Effects of Ti raw materials on microstructure and properties of W–Ti alloys

Tungsten–titanium alloys were obtained by high-energy ball milling and vacuum hot-pressing sintering, using titanium hydride powders, irregularly shaped Ti powders, and spherical Ti powders as the titanium source, mixing with pure tungsten powders as the raw materials. The phase composition, microst...

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Main Authors: XU Yanting, ZHAO Qi, SHEN Yue, ZHAO Zongyan, Wang Chuanjun, SHI Chenqi, WEN Ming
Format: Article
Language:zho
Published: Editorial Office of Powder Metallurgy Technology 2025-06-01
Series:Fenmo yejin jishu
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Online Access:https://pmt.ustb.edu.cn/article/doi/10.19591/j.cnki.cn11-1974/tf.2024040019
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author XU Yanting
ZHAO Qi
SHEN Yue
ZHAO Zongyan
Wang Chuanjun
SHI Chenqi
WEN Ming
author_facet XU Yanting
ZHAO Qi
SHEN Yue
ZHAO Zongyan
Wang Chuanjun
SHI Chenqi
WEN Ming
author_sort XU Yanting
collection DOAJ
description Tungsten–titanium alloys were obtained by high-energy ball milling and vacuum hot-pressing sintering, using titanium hydride powders, irregularly shaped Ti powders, and spherical Ti powders as the titanium source, mixing with pure tungsten powders as the raw materials. The phase composition, microstructure, grain size, relative density, and hardness of tungsten–titanium alloy were measured and studied by X-ray diffractometer, scanning electron microscope, and Vickers hardness tester. The results show that the black titanium-rich phases (β1(Ti,W)) are observed to be distributed in the gray tungsten-rich phases (β2(Ti,W)) of the tungsten–titanium alloys using the three titanium source. The relative density of all these samples exceeds 99%, meeting the compactness requirements for the conventional high-performance target materials. Due to the physicochemical difference of the titanium source, the distribution and particle size of β1(Ti,W) in the tungsten–titanium alloys are different. The tungsten–titanium alloys prepared with TiH2 powders as the titanium source show the best performance. The β1(Ti,W) distribution is uniform, and the grain size is fine; the mutual diffusion rate between tungsten and titanium is higher, and the solid solubility is higher; the relative density and mechanical properties are the best, the relative density is 99.66%, and the hardness is HV (678.88±15.25).
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institution Kabale University
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language zho
publishDate 2025-06-01
publisher Editorial Office of Powder Metallurgy Technology
record_format Article
series Fenmo yejin jishu
spelling doaj-art-081f59cfe94a4b2c8a4eb03de9d60c352025-08-20T03:50:21ZzhoEditorial Office of Powder Metallurgy TechnologyFenmo yejin jishu1001-37842025-06-0143331732410.19591/j.cnki.cn11-1974/tf.2024040019Effects of Ti raw materials on microstructure and properties of W–Ti alloysXU YantingZHAO Qi0SHEN YueZHAO Zongyan1Wang ChuanjunSHI Chenqi2WEN MingYunnan Precious Metals Laboratory Co., Ltd., Kunming 650106, ChinaFaculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaYunnan Precious Metals Laboratory Co., Ltd., Kunming 650106, ChinaTungsten–titanium alloys were obtained by high-energy ball milling and vacuum hot-pressing sintering, using titanium hydride powders, irregularly shaped Ti powders, and spherical Ti powders as the titanium source, mixing with pure tungsten powders as the raw materials. The phase composition, microstructure, grain size, relative density, and hardness of tungsten–titanium alloy were measured and studied by X-ray diffractometer, scanning electron microscope, and Vickers hardness tester. The results show that the black titanium-rich phases (β1(Ti,W)) are observed to be distributed in the gray tungsten-rich phases (β2(Ti,W)) of the tungsten–titanium alloys using the three titanium source. The relative density of all these samples exceeds 99%, meeting the compactness requirements for the conventional high-performance target materials. Due to the physicochemical difference of the titanium source, the distribution and particle size of β1(Ti,W) in the tungsten–titanium alloys are different. The tungsten–titanium alloys prepared with TiH2 powders as the titanium source show the best performance. The β1(Ti,W) distribution is uniform, and the grain size is fine; the mutual diffusion rate between tungsten and titanium is higher, and the solid solubility is higher; the relative density and mechanical properties are the best, the relative density is 99.66%, and the hardness is HV (678.88±15.25).https://pmt.ustb.edu.cn/article/doi/10.19591/j.cnki.cn11-1974/tf.2024040019tungsten–titanium alloysti raw materialstarget materialsphase compositiongrain size
spellingShingle XU Yanting
ZHAO Qi
SHEN Yue
ZHAO Zongyan
Wang Chuanjun
SHI Chenqi
WEN Ming
Effects of Ti raw materials on microstructure and properties of W–Ti alloys
Fenmo yejin jishu
tungsten–titanium alloys
ti raw materials
target materials
phase composition
grain size
title Effects of Ti raw materials on microstructure and properties of W–Ti alloys
title_full Effects of Ti raw materials on microstructure and properties of W–Ti alloys
title_fullStr Effects of Ti raw materials on microstructure and properties of W–Ti alloys
title_full_unstemmed Effects of Ti raw materials on microstructure and properties of W–Ti alloys
title_short Effects of Ti raw materials on microstructure and properties of W–Ti alloys
title_sort effects of ti raw materials on microstructure and properties of w ti alloys
topic tungsten–titanium alloys
ti raw materials
target materials
phase composition
grain size
url https://pmt.ustb.edu.cn/article/doi/10.19591/j.cnki.cn11-1974/tf.2024040019
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AT zhaozongyan effectsoftirawmaterialsonmicrostructureandpropertiesofwtialloys
AT wangchuanjun effectsoftirawmaterialsonmicrostructureandpropertiesofwtialloys
AT shichenqi effectsoftirawmaterialsonmicrostructureandpropertiesofwtialloys
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