Synthesis and Oxidative Coupling of Bi-cyclononatetraenylide – Reaction of Bi-cyclononatetraenyl with Potassium
Contrary to literature reports, treatment of bi-cyclononatetraenyl (1) with potassium does not give bi-cyclononatetraenylide (2), but ccct -cyclononatetraenide (6) in a high yield. Twofold deprotonation of the ring assembly 1 takes place after equilibration 1 ⇌ 1' followed by treatment of 1�...
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1987-02-01
|
| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9774 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Summary: | Contrary to literature reports, treatment of bi-cyclononatetraenyl (1) with potassium does not give bi-cyclononatetraenylide (2), but ccct -cyclononatetraenide (6) in a high yield. Twofold deprotonation of the ring assembly 1 takes place after equilibration 1 ⇌ 1' followed by treatment of 1' with K-tert-butoxide/Li-diisopropylamide. The structure of 2 follows from its spectroscopic data as well as from the successful oxidative treatment of 2 with Ag⊕ to give thermally unstable nonafulvalene (3).
|
|---|---|
| ISSN: | 0009-4293 2673-2424 |