Black Titanium Dioxide Nanomaterials in Photocatalysis

Titanium dioxide (TiO2) nanomaterials are widely considered to be state-of-the-art photocatalysts for environmental protection and energy conversion. However, the low photocatalytic efficiency caused by large bandgap and rapid recombination of photo-excited electrons and holes is a challenging issue...

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Main Authors: Xiaodong Yan, Yong Li, Ting Xia
Format: Article
Language:English
Published: Wiley 2017-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2017/8529851
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author Xiaodong Yan
Yong Li
Ting Xia
author_facet Xiaodong Yan
Yong Li
Ting Xia
author_sort Xiaodong Yan
collection DOAJ
description Titanium dioxide (TiO2) nanomaterials are widely considered to be state-of-the-art photocatalysts for environmental protection and energy conversion. However, the low photocatalytic efficiency caused by large bandgap and rapid recombination of photo-excited electrons and holes is a challenging issue that needs to be settled for their practical applications. Structure engineering has been demonstrated to be a highly promising approach to engineer the optical and electronic properties of the existing materials or even endow them with unexpected properties. Surface structure engineering has witnessed the breakthrough in increasing the photocatalytic efficiency of TiO2 nanomaterials by creating a defect-rich or amorphous surface layer with black color and extension of optical absorption to the whole visible spectrum, along with markedly enhanced photocatalytic activities. In this review, the recent progress in the development of black TiO2 nanomaterials is reviewed to gain a better understanding of the structure-property relationship with the consideration of preparation methods and to project new insights into the future development of black TiO2 nanomaterials in photocatalytic applications.
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institution Kabale University
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publishDate 2017-01-01
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spelling doaj-art-07cf676b1dee4634b76f46cc47c7ccd82025-08-20T03:55:28ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2017-01-01201710.1155/2017/85298518529851Black Titanium Dioxide Nanomaterials in PhotocatalysisXiaodong Yan0Yong Li1Ting Xia2Department of Chemistry, University of Missouri-Kansas City, Kansas City, MO 64110, USADepartment of Chemistry, University of Missouri-Kansas City, Kansas City, MO 64110, USADepartment of Chemistry, University of Missouri-Kansas City, Kansas City, MO 64110, USATitanium dioxide (TiO2) nanomaterials are widely considered to be state-of-the-art photocatalysts for environmental protection and energy conversion. However, the low photocatalytic efficiency caused by large bandgap and rapid recombination of photo-excited electrons and holes is a challenging issue that needs to be settled for their practical applications. Structure engineering has been demonstrated to be a highly promising approach to engineer the optical and electronic properties of the existing materials or even endow them with unexpected properties. Surface structure engineering has witnessed the breakthrough in increasing the photocatalytic efficiency of TiO2 nanomaterials by creating a defect-rich or amorphous surface layer with black color and extension of optical absorption to the whole visible spectrum, along with markedly enhanced photocatalytic activities. In this review, the recent progress in the development of black TiO2 nanomaterials is reviewed to gain a better understanding of the structure-property relationship with the consideration of preparation methods and to project new insights into the future development of black TiO2 nanomaterials in photocatalytic applications.http://dx.doi.org/10.1155/2017/8529851
spellingShingle Xiaodong Yan
Yong Li
Ting Xia
Black Titanium Dioxide Nanomaterials in Photocatalysis
International Journal of Photoenergy
title Black Titanium Dioxide Nanomaterials in Photocatalysis
title_full Black Titanium Dioxide Nanomaterials in Photocatalysis
title_fullStr Black Titanium Dioxide Nanomaterials in Photocatalysis
title_full_unstemmed Black Titanium Dioxide Nanomaterials in Photocatalysis
title_short Black Titanium Dioxide Nanomaterials in Photocatalysis
title_sort black titanium dioxide nanomaterials in photocatalysis
url http://dx.doi.org/10.1155/2017/8529851
work_keys_str_mv AT xiaodongyan blacktitaniumdioxidenanomaterialsinphotocatalysis
AT yongli blacktitaniumdioxidenanomaterialsinphotocatalysis
AT tingxia blacktitaniumdioxidenanomaterialsinphotocatalysis