Synthesis and Studies Pd(II)-NHC complexes with thiosaccharinate, saccharinate or benzothiazolinate ligands
Three cis-chelating di-N-heterocyclic carbene palladium(II) complexes [Pd(X)2(di- NHC)] (X= tsac, sac and bit) tsac= thiosaccharinate, sac= saccharinate, bit= benzisothiazolinate, bearing different anionic co-ligand was synthesized and characterized. A series of palladium(II) complexes (2-5) bearin...
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| Language: | English |
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Tikrit University
2023-01-01
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| Series: | Tikrit Journal of Pure Science |
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| Online Access: | https://tjpsj.org/index.php/tjps/article/view/633 |
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| author | Mohammed H.S. Al-Jibori Nabeel H. Buttrus Ahmed S.M. Al-Janabi |
| author_facet | Mohammed H.S. Al-Jibori Nabeel H. Buttrus Ahmed S.M. Al-Janabi |
| author_sort | Mohammed H.S. Al-Jibori |
| collection | DOAJ |
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Three cis-chelating di-N-heterocyclic carbene palladium(II) complexes [Pd(X)2(di- NHC)] (X= tsac, sac and bit) tsac= thiosaccharinate, sac= saccharinate, bit= benzisothiazolinate, bearing different anionic co-ligand was synthesized and characterized. A series of palladium(II) complexes (2-5) bearing cis-chelating homo-dicarbene ligand with varying propylene-bridged (C3) and N-heterocyclic backbones (imidazole) have been synthesized by reaction of [Pd(OAc)2] with the respective diazolium bromides in DMSO, have been prepared and characterized by elemental analysis, infrared spectra and 1H NMR. These compounds are all stabilized in the sold state. The bidentate (diNHC) ligand together with two N-coordenated sac , bit and two S-coordenated tsac ligand, from the square planar coordination geometry around the palladium(II) ion.
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| format | Article |
| id | doaj-art-08eb2fb4a7bc4031be88fa81def78e5d |
| institution | Kabale University |
| issn | 1813-1662 2415-1726 |
| language | English |
| publishDate | 2023-01-01 |
| publisher | Tikrit University |
| record_format | Article |
| series | Tikrit Journal of Pure Science |
| spelling | doaj-art-08eb2fb4a7bc4031be88fa81def78e5d2025-08-20T03:50:25ZengTikrit UniversityTikrit Journal of Pure Science1813-16622415-17262023-01-0122210.25130/tjps.v22i2.633Synthesis and Studies Pd(II)-NHC complexes with thiosaccharinate, saccharinate or benzothiazolinate ligandsMohammed H.S. Al-JiboriNabeel H. ButtrusAhmed S.M. Al-Janabi Three cis-chelating di-N-heterocyclic carbene palladium(II) complexes [Pd(X)2(di- NHC)] (X= tsac, sac and bit) tsac= thiosaccharinate, sac= saccharinate, bit= benzisothiazolinate, bearing different anionic co-ligand was synthesized and characterized. A series of palladium(II) complexes (2-5) bearing cis-chelating homo-dicarbene ligand with varying propylene-bridged (C3) and N-heterocyclic backbones (imidazole) have been synthesized by reaction of [Pd(OAc)2] with the respective diazolium bromides in DMSO, have been prepared and characterized by elemental analysis, infrared spectra and 1H NMR. These compounds are all stabilized in the sold state. The bidentate (diNHC) ligand together with two N-coordenated sac , bit and two S-coordenated tsac ligand, from the square planar coordination geometry around the palladium(II) ion. https://tjpsj.org/index.php/tjps/article/view/633PalladiumN-Heterocyclic carbinespectral study |
| spellingShingle | Mohammed H.S. Al-Jibori Nabeel H. Buttrus Ahmed S.M. Al-Janabi Synthesis and Studies Pd(II)-NHC complexes with thiosaccharinate, saccharinate or benzothiazolinate ligands Tikrit Journal of Pure Science Palladium N-Heterocyclic carbine spectral study |
| title | Synthesis and Studies Pd(II)-NHC complexes with thiosaccharinate, saccharinate or benzothiazolinate ligands |
| title_full | Synthesis and Studies Pd(II)-NHC complexes with thiosaccharinate, saccharinate or benzothiazolinate ligands |
| title_fullStr | Synthesis and Studies Pd(II)-NHC complexes with thiosaccharinate, saccharinate or benzothiazolinate ligands |
| title_full_unstemmed | Synthesis and Studies Pd(II)-NHC complexes with thiosaccharinate, saccharinate or benzothiazolinate ligands |
| title_short | Synthesis and Studies Pd(II)-NHC complexes with thiosaccharinate, saccharinate or benzothiazolinate ligands |
| title_sort | synthesis and studies pd ii nhc complexes with thiosaccharinate saccharinate or benzothiazolinate ligands |
| topic | Palladium N-Heterocyclic carbine spectral study |
| url | https://tjpsj.org/index.php/tjps/article/view/633 |
| work_keys_str_mv | AT mohammedhsaljibori synthesisandstudiespdiinhccomplexeswiththiosaccharinatesaccharinateorbenzothiazolinateligands AT nabeelhbuttrus synthesisandstudiespdiinhccomplexeswiththiosaccharinatesaccharinateorbenzothiazolinateligands AT ahmedsmaljanabi synthesisandstudiespdiinhccomplexeswiththiosaccharinatesaccharinateorbenzothiazolinateligands |