Prussian Blue analogs and transition metal K-edge XMCD: a longstanding friendship
Prussian Blue analogs (PBAs) are well-known coordination polymers offering a wide range of properties, and their fundamental understanding requires their investigations by various techniques. One of them is transition metal (TM) K-edge X-ray Magnetic Circular Dichroism (XMCD), which is element selec...
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Académie des sciences
2022-09-01
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| Series: | Comptes Rendus. Chimie |
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| Online Access: | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.211/ |
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| author | Bordage, Amélie N’Diaye, Adama Bleuzen, Anne |
| author_facet | Bordage, Amélie N’Diaye, Adama Bleuzen, Anne |
| author_sort | Bordage, Amélie |
| collection | DOAJ |
| description | Prussian Blue analogs (PBAs) are well-known coordination polymers offering a wide range of properties, and their fundamental understanding requires their investigations by various techniques. One of them is transition metal (TM) K-edge X-ray Magnetic Circular Dichroism (XMCD), which is element selective, bulk sensitive and compatible with a wide range of experimental conditions. This short review presents the reciprocal investigation of PBA with TM K-edge XMCD, from the first studies demonstrating that qualitative local magnetic information could be obtained on PBA from TM K-edge XMCD until our on-going project aiming at fundamentally understanding TM K-edge XMCD thanks to PBAs as model-compounds. |
| format | Article |
| id | doaj-art-07c32f6ecfde459889680ef80b8f00fb |
| institution | Kabale University |
| issn | 1878-1543 |
| language | English |
| publishDate | 2022-09-01 |
| publisher | Académie des sciences |
| record_format | Article |
| series | Comptes Rendus. Chimie |
| spelling | doaj-art-07c32f6ecfde459889680ef80b8f00fb2025-02-07T13:31:13ZengAcadémie des sciencesComptes Rendus. Chimie1878-15432022-09-0125G128128810.5802/crchim.21110.5802/crchim.211Prussian Blue analogs and transition metal K-edge XMCD: a longstanding friendshipBordage, Amélie0https://orcid.org/0000-0001-6452-547XN’Diaye, Adama1Bleuzen, Anne2https://orcid.org/0000-0001-9885-4378ICMMO, Université Paris-Saclay, CNRS, Orsay, FranceICMMO, Université Paris-Saclay, CNRS, Orsay, FranceICMMO, Université Paris-Saclay, CNRS, Orsay, FrancePrussian Blue analogs (PBAs) are well-known coordination polymers offering a wide range of properties, and their fundamental understanding requires their investigations by various techniques. One of them is transition metal (TM) K-edge X-ray Magnetic Circular Dichroism (XMCD), which is element selective, bulk sensitive and compatible with a wide range of experimental conditions. This short review presents the reciprocal investigation of PBA with TM K-edge XMCD, from the first studies demonstrating that qualitative local magnetic information could be obtained on PBA from TM K-edge XMCD until our on-going project aiming at fundamentally understanding TM K-edge XMCD thanks to PBAs as model-compounds.https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.211/Prussian Blue analogsTransition metal K-edge XMCDExchange interactionSpectroscopic developmentStructural distortion |
| spellingShingle | Bordage, Amélie N’Diaye, Adama Bleuzen, Anne Prussian Blue analogs and transition metal K-edge XMCD: a longstanding friendship Comptes Rendus. Chimie Prussian Blue analogs Transition metal K-edge XMCD Exchange interaction Spectroscopic development Structural distortion |
| title | Prussian Blue analogs and transition metal K-edge XMCD: a longstanding friendship |
| title_full | Prussian Blue analogs and transition metal K-edge XMCD: a longstanding friendship |
| title_fullStr | Prussian Blue analogs and transition metal K-edge XMCD: a longstanding friendship |
| title_full_unstemmed | Prussian Blue analogs and transition metal K-edge XMCD: a longstanding friendship |
| title_short | Prussian Blue analogs and transition metal K-edge XMCD: a longstanding friendship |
| title_sort | prussian blue analogs and transition metal k edge xmcd a longstanding friendship |
| topic | Prussian Blue analogs Transition metal K-edge XMCD Exchange interaction Spectroscopic development Structural distortion |
| url | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.211/ |
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