggu, Tianjin 300456, ChinaCollege of Biology and the Environment, Nanjing Forestry University, Nanjing 210037, China; Corresponding authors.School of Iron and Steel, Soochow University, Suzhou 215000, ChinaCollege of Biology and the Environment, Nanjing Forestry University, Nanjing 210037, China; Corresponding authors.Zero-valent iron (ZVI) is a widely employed material for environmental remediation due to its capability to effectively degrade or reduce various pollutants. The enhancement of its reactivity and applicability can be achieved through chemical surface modification. Chemical surface modification involves introducing specific chemical functional groups onto the surface of ZVI, altering its surface chemical properties and structural morphology. This article provides an overview of the advancements made in four commonly used chemical modifications of ZVI, namely ZVI sulfide, ZVI silicide, ZVI oxalate, and ZVI phosphate. The review examines the impacts of these four different modified compounds on the surface structure and reactivity of ZVI, as well as elucidates the mechanisms by which modified ZVI interacts with and removes pollutants. Furthermore, the article discusses the prospects and challenges associated with modified ZVI, offering valuable insights for future research and the application of environmental remediation technologies.http://www.sciencedirect.com/science/article/pii/S2666821125000067Advances in ZVI surface chemistryZVI reactivity enhancementEnvironmental remediation with modified ZVIAdvanced oxidation processes |
spellingShingle | Zhendong Li Wei Ye Huiting Li Jianzhe Qiao Yunyi Du Zhujun Dong Lichun Fu Yuwei Pan Recent research on chemically modifying the surface of zero-valent iron: A mini review Chemical Engineering Journal Advances Advances in ZVI surface chemistry ZVI reactivity enhancement Environmental remediation with modified ZVI Advanced oxidation processes |
title | Recent research on chemically modifying the surface of zero-valent iron: A mini review |
title_full | Recent research on chemically modifying the surface of zero-valent iron: A mini review |
title_fullStr | Recent research on chemically modifying the surface of zero-valent iron: A mini review |
title_full_unstemmed | Recent research on chemically modifying the surface of zero-valent iron: A mini review |
title_short | Recent research on chemically modifying the surface of zero-valent iron: A mini review |
title_sort | recent research on chemically modifying the surface of zero valent iron a mini review |
topic | Advances in ZVI surface chemistry ZVI reactivity enhancement Environmental remediation with modified ZVI Advanced oxidation processes |
url | http://www.sciencedirect.com/science/article/pii/S2666821125000067 |
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