Tricalcium phosphate-based capillary suspensions as inks for 3D printing of porous scaffolds

Direct Ink Writing (DIW) has been extensively studied for creating hierarchical porous structures over recent decades. It finds applications in various fields, including aeronautics, industry, energy, and healthcare. On the other hand, capillary suspensions are an emerging field with significant pot...

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Main Authors: Souhaila Nider, Femke De Ceulaer, Berfu Göksel, Annabel Braem, Erin Koos
Format: Article
Language:English
Published: Elsevier 2025-03-01
Series:Open Ceramics
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Online Access:http://www.sciencedirect.com/science/article/pii/S2666539525000112
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author Souhaila Nider
Femke De Ceulaer
Berfu Göksel
Annabel Braem
Erin Koos
author_facet Souhaila Nider
Femke De Ceulaer
Berfu Göksel
Annabel Braem
Erin Koos
author_sort Souhaila Nider
collection DOAJ
description Direct Ink Writing (DIW) has been extensively studied for creating hierarchical porous structures over recent decades. It finds applications in various fields, including aeronautics, industry, energy, and healthcare. On the other hand, capillary suspensions are an emerging field with significant potential for porous material development. These suspensions, typically three-phase systems, consist of solid particles interconnected by a secondary fluid (usually < 5 vol%), which is immiscible with the main one. Upon fluid removal and subsequent thermal treatment, they form a spanning particle network.This study explores the utilisation of β-TCP-based capillary suspensions as DIW inks for fabricating hierarchically porous scaffolds with two different secondary fluids. Rheological assessment of the inks demonstrates shear thinning behaviour, high yield stress, high moduli, and network rebuilding capabilities. While sucrose-based inks exhibit better printability, the ink incorporating silica nanoparticles exhibit structures with the highest porosity.
format Article
id doaj-art-081b66cd212846ac89de2491a5640673
institution Kabale University
issn 2666-5395
language English
publishDate 2025-03-01
publisher Elsevier
record_format Article
series Open Ceramics
spelling doaj-art-081b66cd212846ac89de2491a56406732025-02-10T04:34:58ZengElsevierOpen Ceramics2666-53952025-03-0121100744Tricalcium phosphate-based capillary suspensions as inks for 3D printing of porous scaffoldsSouhaila Nider0Femke De Ceulaer1Berfu Göksel2Annabel Braem3Erin Koos4KU Leuven, Department of Chemical Engineering, Leuven, Belgium; Corresponding authors.KU Leuven, Department of Chemical Engineering, Leuven, BelgiumKU Leuven, Department of Materials Engineering, Leuven, BelgiumKU Leuven, Department of Materials Engineering, Leuven, BelgiumKU Leuven, Department of Chemical Engineering, Leuven, Belgium; Corresponding authors.Direct Ink Writing (DIW) has been extensively studied for creating hierarchical porous structures over recent decades. It finds applications in various fields, including aeronautics, industry, energy, and healthcare. On the other hand, capillary suspensions are an emerging field with significant potential for porous material development. These suspensions, typically three-phase systems, consist of solid particles interconnected by a secondary fluid (usually < 5 vol%), which is immiscible with the main one. Upon fluid removal and subsequent thermal treatment, they form a spanning particle network.This study explores the utilisation of β-TCP-based capillary suspensions as DIW inks for fabricating hierarchically porous scaffolds with two different secondary fluids. Rheological assessment of the inks demonstrates shear thinning behaviour, high yield stress, high moduli, and network rebuilding capabilities. While sucrose-based inks exhibit better printability, the ink incorporating silica nanoparticles exhibit structures with the highest porosity.http://www.sciencedirect.com/science/article/pii/S2666539525000112Direct ink writingTricalcium phosphatePorous ceramicsMicrostructure
spellingShingle Souhaila Nider
Femke De Ceulaer
Berfu Göksel
Annabel Braem
Erin Koos
Tricalcium phosphate-based capillary suspensions as inks for 3D printing of porous scaffolds
Open Ceramics
Direct ink writing
Tricalcium phosphate
Porous ceramics
Microstructure
title Tricalcium phosphate-based capillary suspensions as inks for 3D printing of porous scaffolds
title_full Tricalcium phosphate-based capillary suspensions as inks for 3D printing of porous scaffolds
title_fullStr Tricalcium phosphate-based capillary suspensions as inks for 3D printing of porous scaffolds
title_full_unstemmed Tricalcium phosphate-based capillary suspensions as inks for 3D printing of porous scaffolds
title_short Tricalcium phosphate-based capillary suspensions as inks for 3D printing of porous scaffolds
title_sort tricalcium phosphate based capillary suspensions as inks for 3d printing of porous scaffolds
topic Direct ink writing
Tricalcium phosphate
Porous ceramics
Microstructure
url http://www.sciencedirect.com/science/article/pii/S2666539525000112
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