Nitrate-Bridged One-Dimension Coordination Polymer Self-Assembled from a N4O2-Tetraiminodiphenolate Dicopper(II) Macrocyclic Complex

Herein we report on the synthesis and single crystal X-ray structure characterization of [{Cu2(tidf)(μ-NO3)}∞]ClO4 (tidf = a Robson type macrocyclic ligand obtained upon condensation of 2,6-diformyl-4-methylphenol and 1,3-diaminopropane). The coordination geometry around the copper(II) is square-pyr...

Full description

Saved in:
Bibliographic Details
Main Authors: Julio Cesar da Rocha, Priscilla J. Zambiazi, Manfredo Hörner, Fábio Souza Nunes
Format: Article
Language:English
Published: Wiley 2015-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2015/870834
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1849305440096092160
author Julio Cesar da Rocha
Priscilla J. Zambiazi
Manfredo Hörner
Fábio Souza Nunes
author_facet Julio Cesar da Rocha
Priscilla J. Zambiazi
Manfredo Hörner
Fábio Souza Nunes
author_sort Julio Cesar da Rocha
collection DOAJ
description Herein we report on the synthesis and single crystal X-ray structure characterization of [{Cu2(tidf)(μ-NO3)}∞]ClO4 (tidf = a Robson type macrocyclic ligand obtained upon condensation of 2,6-diformyl-4-methylphenol and 1,3-diaminopropane). The coordination geometry around the copper(II) is square-pyramidal and has [Cu2(tidf)]2+ units connected to each other through nitrate bridges extending as a one-dimension coordination polymer. The compound exhibits an extensive supramolecular structure supported by nonclassic hydrogen bonding between C-H⋯Operchlorate and C-H⋯Onitrate.
format Article
id doaj-art-08092b2c314e44e6b260ebe02ca6c555
institution Kabale University
issn 2090-9063
2090-9071
language English
publishDate 2015-01-01
publisher Wiley
record_format Article
series Journal of Chemistry
spelling doaj-art-08092b2c314e44e6b260ebe02ca6c5552025-08-20T03:55:27ZengWileyJournal of Chemistry2090-90632090-90712015-01-01201510.1155/2015/870834870834Nitrate-Bridged One-Dimension Coordination Polymer Self-Assembled from a N4O2-Tetraiminodiphenolate Dicopper(II) Macrocyclic ComplexJulio Cesar da Rocha0Priscilla J. Zambiazi1Manfredo Hörner2Fábio Souza Nunes3Departamento de Química, Universidade Federal do Paraná, Cx. Postal 19081, 81531-990 Curitiba, PR, BrazilDepartamento de Química, Universidade Federal de Santa Maria, 97105-900 Santa Maria, RS, BrazilDepartamento de Química, Universidade Federal de Santa Maria, 97105-900 Santa Maria, RS, BrazilDepartamento de Química, Universidade Federal do Paraná, Cx. Postal 19081, 81531-990 Curitiba, PR, BrazilHerein we report on the synthesis and single crystal X-ray structure characterization of [{Cu2(tidf)(μ-NO3)}∞]ClO4 (tidf = a Robson type macrocyclic ligand obtained upon condensation of 2,6-diformyl-4-methylphenol and 1,3-diaminopropane). The coordination geometry around the copper(II) is square-pyramidal and has [Cu2(tidf)]2+ units connected to each other through nitrate bridges extending as a one-dimension coordination polymer. The compound exhibits an extensive supramolecular structure supported by nonclassic hydrogen bonding between C-H⋯Operchlorate and C-H⋯Onitrate.http://dx.doi.org/10.1155/2015/870834
spellingShingle Julio Cesar da Rocha
Priscilla J. Zambiazi
Manfredo Hörner
Fábio Souza Nunes
Nitrate-Bridged One-Dimension Coordination Polymer Self-Assembled from a N4O2-Tetraiminodiphenolate Dicopper(II) Macrocyclic Complex
Journal of Chemistry
title Nitrate-Bridged One-Dimension Coordination Polymer Self-Assembled from a N4O2-Tetraiminodiphenolate Dicopper(II) Macrocyclic Complex
title_full Nitrate-Bridged One-Dimension Coordination Polymer Self-Assembled from a N4O2-Tetraiminodiphenolate Dicopper(II) Macrocyclic Complex
title_fullStr Nitrate-Bridged One-Dimension Coordination Polymer Self-Assembled from a N4O2-Tetraiminodiphenolate Dicopper(II) Macrocyclic Complex
title_full_unstemmed Nitrate-Bridged One-Dimension Coordination Polymer Self-Assembled from a N4O2-Tetraiminodiphenolate Dicopper(II) Macrocyclic Complex
title_short Nitrate-Bridged One-Dimension Coordination Polymer Self-Assembled from a N4O2-Tetraiminodiphenolate Dicopper(II) Macrocyclic Complex
title_sort nitrate bridged one dimension coordination polymer self assembled from a n4o2 tetraiminodiphenolate dicopper ii macrocyclic complex
url http://dx.doi.org/10.1155/2015/870834
work_keys_str_mv AT juliocesardarocha nitratebridgedonedimensioncoordinationpolymerselfassembledfroman4o2tetraiminodiphenolatedicopperiimacrocycliccomplex
AT priscillajzambiazi nitratebridgedonedimensioncoordinationpolymerselfassembledfroman4o2tetraiminodiphenolatedicopperiimacrocycliccomplex
AT manfredohorner nitratebridgedonedimensioncoordinationpolymerselfassembledfroman4o2tetraiminodiphenolatedicopperiimacrocycliccomplex
AT fabiosouzanunes nitratebridgedonedimensioncoordinationpolymerselfassembledfroman4o2tetraiminodiphenolatedicopperiimacrocycliccomplex