A Study of the Brönsted Site Acidity of Crystalline and Amorphous Aluminosilicates: 1. Desorption of Ammonia, Dehydration of 2-Propanol and Cracking of Cumene
The acidity of the H-form aluminosilicates, which include ZSM-5, mordenite, Y-faujasite, Al-containing aerosils and silica gels, and the layering of aluminosilicate compounds on an aerosil surface was measured by temperature-programmed mass spectrometry desorption (TPD) of NH 3 . It was found that t...
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| Format: | Article |
| Language: | English |
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SAGE Publishing
1996-12-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1177/026361749601400602 |
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| author | V.V. Brei V.A. Kaspersky K.N. Khomenko A.A. Chuiko |
| author_facet | V.V. Brei V.A. Kaspersky K.N. Khomenko A.A. Chuiko |
| author_sort | V.V. Brei |
| collection | DOAJ |
| description | The acidity of the H-form aluminosilicates, which include ZSM-5, mordenite, Y-faujasite, Al-containing aerosils and silica gels, and the layering of aluminosilicate compounds on an aerosil surface was measured by temperature-programmed mass spectrometry desorption (TPD) of NH 3 . It was found that the desorption energies of NH 3 decrease in the order: H-M > H-ZSM-5 > Al-aerosils> H-Y > CVD Al-silicates> Al-silica gels. The catalytic activities of the studied samples in 2-propanol dehydration and cumene cracking have been shown to decrease in the same order. |
| format | Article |
| id | doaj-art-0888e0c61366429aa97b6a2b6ac79c48 |
| institution | Kabale University |
| issn | 0263-6174 2048-4038 |
| language | English |
| publishDate | 1996-12-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj-art-0888e0c61366429aa97b6a2b6ac79c482025-02-03T10:07:33ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40381996-12-011410.1177/026361749601400602A Study of the Brönsted Site Acidity of Crystalline and Amorphous Aluminosilicates: 1. Desorption of Ammonia, Dehydration of 2-Propanol and Cracking of CumeneV.V. BreiV.A. KasperskyK.N. KhomenkoA.A. ChuikoThe acidity of the H-form aluminosilicates, which include ZSM-5, mordenite, Y-faujasite, Al-containing aerosils and silica gels, and the layering of aluminosilicate compounds on an aerosil surface was measured by temperature-programmed mass spectrometry desorption (TPD) of NH 3 . It was found that the desorption energies of NH 3 decrease in the order: H-M > H-ZSM-5 > Al-aerosils> H-Y > CVD Al-silicates> Al-silica gels. The catalytic activities of the studied samples in 2-propanol dehydration and cumene cracking have been shown to decrease in the same order.https://doi.org/10.1177/026361749601400602 |
| spellingShingle | V.V. Brei V.A. Kaspersky K.N. Khomenko A.A. Chuiko A Study of the Brönsted Site Acidity of Crystalline and Amorphous Aluminosilicates: 1. Desorption of Ammonia, Dehydration of 2-Propanol and Cracking of Cumene Adsorption Science & Technology |
| title | A Study of the Brönsted Site Acidity of Crystalline and Amorphous Aluminosilicates: 1. Desorption of Ammonia, Dehydration of 2-Propanol and Cracking of Cumene |
| title_full | A Study of the Brönsted Site Acidity of Crystalline and Amorphous Aluminosilicates: 1. Desorption of Ammonia, Dehydration of 2-Propanol and Cracking of Cumene |
| title_fullStr | A Study of the Brönsted Site Acidity of Crystalline and Amorphous Aluminosilicates: 1. Desorption of Ammonia, Dehydration of 2-Propanol and Cracking of Cumene |
| title_full_unstemmed | A Study of the Brönsted Site Acidity of Crystalline and Amorphous Aluminosilicates: 1. Desorption of Ammonia, Dehydration of 2-Propanol and Cracking of Cumene |
| title_short | A Study of the Brönsted Site Acidity of Crystalline and Amorphous Aluminosilicates: 1. Desorption of Ammonia, Dehydration of 2-Propanol and Cracking of Cumene |
| title_sort | study of the bronsted site acidity of crystalline and amorphous aluminosilicates 1 desorption of ammonia dehydration of 2 propanol and cracking of cumene |
| url | https://doi.org/10.1177/026361749601400602 |
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