Collision-induced Absorption Spectra of N2 and CH4

Collision-induced spectra are essential for radiative transfer modeling of Titan's atmosphere. We present experimental spectra of nitrogen–methane mixtures with an accompanying fit of N _2 -CH _4 collision-induced absorption in the 30–400 cm ^−1 region at about 130 K. We found a peak absorption...

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Main Authors: Ryan M. Johnson, Peter F. Bernath, Brant Billinghurst, Jianbao Zhao
Format: Article
Language:English
Published: IOP Publishing 2025-01-01
Series:The Astrophysical Journal
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Online Access:https://doi.org/10.3847/1538-4357/ada24a
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author Ryan M. Johnson
Peter F. Bernath
Brant Billinghurst
Jianbao Zhao
author_facet Ryan M. Johnson
Peter F. Bernath
Brant Billinghurst
Jianbao Zhao
author_sort Ryan M. Johnson
collection DOAJ
description Collision-induced spectra are essential for radiative transfer modeling of Titan's atmosphere. We present experimental spectra of nitrogen–methane mixtures with an accompanying fit of N _2 -CH _4 collision-induced absorption in the 30–400 cm ^−1 region at about 130 K. We found a peak absorption of 2.30 × 10 ^−5 cm ^−1 amagat ^−2 at 75 cm ^−1 and a secondary peak of 1.35 × 10 ^−5 cm ^−1 amagat ^−2 at 206.5 cm ^−1 , which agrees with previous studies. Our work does not support the suggestion that N _2 -CH _4 CIA in the far-infrared should be increased by about 50%, as suggested by spectroscopic modeling of Titan using data from A. Borysow & C. Tang.
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spelling doaj-art-07d7f5b20e594aa2b802b37da8665bea2025-01-23T08:14:33ZengIOP PublishingThe Astrophysical Journal1538-43572025-01-01979214910.3847/1538-4357/ada24aCollision-induced Absorption Spectra of N2 and CH4Ryan M. Johnson0https://orcid.org/0000-0001-6363-8499Peter F. Bernath1https://orcid.org/0000-0002-1255-396XBrant Billinghurst2Jianbao Zhao3https://orcid.org/0000-0003-3864-2167Department of Physics, Old Dominion University , Norfolk, VA 23529, USA ; rjohn032@odu.eduDepartment of Physics, Old Dominion University , Norfolk, VA 23529, USA ; rjohn032@odu.edu; Department of Chemistry and Biochemistry, Old Dominion University , Norfolk, VA 23529, USACanadian Light Source Far-Infrared Beamline , 44 Innovation Blvd., Saskatoon, SK S7N 2V3, CanadaCanadian Light Source Far-Infrared Beamline , 44 Innovation Blvd., Saskatoon, SK S7N 2V3, CanadaCollision-induced spectra are essential for radiative transfer modeling of Titan's atmosphere. We present experimental spectra of nitrogen–methane mixtures with an accompanying fit of N _2 -CH _4 collision-induced absorption in the 30–400 cm ^−1 region at about 130 K. We found a peak absorption of 2.30 × 10 ^−5 cm ^−1 amagat ^−2 at 75 cm ^−1 and a secondary peak of 1.35 × 10 ^−5 cm ^−1 amagat ^−2 at 206.5 cm ^−1 , which agrees with previous studies. Our work does not support the suggestion that N _2 -CH _4 CIA in the far-infrared should be increased by about 50%, as suggested by spectroscopic modeling of Titan using data from A. Borysow & C. Tang.https://doi.org/10.3847/1538-4357/ada24aCollision physicsTitanRadiative transferAtmospheric extinction
spellingShingle Ryan M. Johnson
Peter F. Bernath
Brant Billinghurst
Jianbao Zhao
Collision-induced Absorption Spectra of N2 and CH4
The Astrophysical Journal
Collision physics
Titan
Radiative transfer
Atmospheric extinction
title Collision-induced Absorption Spectra of N2 and CH4
title_full Collision-induced Absorption Spectra of N2 and CH4
title_fullStr Collision-induced Absorption Spectra of N2 and CH4
title_full_unstemmed Collision-induced Absorption Spectra of N2 and CH4
title_short Collision-induced Absorption Spectra of N2 and CH4
title_sort collision induced absorption spectra of n2 and ch4
topic Collision physics
Titan
Radiative transfer
Atmospheric extinction
url https://doi.org/10.3847/1538-4357/ada24a
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