Multifunctional composite phase change materials with CNTs/SiC-modified epoxy coating for synergistically enhanced solar energy storage and photothermal conversion

Multifunctional composite phase change materials with CNTs/SiC-modified epoxy coating for synergistically enhanced solar energy storage and photothermal conversion

Developing multifunctional composite phase change materials (PCMs) featuring enhanced photothermal energy conversion and storage performance is of vital importance, yet traditional organic PCMs suffer from inherent drawbacks, including leakage and poor thermal conductivity throughout the phase chang...

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Bibliographic Details
Main Authors: Meng Fu, Youchong Hu, Shuai Luo, Yuanyuan Li, Yaoqi Huang, Xiaomin Cheng
Format: Article
Language:English
Published: Elsevier 2025-10-01
Series:Materials & Design
Subjects:
Phase change material
Solar energy
Photothermal conversion
Carbon foam
Modified epoxy resin
Online Access:http://www.sciencedirect.com/science/article/pii/S026412752500989X
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Summary:Developing multifunctional composite phase change materials (PCMs) featuring enhanced photothermal energy conversion and storage performance is of vital importance, yet traditional organic PCMs suffer from inherent drawbacks, including leakage and poor thermal conductivity throughout the phase change process. To solve this problem, a new PCM design is provided, where stearic acid (SA) was employed as a latent heat storage unit, and carbon foam (CF) was served as a supporting framework. In this design, CNTs/SiC composite nanoparticles were uniformly dispersed into epoxy resin (ER) to fabricate a photothermal conversion coating. The modified epoxy resin (MER) coating acted as a protective effect for the internal PCMs, effectively mitigating leakage during phase transitions. With the incorporation of 9 wt% CNTs/SiC, the prepared composite PCMs retained the high latent heat (143.5J⋅g−1) and excellent photothermal conversion efficiency (96.76 %). Furthermore, the latent heat of the material showed a minimal reduction of only 0.4 % following 200 thermal cycles. These results demonstrate the potential of composite PCMs for efficient solar energy harvesting and storage in thermal regulation systems.
ISSN:0264-1275

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