Synthesis and characterization of cis-bisdiphenylphosphinoethene gold(I) complexes
A series of solid-state structures of gold(I) complexes using the semi-rigid cis-1,2- bis(diphenylphosphino)ethene (= cis-bdppe) ligand are reported. The proximity of the phosphine donor atoms of the bidentate ligand framework greatly favors formation of mononuclear over di- nuclear complexes. Struc...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Académie des sciences
2024-08-01
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| Series: | Comptes Rendus. Chimie |
| Subjects: | |
| Online Access: | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.328/ |
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| Summary: | A series of solid-state structures of gold(I) complexes using the semi-rigid cis-1,2- bis(diphenylphosphino)ethene (= cis-bdppe) ligand are reported. The proximity of the phosphine donor atoms of the bidentate ligand framework greatly favors formation of mononuclear over di- nuclear complexes. Structural analysis and theoretical studies shed further light on counter intermolecular packing motifs in the solid state including interactions of solvent, ligand and counterion fragments. |
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| ISSN: | 1878-1543 |