Nitrate-Bridged One-Dimension Coordination Polymer Self-Assembled from a N4O2-Tetraiminodiphenolate Dicopper(II) Macrocyclic Complex
Herein we report on the synthesis and single crystal X-ray structure characterization of [{Cu2(tidf)(μ-NO3)}∞]ClO4 (tidf = a Robson type macrocyclic ligand obtained upon condensation of 2,6-diformyl-4-methylphenol and 1,3-diaminopropane). The coordination geometry around the copper(II) is square-pyr...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley
2015-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2015/870834 |
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| Summary: | Herein we report on the synthesis and single crystal X-ray structure characterization of [{Cu2(tidf)(μ-NO3)}∞]ClO4 (tidf = a Robson type macrocyclic ligand obtained upon condensation of 2,6-diformyl-4-methylphenol and 1,3-diaminopropane). The coordination geometry around the copper(II) is square-pyramidal and has [Cu2(tidf)]2+ units connected to each other through nitrate bridges extending as a one-dimension coordination polymer. The compound exhibits an extensive supramolecular structure supported by nonclassic hydrogen bonding between C-H⋯Operchlorate and C-H⋯Onitrate. |
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| ISSN: | 2090-9063 2090-9071 |