Mechanistic Insights into the Surface Instabilities of TiNb2O7, a High‐Power Li‐Ion Anode
Abstract TiNb2O7 (TNO) is a promising Li‐ion battery anode for high‐power applications, such as implantable medical devices and heavy‐duty equipment. Hailed as being safe due to its elevated operating potential near 1.6 V, TNO has long been assumed to be highly stable in the carbonate‐based electrol...
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| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley-VCH
2025-06-01
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| Series: | Advanced Materials Interfaces |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/admi.202500123 |
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| Summary: | Abstract TiNb2O7 (TNO) is a promising Li‐ion battery anode for high‐power applications, such as implantable medical devices and heavy‐duty equipment. Hailed as being safe due to its elevated operating potential near 1.6 V, TNO has long been assumed to be highly stable in the carbonate‐based electrolytes used in Li‐ion batteries. Herein, all mechanisms occurring at the surface of both TNO and Nd‐doped TNO are identified, and both materials in fact show significant gassing. CO2 is even released at open circuit conditions, demonstrating the poor chemical stability of the material in the electrolyte even prior to battery operation. Such extreme instability is a critical safety concern. In addition, it was found that Ti dissolves from the surface of TNO particles at low voltage (below 1.4 V vs Li), and in fact deposits on the counter electrode. Ti further inside TNO particles then diffuses to the Ti‐poor surface during discharge. Partial carbon‐coating as a mitigating measure has also been tested and found to exacerbate these processes. The findings identify novel reactions occurring within TNO, and clearly highlight the need to stabilize the surfaces of TNO in order to prevent such aggressive deterioration at the surface of the particles. |
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| ISSN: | 2196-7350 |