NEW [SnR2(C2O4)2]2- (R = Ph, Bu) MOIETY CONTAINING ADDUCTS AND COMPLEXES: SYNTHESIS, INFRARED AND MOSSBAUER STUDIES
New oxalato and hydrogenoxalato organotin (IV) derivatives containing mono- and bichelating oxalates or a monochelating hydrogenoxalate, have been synthesized and characterized by elemental analyses, infrared and Mossbauer spectroscopy. The suggested structures are discrete, the environments around...
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2015-05-01
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| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
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| Online Access: | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201501&vol=1&aid=4204 |
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| _version_ | 1850146009185779712 |
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| author | YAYA SOW LIBASSE DIOP |
| author_facet | YAYA SOW LIBASSE DIOP |
| author_sort | YAYA SOW |
| collection | DOAJ |
| description | New oxalato and hydrogenoxalato organotin (IV) derivatives containing mono- and bichelating oxalates or a monochelating hydrogenoxalate, have been synthesized and characterized by elemental analyses, infrared and Mossbauer spectroscopy. The suggested structures are discrete, the environments around the tin (IV) atoms being trans octahedral, seven coordinated or tetrahedral. The cations when present are involved in NH…O bonds. A 1 D supramolecular architecture is suggested for SnPh2 (HC2O4)2.1/2 C6H6. The C6H6 molecules obtained in situ molecules are lattice. SnPh3OH is involved in hydrogen bonding. |
| format | Article |
| id | doaj-art-08fc933a08fd484aa42da198fc230e98 |
| institution | OA Journals |
| issn | 1582-540X 1582-540X |
| language | English |
| publishDate | 2015-05-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj-art-08fc933a08fd484aa42da198fc230e982025-08-20T02:27:57ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X1582-540X2015-05-01161061067NEW [SnR2(C2O4)2]2- (R = Ph, Bu) MOIETY CONTAINING ADDUCTS AND COMPLEXES: SYNTHESIS, INFRARED AND MOSSBAUER STUDIESYAYA SOW0LIBASSE DIOP1Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA) Dakar Sénégal Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA) Dakar Sénégal New oxalato and hydrogenoxalato organotin (IV) derivatives containing mono- and bichelating oxalates or a monochelating hydrogenoxalate, have been synthesized and characterized by elemental analyses, infrared and Mossbauer spectroscopy. The suggested structures are discrete, the environments around the tin (IV) atoms being trans octahedral, seven coordinated or tetrahedral. The cations when present are involved in NH…O bonds. A 1 D supramolecular architecture is suggested for SnPh2 (HC2O4)2.1/2 C6H6. The C6H6 molecules obtained in situ molecules are lattice. SnPh3OH is involved in hydrogen bonding.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201501&vol=1&aid=42041 D supramolecular architecturediscrete structureshydrogen bondsinfraredlattice benzene moleculesMossbauerseven coordinatedtrans octahedral or tetrahedral environments |
| spellingShingle | YAYA SOW LIBASSE DIOP NEW [SnR2(C2O4)2]2- (R = Ph, Bu) MOIETY CONTAINING ADDUCTS AND COMPLEXES: SYNTHESIS, INFRARED AND MOSSBAUER STUDIES Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry 1 D supramolecular architecture discrete structures hydrogen bonds infrared lattice benzene molecules Mossbauer seven coordinated trans octahedral or tetrahedral environments |
| title | NEW [SnR2(C2O4)2]2- (R = Ph, Bu) MOIETY CONTAINING ADDUCTS AND COMPLEXES: SYNTHESIS, INFRARED AND MOSSBAUER STUDIES |
| title_full | NEW [SnR2(C2O4)2]2- (R = Ph, Bu) MOIETY CONTAINING ADDUCTS AND COMPLEXES: SYNTHESIS, INFRARED AND MOSSBAUER STUDIES |
| title_fullStr | NEW [SnR2(C2O4)2]2- (R = Ph, Bu) MOIETY CONTAINING ADDUCTS AND COMPLEXES: SYNTHESIS, INFRARED AND MOSSBAUER STUDIES |
| title_full_unstemmed | NEW [SnR2(C2O4)2]2- (R = Ph, Bu) MOIETY CONTAINING ADDUCTS AND COMPLEXES: SYNTHESIS, INFRARED AND MOSSBAUER STUDIES |
| title_short | NEW [SnR2(C2O4)2]2- (R = Ph, Bu) MOIETY CONTAINING ADDUCTS AND COMPLEXES: SYNTHESIS, INFRARED AND MOSSBAUER STUDIES |
| title_sort | new snr2 c2o4 2 2 r ph bu moiety containing adducts and complexes synthesis infrared and mossbauer studies |
| topic | 1 D supramolecular architecture discrete structures hydrogen bonds infrared lattice benzene molecules Mossbauer seven coordinated trans octahedral or tetrahedral environments |
| url | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201501&vol=1&aid=4204 |
| work_keys_str_mv | AT yayasow newsnr2c2o422rphbumoietycontainingadductsandcomplexessynthesisinfraredandmossbauerstudies AT libassediop newsnr2c2o422rphbumoietycontainingadductsandcomplexessynthesisinfraredandmossbauerstudies |