A Study of the Brönsted Site Acidity of Crystalline and Amorphous Aluminosilicates: 1. Desorption of Ammonia, Dehydration of 2-Propanol and Cracking of Cumene
The acidity of the H-form aluminosilicates, which include ZSM-5, mordenite, Y-faujasite, Al-containing aerosils and silica gels, and the layering of aluminosilicate compounds on an aerosil surface was measured by temperature-programmed mass spectrometry desorption (TPD) of NH 3 . It was found that t...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
SAGE Publishing
1996-12-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1177/026361749601400602 |
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| Summary: | The acidity of the H-form aluminosilicates, which include ZSM-5, mordenite, Y-faujasite, Al-containing aerosils and silica gels, and the layering of aluminosilicate compounds on an aerosil surface was measured by temperature-programmed mass spectrometry desorption (TPD) of NH 3 . It was found that the desorption energies of NH 3 decrease in the order: H-M > H-ZSM-5 > Al-aerosils> H-Y > CVD Al-silicates> Al-silica gels. The catalytic activities of the studied samples in 2-propanol dehydration and cumene cracking have been shown to decrease in the same order. |
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| ISSN: | 0263-6174 2048-4038 |